公开(公告)号：US3607849A

公开(公告)日：1971-09-21

申请号：US3607849D

申请日：1966-09-29

Applicant: DYNAMIT NOBEL AG

Inventor： BUNING ROBERT ,  KIESSEL KARL-HEINZ ,  FRICK SIEGMUND ,  BIER GERHARD

IPC: C08F2/02 ,  C08F214/06 ,  C08F1/04 ,  C08F1/62 ,  C08F15/06

CPC classification number: C08F214/06

Abstract: Production of an improved chlorinated polymer by the low temperature bulk copolymerization of vinyl chloride and 1,2-trans dichloroethylene where the polymerization is carried out to at least a 30 percent conversion of monomers at a temperature of -5 to -30* C. and under substantially shearing action.

公开(公告)号：US3459692A

公开(公告)日：1969-08-05

申请号：US3459692D

申请日：1966-04-21

Applicant: DYNAMIT NOBEL AG

Inventor： BUNING ROBERT ,  KONERMANN HANS-EWALD ,  DIESSEL KARL-HEINZ ,  BIER GERHARD

IPC: C08L27/24 ,  C08F29/24 ,  C08F29/04 ,  C08F29/14

CPC classification number: C08L27/24 ,  C08K5/09 ,  C08L23/06 ,  C08L23/28 ,  C08L31/04 ,  C08L33/20 ,  C08L2666/04

Abstract: A composition comprises (i) from 0.5 to 25 parts by weight of an after-chlorinated polyethylene having a relative viscosity of of 1.5 to 18 and a chlorine content of from 20 to 60% by weight, and (ii) from 99.5 to 75 parts by weight of an after-chlorinated stereoregular polyvinylchloride having a relative viscosity of 1.5 to 6.5 and a chlorine content of from 58 to 71% by weight, the chlorine atoms of the after-chlorinated polyvinyl chloride originally being 55 to 85% syndiotactically arranged. Other components of the composition may be: polyvinyl acetate, polyethylene, polyacrylonitrile, lubricants, e.g. low molecular weight polyethylene or barium cadmium stearate, stabilizers, pigments, dyestuffs, fillers, and light-protection agents, e.g. phosphorous acid esters. The chlorination of polyvinyl chloride in suspension, using a swelling agent, excess chlorine, and ultra-violet light, is described in the examples. In comparative Examples 5-8, an after-chlorinated atactic polyvinyl chloride is used in place of the stereoregular polymer. The compositions may be formed into shaped elements or coatings.

公开(公告)号：US3509109A

公开(公告)日：1970-04-28

申请号：US3509109D

申请日：1967-07-12

Applicant: DYNAMIT NOBEL AG

Inventor： BUNING ROBERT ,  DIESSEL KARL-HEINZ

IPC: C08F14/06 ,  C08F1/56 ,  C08F1/46 ,  C08F3/30

CPC classification number: C08F14/06

公开(公告)号：US3647402A

公开(公告)日：1972-03-07

申请号：US3647402D

申请日：1968-10-08

Applicant: DYNAMIT NOBEL AG

Inventor： BUNING ROBERT ,  BERNHARDT GUNTHER ,  BIERWIRTH EGON ,  TRAUTVETTER WERNER

IPC: C08L23/28 ,  C23C18/20 ,  C23B5/60

CPC classification number: C08L23/286 ,  C23C18/2033 ,  C23C18/208 ,  C23C18/24 ,  C23C18/285 ,  C23C18/30 ,  Y10S428/935 ,  Y10T428/12569 ,  Y10T428/12646 ,  Y10T428/12778 ,  Y10T428/31696 ,  Y10T428/31699 ,  C08L2666/04

Abstract: Galvanically metallized thermoplastic shaped articles comprising post-chlorinated polyethylene or mixtures thereof with polyvinyl chloride and/or post-chlorinated polyvinyl chloride.

Abstract translation: 包含后氯化聚乙烯或其与聚氯乙烯和/或后氯化聚氯乙烯的混合物的电镀金属化热塑性成型制品。

公开(公告)号：US3616296A

公开(公告)日：1971-10-26

申请号：US3616296D

申请日：1969-12-31

Applicant: DYNAMIT NOBEL AG

Inventor： BERNHARDT GUNTHER ,  BUNING ROBERT

IPC: C23C18/28 ,  B44D1/092 ,  C23C3/02

CPC classification number: C23C18/285

Abstract: Improved process for metallizing various plastic materials, including shaped vinyl chloride polymer and acrylonitrilebutadiene-styrene polymer articles, which includes using as the sensitizing solution in the known metallization process a solution which contains at least one tin IV salt dissolved therein in addition to the tin II and other conventional components. The sensitizing solution is itself disclosed and claimed.

