-
公开(公告)号：US06251999B1
公开(公告)日：2001-06-26
申请号：US09339394
申请日：1999-06-23
IPC分类号： C08F800
CPC分类号： C09D163/00 , C07F7/2224 , C08G59/42 , C08G59/685 , C08L2666/04 , C08L2666/18
摘要： A catalytic tin carboxylate adduct, which is useful as a catalyst in epoxy-acid coating compositions, is the reaction product of (A) a mono-, di-, or poly-carboxylic acid functional compound and (B) an organotin compound containing one to three aryl groups and at least one halogen or hydroxyl group attached to the tin atom. There is also provided an epoxy-acid coating composition, which incorporates this catalytic tin carboxylate adduct. The epoxy-acid coating composition is advantageous as an automotive topcoat, particularly as a clear coat composition because it exhibits good appearance, durability, stability and generates no, or extremely low levels of benzene during the curing process.
摘要翻译： 可用作环氧 - 酸性涂料组合物中的催化剂的催化锡羧酸盐加合物是（A）单羧酸官能化合物，二羧酸或多羧酸官能化合物与（B）含有一个或多个羧酸官能化合物的有机锡化合物的反应产物 至三个芳基和至少一个与锡原子连接的卤素或羟基。 还提供了一种环氧酸涂料组合物，其包含该催化性羧酸锡加合物。 环氧酸涂料组合物作为汽车面漆是特别有利的，特别是作为透明涂料组合物，因为它在固化过程中表现出良好的外观，耐久性，稳定性和不产生或极低的苯含量。
-
公开(公告)号：US06313224B1
公开(公告)日：2001-11-06
申请号：US09437891
申请日：1999-11-09
IPC分类号： C08L2304
CPC分类号： C09D201/00 , C09D7/47 , Y10T428/31692 , C08L2666/04
摘要： Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer. Comonomer (iii) can be present in the copolymer in an effective amount to give the copolymer a hydroxyl number is in the range of about 0 to 100.
摘要翻译： 可固化的涂料组合物包括液体或颗粒状可固化成膜树脂材料，流动控制剂，其是共聚物和任选的液体树脂材料的载体。 该共聚物来自烷基中至少一个含有1-20个碳原子的非氨基，非羟基和非酸官能的丙烯酸酯或甲基丙烯酸烷基酯，和（i）氨基官能的丙烯酸酯和甲基丙烯酸酯的官能单体 有效量使得共聚物的胺值在2-70范围内，或（ii）酸官能丙烯酸酯和甲基丙烯酸酯有效量，以使共聚物的酸值在10至30的范围内。另外， 在丙烯酸羟烷基酯和/或甲基丙烯酸羟烷基酯和/或己内酯多元醇单体的共聚物中可以存在官能单体（i）或（ii）另一功能性共聚单体（iii）。 共聚单体（iii）可以以有效的量存在于共聚物中，得到共聚物，羟值在约0-100范围内。
-
公开(公告)号：US6013733A
公开(公告)日：2000-01-11
申请号：US38107
申请日：1998-03-11
CPC分类号： C09D7/06 , C09D201/00 , Y10T428/31692
摘要： Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer. Comonomer (iii) can be present in the copolymer in an effective amount to give the copolymer a hydroxyl number is in the range of about 0 to 100.
摘要翻译： 可固化的涂料组合物包括液体或颗粒状可固化成膜树脂材料，流动控制剂，其是共聚物和任选的液体树脂材料的载体。 该共聚物来自烷基中至少一个含有1-20个碳原子的非氨基，非羟基和非酸官能的丙烯酸酯或甲基丙烯酸烷基酯，和（i）氨基官能的丙烯酸酯和甲基丙烯酸酯的官能单体 有效量使得共聚物的胺值在2-70范围内，或（ii）酸官能丙烯酸酯和甲基丙烯酸酯有效量，以使共聚物的酸值在10至30的范围内。另外， 在丙烯酸羟烷基酯和/或甲基丙烯酸羟烷基酯和/或己内酯多元醇单体的共聚物中可以存在官能单体（i）或（ii）另一功能性共聚单体（iii）。 共聚单体（iii）可以以有效的量存在于共聚物中，得到共聚物，羟值在约0-100范围内。
-
4.发明授权Thermosetting compositions containing carboxylic acid functional polymers prepared by atom transfer radical polymerization 失效含有通过原子转移自由基聚合制备的羧酸官能聚合物的热固性组合物公开(公告)号：US06265489B1
公开(公告)日：2001-07-24
申请号：US09375017
申请日：1999-08-16
申请人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
发明人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
IPC分类号： C08L3302
CPC分类号： C09D133/02 , C08L63/00 , C09D133/064 , C08L2666/14
摘要： A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) polycarboxylic acid functional polymer, and (b) epoxide functional crosslinking agent having at least two epoxide groups, e.g., triglycidyl isocyanurate (TGIC), is described. The polycarboxylic acid functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.0. The thermosetting compositions of the present invention have utility as powder coatings compositions.
