公开(公告)号：US07005268B2

公开(公告)日：2006-02-28

申请号：US10098091

申请日：2002-03-13

申请人： Daniel B. Roitman ,  Calvin B. Ward ,  Seiji Inaoka

发明人： Daniel B. Roitman ,  Calvin B. Ward ,  Seiji Inaoka

IPC分类号： G01N33/53

CPC分类号： G01N33/5438 ,  C12Q1/6816 ,  C12Q1/6837 ,  G01N33/54373 ,  C12Q2537/125 ,  C12Q2565/543 ,  C12Q2563/113

摘要： A method for detecting the presence of target molecules bound to a working electrode in a first location. The first location is coated with a detection solution containing labeling molecules that include a first charge-separation moiety attached to a first molecule that binds to the target molecule. The first charge-separation moiety includes a material that generates hole-electron pairs in response to being illuminated by light in a first band of wavelengths. After removing any unbound labeling, the working electrode is immersed in a solution containing a compound that is oxidized by the generated holes. The first location is then selectively illuminated with light in the first band; and the change in the current and/or potential is measured between the working electrode and a reference electrode in contact with the solution. The first charge-separation moiety is preferably constructed from particles of a semiconducting material such as TiO2.

摘要翻译： 一种用于检测在第一位置与工作电极结合的靶分子的存在的方法。 第一位置涂覆有包含标记分子的检测溶液，其包括连接到结合靶分子的第一分子的第一电荷分离部分。 第一电荷分离部分包括响应于在第一波长波段的光照射而产生空穴 - 电子对的材料。 在去除任何未结合的标签之后，将工作电极浸入含有被所产生的孔氧化的化合物的溶液中。 然后用第一波段的光选择性地照亮第一位置; 并且在与溶液接触的工作电极和参考电极之间测量电流和/或电位的变化。 第一电荷分离部分优选由半导体材料（例如TiO 2）的颗粒构成。

公开(公告)号：US06552101B1

公开(公告)日：2003-04-22

申请号：US09401665

申请日：1999-09-22

申请人： Daniel B. Roitman ,  Seiji Inaoka ,  Riogoberto C. Advincula

发明人： Daniel B. Roitman ,  Seiji Inaoka ,  Riogoberto C. Advincula

IPC分类号： C08F3208

CPC分类号： C08G61/126 ,  C08G61/123 ,  C08G61/124

摘要： A precursor polymer that can be electrochemically polymerized to form an electrically conducting polymer. A precursor according to the present invention includes a plurality of electrochemical polymerizable monomers, each monomer having first and second polymer-forming active sites that can be joined by electrochemical polymerization. The monomers also include third and fourth polymer-forming active sites that can be joined chemically in solution. The monomers in the precursor polymer are linked by the third and fourth polymer-forming active sites. The monomers are chosen such the precursor polymer is soluble in a predetermined solvent while the polymer resulting from the electrochemical polymerization of the precursor polymers via the first and second polymer-forming sites is electrically conducting and insoluble in the solvent. The monomers can be synthesized from fluorene, triophene, pyrrol, biphenyl, poly(vinyl carbazole) or poly (vinyl oxy thiophene). Monomers comprising dimers chosen from this group can also be utilized. The monomers may also include a spacer group bonded to one of the first or second polymer-forming active sites. Spacer groups consisting of (CH2)n, (OCH2)n, or (OCH2CH2)n, where 1≦n≦20 may be utilized for this purpose.

摘要翻译： 可以进行电化学聚合以形成导电聚合物的前体聚合物。 根据本发明的前体包括多个电化学可聚合单体，每个单体具有可通过电化学聚合连接的第一和第二聚合物形成活性位点。 单体还包括可以在溶液中化学连接的第三和第四聚合物形成活性位点。 前体聚合物中的单体通过第三和第四聚合物形成活性位点连接。 选择单体，使得前体聚合物可溶于预定溶剂，而由前体聚合物经由第一和第二聚合物形成位点的电化学聚合得到的聚合物是导电的并且不溶于溶剂。 单体可以由芴，三酚，吡咯，联苯，聚（乙烯基咔唑）或聚（乙烯基氧基噻吩）合成。 也可以使用包含从该组中选择的二聚体的单体。 单体还可以包括键合到第一或第二聚合物形成活性位点之一的间隔基。 由此可以使用由（CH 2）n，（OCH 2）n或（OCH 2 CH 2）n组成的间隔基团，其中1 <= n <= 20可用于此目的。

