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公开(公告)号：US11505879B2
公开(公告)日：2022-11-22
申请号：US17336040
申请日：2021-06-01
Applicant: DSM IP ASSETS B.V.
Inventor： Joseph Arnold Paul Maria Simmelink , Jacobus Johannes Mencke , Martinus Johannes Nicolaas Jacobs , Roeloef Marissen
IPC: D01F6/04 , A61L17/04 , A61L27/16 , D01D4/02 , D02G3/02 , F41H5/04 , B32B5/22 , B32B27/06 , B32B15/14 , B32B7/03 , D01D5/18 , C08F10/02 , C08L23/06 , C08L53/02 , D07B1/02
Abstract: Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.
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公开(公告)号：US10711375B2
公开(公告)日：2020-07-14
申请号：US16353993
申请日：2019-03-14
Applicant: DSM IP ASSETS B.V.
Inventor： Joseph Arnold Paul Maria Simmelink , Jacobus Johannes Mencke , Martinus Johannes Nicolaas Jacobs , Roeloef Marissen
IPC: D01F6/04 , D01D4/02 , D02G3/02 , D01D5/18 , C08F10/02 , C08L23/06 , C08L53/02 , D07B1/02 , A61L17/04 , A61L27/16 , F41H5/04
Abstract: Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.
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公开(公告)号：US09863742B2
公开(公告)日：2018-01-09
申请号：US15178561
申请日：2016-06-09
Applicant: DSM IP ASSETS B.V.
Inventor： Roelof Marissen , Joseph Arnold Paul Maria Simmelink , Reinard Jozef Maria Steeman , Gijsbertus Hendrikus Maria Calis , Jacobus Johannes Mencke , Jean Hubert Marie Beugels , David Vanek , Johann Van Elburg , Alexander Volker Peters , Steen Tanderup , Marko Dorschu
CPC classification number: F41H5/0471 , B32B5/022 , B32B5/024 , B32B7/005 , B32B27/06 , B32B2571/02 , F41H5/0421 , F41H5/0428 , F41H5/0457 , F41H5/0485 , Y10T156/1015 , Y10T428/24058 , Y10T428/24074 , Y10T428/24479 , Y10T428/2495 , Y10T428/2913
Abstract: The invention relates to ballistic resistant article having a multilayered material sheet which includes a consolidated stack of unidirectional monolayers of drawn polymer, whereby the draw direction of two subsequent monolayers in the stack differs. At least one monolayer comprises a plurality of unidirectional tapes of the drawn polymer, aligned in the same direction, whereby adjacent tapes do not overlap. The invention also relates to a process for the preparation of the multilayered material sheet, and to a ballistic resistant article comprising the multilayered material sheet.
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公开(公告)号：US10557690B2
公开(公告)日：2020-02-11
申请号：US16354021
申请日：2019-03-14
Applicant: DSM IP ASSETS B.V.
Inventor： Joseph Arnold Paul Maria Simmelink , Jacobus Johannes Mencke , Martinus Johannes Nicolaas Jacobs , Roeloef Marissen
IPC: F41H5/04 , A61L17/04 , A61L27/16 , D01D4/02 , D01F6/04 , D02G3/02 , D01D5/18 , C08F10/02 , C08L23/06 , C08L53/02 , D07B1/02
Abstract: Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.
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公开(公告)号：US09625237B2
公开(公告)日：2017-04-18
申请号：US13942681
申请日：2013-07-15
Applicant: DSM IP ASSETS B.V.
Inventor： Roelof Marissen , Joseph Arnold Paul Maria Simmelink , Reinard Jozef Maria Steeman , Gijsbertus Hendrikus Maria Calis , Jacobus Johannes Mencke , Jean Hurbert Marie Beugels , David Vanek , Johann Van Elburg , Alexander Volker Peters , Steen Tanderup
IPC: F41H5/04
CPC classification number: F41H5/0471 , D07B2201/2003 , D07B2205/2014 , F41H5/04 , F41H5/0428 , F41H5/0457 , F41H5/0478 , F41H5/0485 , Y10T156/10 , Y10T428/24058 , Y10T428/24074 , Y10T428/24116 , Y10T428/24479 , Y10T428/2495 , Y10T428/26 , Y10T428/265 , Y10T428/269 , Y10T428/2913 , Y10T442/30 , Y10T442/3504 , Y10T442/3707 , Y10T442/3886 , D07B2801/10
Abstract: The invention relates to a multilayered material sheet comprising a consolidated stack of unidirection monolayers of drawn ultra high molecular weight polyolefine. The draw direction of two subsequent monolayers in the stack differs. Moreover the thickness of at least one monolayer does not exceed 50 μm, and the strength of at least one monolayer is comprised between 1.2 GPa and 3 GPa. The invention also relates to a ballistic resistant article comprising the multilayered material sheet and to a process for the preparation of the ballistic resistant article.
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Patent Agency Ranking
公开(公告)号：US09702664B2
公开(公告)日：2017-07-11
申请号：US14092819
申请日：2013-11-27
Applicant: DSM IP ASSETS B.V.