公开(公告)号：US3556746A

公开(公告)日：1971-01-19

申请号：US3556746D

申请日：1968-10-03

Applicant: DYNAMIT NOBEL AG

Inventor： BERNHARDT GUNTHER ,  BUNING ROBERT ,  BIERWIRTH EGON ,  TRAUTVETTER WERNER

IPC: C08F259/04 ,  C23C18/20 ,  B32B15/08

CPC classification number: C08F259/04 ,  C23C18/2033 ,  C23C18/208 ,  C23C18/24 ,  C23C18/285 ,  C23C18/30 ,  Y10S428/935 ,  Y10T428/12569 ,  Y10T428/12778 ,  Y10T428/31696 ,  Y10T428/31699 ,  C08F214/06

Abstract: A SHAPED ARTICLE OF A VINYLCHLORIDE GRAFTED COPOLYMER OF ETHYLENE AND VINYLCHLORIDE HAVING ON THE SURFACE THEREOF A METAL FILM AND PROCESS FOR PRODUCING SUCH METALLIZED SHAPED ARTICLE COMPRISING (1) PREPARING AN ETHYLENE-VINYLCHLORIDE COPOLYMER, (2) GRAFTING VINYLCHLORIDE ONTO SAID COPOLYMER, (3) FORMING SAID GRAFT COPOLYMER INTO A SHAPED ARTICLE AND (4) APPLYING A METAL FILM TO THE SURFACE OF SAID ARTICLE.

公开(公告)号：US3523109A

公开(公告)日：1970-08-04

申请号：US3523109D

申请日：1966-02-18

Applicant: DYNAMIT NOBEL AG

Inventor： DIESSEL KARL-HEINZ ,  BIER GERHARD ,  TRAUTVETTER WERNER ,  BUNING ROBERT

IPC: C08F14/06 ,  C08F1/62 ,  C08F3/30 ,  C08F15/24

CPC classification number: C08F14/06 ,  Y10S526/915

公开(公告)号：US3928684A

公开(公告)日：1975-12-23

申请号：US36376973

申请日：1973-05-24

Applicant: DYNAMIT NOBEL AG

Inventor： BUNING ROBERT ,  LOEBLER PETER ,  TRAUTVETTER WERNER

IPC: C08J5/24 ,  C08F14/00 ,  C08F214/00 ,  C08F214/06 ,  C08J5/08 ,  C08K7/00 ,  C08L1/00 ,  C08L27/00 ,  B32B5/22 ,  B32B17/06

CPC classification number: B32B27/30 ,  B32B27/12 ,  B32B27/304 ,  B32B2262/101 ,  B32B2305/08 ,  B32B2309/68 ,  C08J5/08 ,  C08J2327/00 ,  C08J2327/06 ,  C08K7/14 ,  C08K9/04 ,  C08L27/06 ,  Y10T428/2962 ,  Y10T428/2964 ,  Y10T428/31612 ,  Y10T428/31663 ,  Y10T442/2402 ,  Y10T442/3594

Abstract: Polyvinylchloride or chlorinated polyvinylchloride polymer article reinforced with glass fibers coated with vinyl chloridevinyl trialkoxysilane copolymers in an amount effective to increase the strength characteristics of the article. The copolymer can include at least one of carboxylic acid vinyl esters, unsaturated mono- or dicarboxylic acid esters, and alkyl vinyl ethers.

Abstract translation: 聚氯乙烯或氯化聚氯乙烯聚合物制品用涂覆有氯乙烯基乙烯基三烷氧基硅烷共聚物的玻璃纤维增​​强，其量有效地增加制品的强度特性。 共聚物可以包括羧酸乙烯基酯，不饱和单羧酸酯或二羧酸酯和烷基乙烯基醚中的至少一种。

公开(公告)号：US3637625A

公开(公告)日：1972-01-25

申请号：US3637625D

申请日：1968-05-15

Applicant: DYNAMIT NOBEL AG

Inventor： BUNING ROBERT ,  DIESSEL KARL-HEINZ ,  BIER GERHARD

IPC: C08F14/06 ,  C08F3/30 ,  C08F15/08

CPC classification number: C08F14/06 ,  C08F2/02

Abstract: HOMO AND COPOLYMERIZATION OF VINYL CHLORIDE WITH OR WITHOUT COMONOMERS AT ABOUT -8 TO -50*C. IN THE PRESENCE OF ASCORBIC ACID, HEAVY METAL SALTS AND A COMBINATION OF HYDROGEN PEROXIDE AND CYCLOHEXANESULFONYLACETYL PEROXIDE AS A REDOX SYSTEM POLYMERIZATION CATALYST.

公开(公告)号：US3597334A

公开(公告)日：1971-08-03

申请号：US3597334D

申请日：1968-10-03

Applicant: DYNAMIT NOBEL AG

Inventor： BERNHARDT GUNTHER ,  BUNING ROBERT ,  BIERWIRTH EGON ,  TRAUTVETTER WERNER

IPC: C23C18/20 ,  C23B5/60

CPC classification number: C23C18/30 ,  C23C18/208 ,  C23C18/24 ,  C23C18/285 ,  Y10S428/934 ,  Y10T428/12569 ,  Y10T428/12778

Abstract: AN ELECTROPLATED PRODUCT CONPRISING A GRAFT COPOLYMER OF VINYL CHLORIDE ON A CONJUGATED DIENE BACKBONE. THE COPOLYMER IS FIRST SENSITIZED WITH STANNOUS CHLORIDE, THEN CHEMICALLY PLATED WITH METAL AND THEN ELECTROPLATED.