公开(公告)号：US06627331B1

公开(公告)日：2003-09-30

申请号：US09401691

申请日：1999-09-22

申请人： Daniel B. Roitman ,  Seiji Inaoka ,  Riogoberto C. Advincula

发明人： Daniel B. Roitman ,  Seiji Inaoka ,  Riogoberto C. Advincula

IPC分类号： H05B3314

CPC分类号： H05B33/14 ,  C09K11/06 ,  C09K2211/14 ,  H01L27/3211 ,  H01L27/3281 ,  H01L51/0006 ,  H01L51/0036 ,  H01L51/0044 ,  H01L51/56 ,  Y10S428/917 ,  Y10T428/24917

摘要： A display device and a method for fabricating the display device. A display device according to the present invention is fabricated from an electrode layer that includes a plurality of electrodes on a substrate. The electrode layer is immersed in a solution of a first precursor polymer in a first solvent. The first precursor polymer includes a plurality of electrochemical polymerizable monomers. Each monomer has first and second polymer-forming active sites that can be joined by electrochemical polymerization and third and fourth polymer-forming active sites that can be joined chemically in solution. The first precursor polymer is soluble in the first solvent whereas a first polymer formed by electrochemical polymerization of the first and second polymer-forming active sites is insoluble in the first solvent. A layer of the first polymer is deposited on the a first one of the electrodes by connecting that electrode to an electric circuit while leaving the others of the electrodes disconnected from the circuit. The electrode is then immersed in a solution of said first precursor polymer. The circuit applies a potential to the electrode sufficient to cause the first and second polymer active sites to polymerize by electrochemical polymerization thereby depositing a first polymer layer includes the first polymer precursor on the first one of the electrodes. A second electrode layer is then deposited over the first polymer layer. In multi-color displays, the different polymer layers corresponding to the various colors are deposited on different ones of the electrodes by sequentially depositing each polymer layer in a similar manner.

摘要翻译： 一种显示装置及其制造方法。 根据本发明的显示装置由在基板上包括多个电极的电极层制成。 将电极层浸渍在第一前体聚合物在第一溶剂中的溶液中。 第一前体聚合物包括多个电化学可聚合单体。 每个单体具有可以通过电化学聚合连接的第一和第二聚合物形成活性位点和可以在溶液中化学连接的第三和第四聚合物形成活性位点。 第一前体聚合物可溶于第一溶剂，而通过第一和第二聚合物形成活性位点的电化学聚合形成的第一聚合物不溶于第一溶剂。 将第一聚合物层沉积在第一电极上，将该电极连接到电路上，同时使电极中的其它电极与电路断开。 然后将电极浸入所述第一前体聚合物的溶液中。 电路向电极施加足以使第一和第二聚合物活性位点通过电化学聚合聚合的电势，从而沉积包含第一聚合物前体在第一电极上的第一聚合物前体。 然后在第一聚合物层上沉积第二电极层。 在多色显示器中，通过以类似的方式依次沉积每个聚合物层，将不同颜色的不同聚合物层沉积在不同的电极上。

公开(公告)号：US06803097B2

公开(公告)日：2004-10-12

申请号：US10327285

申请日：2002-12-19

申请人： Daniel B. Roitman ,  Seiji Inaoka

发明人： Daniel B. Roitman ,  Seiji Inaoka

IPC分类号： B32B516

CPC分类号： C08J5/18 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/259 ,  Y10T428/2982 ,  Y10T428/2987

摘要： The present invention is a film and method for making the same. The film includes a plurality of particles having a desired film property that are entrapped in a matrix of linkage polymer molecules. The linkage polymer molecules ionically bind to the particles. The linkage polymer molecules are electrochemically polymerizable in a solvent. The particles are insoluble in the solvent. The film is prepared by providing an electrode and a solution of the linkage polymer molecules in which the particles are suspended. An electrical potential is provided between the solution and the electrode in temporal sequence that causes the linkage polymer molecules to polymerize in the vicinity of the electrode thereby entrapping the particles.

