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1.发明授权Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith 有权制备贵金属合金催化剂的方法及其制备的催化剂公开(公告)号：US08273504B2
公开(公告)日：2012-09-25
申请号：US13223750
申请日：2011-09-01
IPC分类号： B01J23/00 , B01J23/40 , B01J23/42 , B01J23/44 , B01J21/18 , H01M4/02 , H01M4/36 , H01M4/90 , H01M4/92 , H01M4/94
CPC分类号： B82Y30/00 , B01D53/944 , B01D2255/1021 , B01D2255/1026 , B01D2255/106 , B01D2255/20746 , B01D2255/9202 , B01D2257/502 , B01J21/18 , B01J23/40 , B01J23/462 , B01J23/52 , B01J23/8913 , B01J35/0013 , B01J35/006 , B01J37/0072 , B01J37/0211 , B01J37/088 , B22F9/24 , B22F2998/00 , H01M4/921 , H01M4/926 , B22F2303/01 , B22F2301/25 , B22F2303/05 , B22F2301/15
摘要： The invention provides a method for manufacturing supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method involves using polyol solvents as reaction medium and comprises a two-step reduction process in the presence of a support material. In the first step, the first metal (transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (noble metal; e.g. Pt, Pd, Au) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300 ° C. The catalysts manufactured according to the method are used as electrocatalysts for polymer electrolyte membrane fuel cells (PEMFC), direct-methanol fuel cells (DMFC) or as gas phase catalysts for CO oxidation or exhaust gas purification.
摘要翻译： 本发明提供一种具有高合金化和微晶尺寸的负载型贵金属基合金催化剂的制造方法。 该方法包括使用多元醇溶剂作为反应介质，并且在载体材料存在下包括两步还原方法。 在第一步骤中，第一金属（过渡金属，例如Co，Cr，Ru）通过将反应温度升高至80至160℃而被活化。在第二步中，第二金属（贵金属，例如Pt，Pd， Au），将浆料加热到多元醇溶剂的沸点在160〜300℃的范围内。根据该方法制造的催化剂用作聚合物电解质膜燃料电池（PEMFC）的电极催化剂， 甲醇燃料电池（DMFC）或用于CO氧化或废气净化的气相催化剂。
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2.发明授权Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith 有权制备贵金属合金催化剂的方法及其制备的催化剂公开(公告)号：US07713910B2
公开(公告)日：2010-05-11
申请号：US10977579
申请日：2004-10-29
CPC分类号： B82Y30/00 , B01D53/944 , B01D2255/1021 , B01D2255/1026 , B01D2255/106 , B01D2255/20746 , B01D2255/9202 , B01D2257/502 , B01J21/18 , B01J23/40 , B01J23/462 , B01J23/52 , B01J23/8913 , B01J35/0013 , B01J35/006 , B01J37/0072 , B01J37/0211 , B01J37/088 , B22F9/24 , B22F2998/00 , H01M4/921 , H01M4/926 , B22F2303/01 , B22F2301/25 , B22F2303/05 , B22F2301/15
摘要： The present invention provides a method for manufacture of supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method is based on the use of polyol solvents as reaction medium and comprises of a two-step reduction process in the presence of a support material. In the first step, the first metal (M1=transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (M2=noble metal; e.g. Pt, Pd, Au and mixtures thereof) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300° C. Due to this two-step method, an uniform reduction occurs, resulting in noble metal based catalysts with a high degree of alloying and a small crystallite size of less than 3 nm. Due to the high degree of alloying, the lattice constants are lowered. The catalysts manufactured according to the method are used as electrocatalysts for polymer electrolyte membrane fuel cells (PEMFC), direct-methanol fuel cells (DMFC) or as gas phase catalysts for CO oxidation or exhaust gas purification.