Inventor： Roelof Marissen , Joseph Arnold Paul Maria Simmelink , Reinard Jozef Maria Steeman , Gijsbertus Hendrikus Maria Calis , Jacobus Johannes Mencke , Jean Hubert Marie Beugels , David Vanek , Johann Van Elburg , Alexander Volker Peters , Steen Tanderup , Marko Dorschu
CPC classification number: F41H5/0471 , B32B5/022 , B32B5/024 , B32B7/005 , B32B27/06 , B32B2571/02 , F41H5/0421 , F41H5/0428 , F41H5/0457 , F41H5/0485 , Y10T156/1015 , Y10T428/24058 , Y10T428/24074 , Y10T428/24479 , Y10T428/2495 , Y10T428/2913
Abstract: The invention relates to a multilayered material sheet comprising a consolidated stack of unidirectional monolayers of drawn polymer, whereby the draw direction of two subsequent monolayers in the stack differs. At least one monolayer comprises a plurality of unidirectional tapes of the drawn polymer, aligned in the same direction, whereby adjacent tapes do not overlap. The invention also relates to a process for the preparation of the multilayered material sheet, and to a ballistic resistant article comprising the multilayered material sheet.
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公开(公告)号：US10557689B2
公开(公告)日：2020-02-11
申请号：US16353957
申请日：2019-03-14
Applicant: DSM IP ASSETS B.V.
Inventor： Joseph Arnold Paul Maria Simmelink , Jacobus Johannes Mencke , Martinus Johannes Nicolaas Jacobs , Roeloef Marissen
IPC: F41H5/04 , A61L17/04 , A61L27/16 , D01D4/02 , D01F6/04 , D02G3/02 , D01D5/18 , C08F10/02 , C08L23/06 , C08L53/02 , D07B1/02
Abstract: Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.
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公开(公告)号：US11230797B2
公开(公告)日：2022-01-25
申请号：US14364910
申请日：2012-12-14
Applicant: DSM IP ASSETS B.V.
Abstract: The invention relates to a multifilament yarn containing n filaments, wherein the filaments are obtained by spinning an ultra-high molecular weight polyethylene (UHMWPE), said yarn having a tenacity (Ten) as expressed in cN/dtex of Ten(cN/dtex)=f×n−0.05×dpf−0.15, wherein Ten is at least 39 cN/dtex, n is at least 25, f is a factor of at least 58 and dpf is the dtex per filament.
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公开(公告)号：US09759525B2
公开(公告)日：2017-09-12
申请号：US14635993
申请日：2015-03-02
Applicant: DSM IP Assets B.V.
Inventor： Joseph Arnold Paul Maria Simmelink , Jacobus Johannes Mencke , Martinus Johannes Nicolaas Jacobs , Roeloef Marissen
IPC: F41H5/04 , A61L17/04 , A61L27/16 , D01D4/02 , D01F6/04 , D02G3/02 , D01D5/18 , C08F10/02 , C08L23/06 , C08L53/02 , D07B1/02
CPC classification number: F41H5/0478 , A61L17/04 , A61L27/16 , C08F10/02 , C08L23/06 , C08L53/02 , C08L2203/12 , D01D4/02 , D01D5/18 , D01F6/04 , D02G3/02 , D07B1/025 , D07B2205/2014 , D07B2801/10 , D10B2321/0211 , F41H5/0471 , F41H5/0485 , Y10T428/24041 , Y10T428/24058 , Y10T428/24124 , Y10T428/249921 , Y10T428/29 , Y10T428/2913 , Y10T428/2967 , Y10T442/2615 , Y10T442/2623
Abstract: The invention relates to a process for making high-performance polyethylene multi-filament yarn comprising the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Ln with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. The invention further relates to a high-performance polyethylene multifilament yarn, and to semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites.
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公开(公告)号：US20140342109A1
公开(公告)日：2014-11-20
申请号：US14364910
申请日：2012-12-14
Applicant: DSM IP ASSETS B.V.
CPC classification number: D01F6/04 , D01D5/06 , D02G3/02 , D07B1/025 , D07B2201/1096 , D07B2201/2009 , D07B2205/2014 , D07B2501/2038 , D07B2501/2061 , D10B2321/0211 , Y10T428/1369 , Y10T428/24124 , Y10T428/249921 , Y10T428/298 , Y10T428/31913 , Y10T442/60 , D07B2801/10
Abstract: The invention relates to a multifilament yarn containing n filaments, wherein the filaments are obtained by spinning an ultra-high molecular weight polyethylene (UHMWPE), said yarn having a tenacity (Ten) as expressed in cN/dtex of Ten(cN/dtex)=f×n−0.05×dpf−0.15, wherein Ten is at least 39 cN/dtex, n is at least 25, f is a factor of at least 58 and dpf is the dtex per filament.
Abstract translation: 本发明涉及一种含有n根长丝的复丝纱，其中通过纺丝超高分子量聚乙烯（UHMWPE）获得长丝，所述纱线具有以cN / dtex为单位表示的强度（Ten）（Ten）（cN / dtex） = f×n-0.05×dpf-0.15，其中十个为至少39cN / dtex，n为至少25，f为至少58的系数，dpf为每丝的dtex。
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