摘要翻译： 本发明是其制造方法及其制造方法。 膜包括多个具有期望的膜性质的颗粒，其被捕获在连接聚合物分子的基质中。 连接聚合物分子与颗粒离子结合。 连接聚合物分子在溶剂中可电化学聚合。 颗粒不溶于溶剂。 通过提供悬浮颗粒的连接聚合物分子的电极和溶液来制备膜。 以时间顺序在溶液和电极之间提供电位，使得连接聚合物分子在电极附近聚合，从而截留颗粒。

公开(公告)号：US06533918B2

公开(公告)日：2003-03-18

申请号：US09919072

申请日：2001-09-11

申请人： Daniel B. Roitman ,  Seiji Inaoka ,  Riogoberto C. Advincula

发明人： Daniel B. Roitman ,  Seiji Inaoka ,  Riogoberto C. Advincula

IPC分类号： C25B300

CPC分类号： C08G61/02 ,  C08G61/10 ,  C08G61/123 ,  Y10T428/24942

摘要： A method for depositing an electrically conducting film on an electrode and the film resulting from that method. An electrically conducting film according to the present invention is deposited by immersing the electrode in a solution of a precursor polymer in a predetermined solvent. The precursor polymer includes a plurality of electrochemical polymerizable monomers. Each monomer has first and second polymer-forming active sites that can be joined by electrochemical polymerization and third and fourth polymer-forming active sites that can be joined chemically in solution. The precursor polymer is constructed from the monomers joined by the third and fourth polymer-forming active sites. The precursor polymer is soluble in the solvent whereas a polymer formed by electrochemical polymerization of the first and second polymer-forming active sites is insoluble in the solvent. An electrical potential is applied to the electrode to cause monomers of the precursor polymer molecules to be joined electrochemically by their first and second polymer-forming active sites.

摘要翻译： 用于在电极上沉积导电膜的方法和由该方法得到的膜。 通过将电极浸入前体聚合物在预定溶剂中的溶液中来沉积根据本发明的导电膜。 前体聚合物包括多个电化学可聚合单体。 每个单体具有可以通过电化学聚合连接的第一和第二聚合物形成活性位点和可以在溶液中化学连接的第三和第四聚合物形成活性位点。 前体聚合物由由第三和第四聚合物形成活性位点连接的单体构成。 前体聚合物可溶于溶剂，而由第一和第二聚合物形成活性位点的电化学聚合形成的聚合物不溶于溶剂。 对电极施加电位，使前体聚合物分子的单体通过其第一和第二聚合物形成活性位点电化学连接。

公开(公告)号：US06294245B1

公开(公告)日：2001-09-25

申请号：US09401666

申请日：1999-09-22

申请人： Daniel B. Roitman ,  Seiji Inaoka ,  Riogoberto C. Advincula

发明人： Daniel B. Roitman ,  Seiji Inaoka ,  Riogoberto C. Advincula

IPC分类号： B41M520

CPC分类号： C08G61/02 ,  C08G61/10 ,  C08G61/123 ,  Y10T428/24942

摘要： A method for depositing an electrically conducting film on an electrode and the film resulting from that method. An electrically conducting film according to the present invention is deposited by immersing the electrode in a solution of a precursor polymer in a predetermined solvent. The precursor polymer includes a plurality of electrochemical polymerizable monomers. Each monomer has first and second polymer-forming active sites that can be joined by electrochemical polymerization and third and fourth polymer-forming active sites that can be joined chemically in solution. The precursor polymer is constructed from the monomers joined by the third and fourth polymer-forming active sites. The precursor polymer is soluble in the solvent whereas a polymer formed by electrochemical polymerization of the first and second polymer-forming active sites is insoluble in the solvent.

摘要翻译： 用于在电极上沉积导电膜的方法和由该方法得到的膜。 通过将电极浸入前体聚合物在预定溶剂中的溶液中来沉积根据本发明的导电膜。 前体聚合物包括多个电化学可聚合单体。 每个单体具有可以通过电化学聚合连接的第一和第二聚合物形成活性位点和可以在溶液中化学连接的第三和第四聚合物形成活性位点。 前体聚合物由由第三和第四聚合物形成活性位点连接的单体构成。 前体聚合物可溶于溶剂，而由第一和第二聚合物形成活性位点的电化学聚合形成的聚合物不溶于溶剂。

公开(公告)号：US20080287333A1

公开(公告)日：2008-11-20

申请号：US11630602

申请日：2005-02-01

申请人： Seiji Inaoka

发明人： Seiji Inaoka

IPC分类号： G03F7/42

CPC分类号： G03F7/425 ,  G03F7/426

摘要： Back end photoresist strippers and residue compositions are provided by non-aqueous compositions that are essentially non-corrosive toward copper as well as aluminum and that comprise a polar organic solvent, a hydroxylated amine, and as a corrosion inhibitor fructose.