摘要翻译： 本发明提供一种具有高合金化和微晶尺寸的负载型贵金属基合金催化剂的制造方法。 该方法基于使用多元醇溶剂作为反应介质，并且包括在存在载体材料的情况下的两步还原过程。 在第一步骤中，第一金属（M1 =过渡金属，例如Co，Cr，Ru）通过将反应温度升高至80至160℃来活化。在第二步中，第二金属（M2 =贵金属;例如 Pt，Pd，Au及其混合物），将浆料加热到多元醇溶剂的沸点在160〜300℃的范围内。由于这种两步法，发生均匀的还原，导致贵金属 具有高度合金化和小于3nm的微晶尺寸的金属基催化剂。 由于高合金化，晶格常数降低。 根据该方法制造的催化剂用作聚合物电解质膜燃料电池（PEMFC），直接甲醇燃料电池（DMFC）或用于CO氧化或废气净化的气相催化剂的电极催化剂。
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3.发明授权Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith 有权制备贵金属合金催化剂的方法及其制备的催化剂公开(公告)号：US08017548B2
公开(公告)日：2011-09-13
申请号：US12752410
申请日：2010-04-01
CPC分类号： B82Y30/00 , B01D53/944 , B01D2255/1021 , B01D2255/1026 , B01D2255/106 , B01D2255/20746 , B01D2255/9202 , B01D2257/502 , B01J21/18 , B01J23/40 , B01J23/462 , B01J23/52 , B01J23/8913 , B01J35/0013 , B01J35/006 , B01J37/0072 , B01J37/0211 , B01J37/088 , B22F9/24 , B22F2998/00 , H01M4/921 , H01M4/926 , B22F2303/01 , B22F2301/25 , B22F2303/05 , B22F2301/15
摘要： The present invention provides a method for manufacture of supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method is based on the use of polyol solvents as reaction medium and comprises of a two-step reduction process in the presence of a support material. In the first step, the first metal (M1=transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (M2=noble metal; e.g. Pt, Pd, Au and mixtures thereof) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300° C. Due to this two-step method, an uniform reduction occurs, resulting in noble metal based catalysts with a high degree of alloying and a small crystallite size of less than 3 nm. Due to the high degree of alloying, the lattice constants are lowered. The catalysts manufactured according to the method are used as electrocatalysts for polymer electrolyte membrane fuel cells (PEMFC), direct-methanol fuel cells (DMFC) or as gas phase catalysts for CO oxidation or exhaust gas purification.
摘要翻译： 本发明提供一种具有高合金化和微晶尺寸的负载型贵金属基合金催化剂的制造方法。 该方法基于使用多元醇溶剂作为反应介质，并且包括在存在载体材料的情况下的两步还原过程。 在第一步骤中，第一金属（M1 =过渡金属，例如Co，Cr，Ru）通过将反应温度升高至80至160℃来活化。在第二步中，第二金属（M2 =贵金属;例如 Pt，Pd，Au及其混合物），将浆料加热到多元醇溶剂的沸点在160〜300℃的范围内。由于这种两步法，发生均匀的还原，导致贵金属 具有高度合金化和小于3nm的微晶尺寸的金属基催化剂。 由于高合金化，晶格常数降低。 根据该方法制造的催化剂用作聚合物电解质膜燃料电池（PEMFC），直接甲醇燃料电池（DMFC）或用于CO氧化或废气净化的气相催化剂的电极催化剂。
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4.发明申请Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith 有权制备贵金属合金催化剂的方法及其制备的催化剂公开(公告)号：US20100190641A1
公开(公告)日：2010-07-29
申请号：US12752410
申请日：2010-04-01
CPC分类号： B82Y30/00 , B01D53/944 , B01D2255/1021 , B01D2255/1026 , B01D2255/106 , B01D2255/20746 , B01D2255/9202 , B01D2257/502 , B01J21/18 , B01J23/40 , B01J23/462 , B01J23/52 , B01J23/8913 , B01J35/0013 , B01J35/006 , B01J37/0072 , B01J37/0211 , B01J37/088 , B22F9/24 , B22F2998/00 , H01M4/921 , H01M4/926 , B22F2303/01 , B22F2301/25 , B22F2303/05 , B22F2301/15
摘要： The present invention provides a method for manufacture of supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method is based on the use of polyol solvents as reaction medium and comprises of a two-step reduction process in the presence of a support material. In the first step, the first metal (M1 =transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (M2=noble metal; e.g. Pt, Pd, Au and mixtures thereof) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300° C. Due to this two-step method, an uniform reduction occurs, resulting in noble metal based catalysts with a high degree of alloying and a small crystallite size of less than 3 nm. Due to the high degree of alloying, the lattice constants are lowered. The catalysts manufactured according to the method are used as electrocatalysts for polymer electrolyte membrane fuel cells (PEMFC), direct-methanol fuel cells (DMFC) or as gas phase catalysts for CO oxidation or exhaust gas purification.
摘要翻译： 本发明提供一种具有高合金化和微晶尺寸的负载型贵金属基合金催化剂的制造方法。 该方法基于使用多元醇溶剂作为反应介质，并且包括在存在载体材料的情况下的两步还原过程。 在第一步骤中，第一金属（M1 =过渡金属，例如Co，Cr，Ru）通过将反应温度升高至80至160℃来活化。在第二步中，第二金属（M2 =贵金属;例如 Pt，Pd，Au及其混合物），将浆料加热到多元醇溶剂的沸点在160〜300℃的范围内。由于这种两步法，发生均匀的还原，导致贵金属 具有高度合金化和小于3nm的微晶尺寸的金属基催化剂。 由于高合金化，晶格常数降低。 根据该方法制造的催化剂用作聚合物电解质膜燃料电池（PEMFC），直接甲醇燃料电池（DMFC）或用于CO氧化或废气净化的气相催化剂的电极催化剂。
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5.发明申请Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith 有权制备贵金属合金催化剂的方法及其制备的催化剂公开(公告)号：US20060094597A1
公开(公告)日：2006-05-04
申请号：US10977579
申请日：2004-10-29
申请人： Dan Goia , Marco Lopez , Tapan Sau , Mihaela-Ortansa Jitianu
发明人： Dan Goia , Marco Lopez , Tapan Sau , Mihaela-Ortansa Jitianu
CPC分类号： B82Y30/00 , B01D53/944 , B01D2255/1021 , B01D2255/1026 , B01D2255/106 , B01D2255/20746 , B01D2255/9202 , B01D2257/502 , B01J21/18 , B01J23/40 , B01J23/462 , B01J23/52 , B01J23/8913 , B01J35/0013 , B01J35/006 , B01J37/0072 , B01J37/0211 , B01J37/088 , B22F9/24 , B22F2998/00 , H01M4/921 , H01M4/926 , B22F2303/01 , B22F2301/25 , B22F2303/05 , B22F2301/15
摘要： The present invention provides a method for manufacture of supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method is based on the use of polyol solvents as reaction medium and comprises of a two-step reduction process in the presence of a support material. In the first step, the first metal (M1=transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (M2=noble metal; e.g. Pt, Pd, Au and mixtures thereof) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300° C. Due to this two-step method, an uniform reduction occurs, resulting in noble metal based catalysts with a high degree of alloying and a small crystallite size of less than 3 nm. Due to the high degree of alloying, the lattice constants are lowered. The catalysts manufactured according to the method are used as electrocatalysts for polymer electrolyte membrane fuel cells (PEMFC), direct-methanol fuel cells (DMFC) or as gas phase catalysts for CO oxidation or exhaust gas purification.
摘要翻译： 本发明提供一种具有高合金化和微晶尺寸的负载型贵金属基合金催化剂的制造方法。 该方法基于使用多元醇溶剂作为反应介质，并且包括在存在载体材料的情况下的两步还原过程。 在第一步骤中，第一金属（M1 =过渡金属，例如Co，Cr，Ru）通过将反应温度升高至80至160℃来活化。在第二步中，第二金属（M2 =贵金属;例如 Pt，Pd，Au及其混合物），将浆料加热到多元醇溶剂的沸点在160〜300℃的范围内。由于这种两步法，发生均匀的还原，导致贵金属 具有高度合金化和小于3nm的微晶尺寸的金属基催化剂。 由于高合金化，晶格常数降低。 根据该方法制造的催化剂用作聚合物电解质膜燃料电池（PEMFC），直接甲醇燃料电池（DMFC）或用于CO氧化或废气净化的气相催化剂的电极催化剂。
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