摘要翻译： 后端光致抗蚀剂剥离剂和残余物组合物由非水性组合物提供，其对铜以及铝基本上是非腐蚀性的，并且包含极性有机溶剂，羟基化胺和作为腐蚀抑制剂果糖。

公开(公告)号：US20110212865A1

公开(公告)日：2011-09-01

申请号：US12998499

申请日：2009-10-22

申请人： Seiji Inaoka

发明人： Seiji Inaoka

IPC分类号： C11D7/60

CPC分类号： C11D3/222 ,  C11D3/382 ,  C11D7/26 ,  C11D7/263 ,  C11D7/265 ,  C11D7/3218 ,  C11D7/3281 ,  C11D7/34 ,  C11D7/5009 ,  C11D7/5013 ,  C11D11/0047 ,  G03F7/425 ,  G03F7/426 ,  H01L21/02071

摘要： A microelectronic photoresist cleaning composition suitable for cleaning multi-metal microelectronic devices and to do so without any substantial or significant galvanic corrosion occurring when there is a subsequent rinsing step employing water.

摘要翻译： 适用于清洁多金属微电子器件的微电子光致抗蚀剂清洁组合物，并且当采用随后的采用水的冲洗步骤时，不会发生任何明显或显着的电偶腐蚀。

公开(公告)号：US07951764B2

公开(公告)日：2011-05-31

申请号：US11720084

申请日：2005-02-25

申请人： Seiji Inaoka

发明人： Seiji Inaoka

IPC分类号： G03F7/42 ,  C11D7/50

CPC分类号： G03F7/425 ,  C23F11/10 ,  G03F7/426

摘要： Back end photoresist strippers and cleaning compositions of this invention are provided by amino acid-free, non-aqueous cleaning compositions that are essentially non-corrosive toward copper as well as aluminum and that comprise at least one polar organic solvent, at least one hydroxylated organic amine, and at least one corrosion inhibitor compound with multiple hydroxyl functional groups that is a compound of the formula: T1-[(CR1R2)m—(CR3R4)n]p—(CR5R6)q-T2 where at least one of R1 and R2 OH and if one of R1 and R2 is not OH, it is selected from H, alkyl or alkoxy, m is a whole integer of 1 or greater, R3 and R4 are selected from H, alkyl or alkoxy, n is 0 or a greater whole positive integer, p is a whole integer of 1 or greater; at least one of R5 and R6 is OH and if one of R5 and R6 is not OH, it is selected from H, alkyl or alkoxy, q is a whole integer of 1 or greater; T1 and T2 are selected from H, alkyl, hydroxyalkyl, polyhydroxyalkyl, aminoalkyl, carbonylalkyl or amide groups or T1 and T2 may be connected forming a structure selected from an aliphatic cyclic or fused cyclic structure.

摘要翻译： 本发明的后端光致抗蚀剂剥离剂和清洁组合物由对氨基酸，非水性清洁组合物提供，其对铜以及铝基本上不具有腐蚀性，并且包含至少一种极性有机溶剂，至少一种羟基化有机溶剂 胺和至少一种具有多个羟基官能团的腐蚀抑制剂化合物，其为下式的化合物：T1 - [（CR1R2）m-（CR3R4）n] p - （CR5R6）q-T2，其中R1和 R 2 OH，如果R 1和R 2中的一个不是OH，则其选自H，烷基或烷氧基，m为1或更大的整数，R 3和R 4选自H，烷基或烷氧基，n为0或 更大的整数正整数，p是1或更大的整数; R 5和R 6中的至少一个是OH，如果R 5和R 6中的一个不是OH，则其选自H，烷基或烷氧基，q是1或更大的整数; T 1和T 2选自H，烷基，羟基烷基，多羟基烷基，氨基烷基，羰基烷基或酰胺基，或者可以连接T1和T2，形成选自脂族环或稠合环结构的结构。

公开(公告)号：US07825078B2

公开(公告)日：2010-11-02

申请号：US11630602

申请日：2005-02-01

申请人： Seiji Inaoka

发明人： Seiji Inaoka

IPC分类号： C11D7/26 ,  C11D7/32 ,  C11D7/34 ,  C11D7/50

CPC分类号： G03F7/425 ,  G03F7/426

摘要： Back end photoresist strippers and residue compositions are provided by non-aqueous compositions that are essentially non-corrosive toward copper as well as aluminum and that comprise a polar organic solvent, a hydroxylated amine, and as a corrosion inhibitor fructose.

摘要翻译： 后端光致抗蚀剂剥离剂和残余物组合物由非水性组合物提供，其对铜以及铝基本上是非腐蚀性的，并且包含极性有机溶剂，羟基化胺和作为腐蚀抑制剂果糖。