摘要翻译： 描述了包含（a）多元羧酸官能聚合物和（b）具有至少两个环氧基团的环氧官能交联剂例如三缩水甘油基异氰脲酸酯（TGIC）的共反应固体，颗粒混合物的热固性组合物。 聚羧酸官能聚合物通过原子转移自由基聚合制备，并且具有良好的聚合物链结构和小于2.0的多分散指数。 本发明的热固性组合物可用作粉末涂料组合物。
-
公开(公告)号：US06670043B2
公开(公告)日：2003-12-30
申请号：US09992038
申请日：2001-11-16
申请人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
发明人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
IPC分类号： B32B2708
CPC分类号： C09D133/02 , C09D133/064 , Y10T428/31551 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , C08L2666/36
摘要： A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) beta-hydroxyalkylamide crosslinking agent, e.g., bis(N,N-di-2-hydroxyethyl)adipamide, and (b) polycarboxylic acid functional polymer, is described. The polycarboxylic acid functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.5. The thermosetting compositions of the present invention have utility as powder coatings compositions.
-
公开(公告)号：US06638578B2
公开(公告)日：2003-10-28
申请号：US09992037
申请日：2001-11-16
申请人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
发明人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
IPC分类号： C08J712
CPC分类号： C09D133/02 , C09D133/064 , Y10T428/31551 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , C08L2666/36
摘要： A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) beta-hydroxyalkylamide crosslinking agent, e.g., bis(N,N-di-2-hydroxyethyl)adipamide, and (b) polycarboxylic acid functional polymer, is described. The polycarboxylic acid functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.5. The thermosetting compositions of the present invention have utility as powder coatings compositions.
-
公开(公告)号：US06288173B1
公开(公告)日：2001-09-11
申请号：US09325227
申请日：1999-06-03
IPC分类号： C08F29700
CPC分类号： C08L53/00 , C08F293/005 , C09D153/00
摘要： Block copolymers containing at least two blocks are provided and comprise: (a) a first block containing residues of at least one first ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality, e.g., 2-ethylhexyl methacrylate, and a minor amount of at least one hydroxy functional ethylenically unsaturated radically polymerizable monomer, e.g., hydroxypropyl methacrylate; and (b) a second block containing residues of at least one second ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality, e.g., iso-butyl methacrylate, and a minor amount of at least one hydroxy functional ethylenically unsaturated radically polymerizable monomer. The calculated Tg of the second monomer of the block copolymer is at least 20° C. greater than the calculated Tg of the first monomer.
摘要翻译： 提供含有至少两个嵌段的嵌段共聚物，其包含：（a）含有至少一种不含羟基官能团的至少一种第一烯属不饱和自由基可聚合单体的残基的第一嵌段，例如甲基丙烯酸2-乙基己基酯和少量的 至少一种羟基官能的烯属不饱和自由基聚合单体，例如甲基丙烯酸羟丙酯; 和（b）含有至少一种不含羟基官能团的第二烯属不饱和自由基可聚合单体残基的第二嵌段，例如甲基丙烯酸异丁酯和少量至少一种羟基官能烯属不饱和自由基聚合单体。 嵌段共聚物的第二单体的计算的Tg比第一单体的计算的Tg大至少20℃。
-
8.发明授权Thermosetting compositions containing carboxylic acid functional polymers and epoxy functional polymers prepared by atom transfer radical polymerization 失效含有羧酸官能聚合物和通过原子转移自由基聚合制备的环氧官能聚合物的热固性组合物公开(公告)号：US06191225B1
公开(公告)日：2001-02-20
申请号：US09375016
申请日：1999-08-16
申请人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
发明人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
IPC分类号： C08G5942
CPC分类号： C08F2/38 , C08F2438/01 , C08G59/4246 , C09D5/031 , C09D163/00 , Y10T428/31678 , Y10T428/31692
摘要： A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) polycarboxylic acid functional polymer, and (b) epoxy functional polymer, is described. The polycarboxylic acid functional polymer and epoxy functional polymer are each prepared by atom transfer radical polymerization and have well defined polymer chain architecture and polydispersity index of less than 2.5. The thermosetting compositions of the present invention have utility as powder coatings compositions.
摘要翻译： 描述了包含（a）多元羧酸官能聚合物和（b）环氧官能聚合物的共反应固体，颗粒混合物的热固性组合物。 聚羧酸官能聚合物和环氧官能聚合物各自通过原子转移自由基聚合制备，并且具有明确的聚合物链结构和小于2.5的多分散指数。 本发明的热固性组合物可用作粉末涂料组合物。
-
9.发明授权公开(公告)号：US06863982B2
公开(公告)日：2005-03-08
申请号：US10269389
申请日：2002-10-11
申请人： Masayuki Nakajima , Charles M. Kania , Stephen G. McQuown , Karen S. Rechenberg , Susan A. Campbell , Kurt A. Humbert , Karen A. Barkac
发明人： Masayuki Nakajima , Charles M. Kania , Stephen G. McQuown , Karen S. Rechenberg , Susan A. Campbell , Kurt A. Humbert , Karen A. Barkac
CPC分类号： C09D163/00 , C08G59/304 , C08G59/3254 , C08G59/4284 , C09D5/036 , C09D7/63 , Y10T428/31511 , C08L2666/02
摘要： A curable film-forming composition of 5 to 95 weight percent (based on the total resin solids weight in the composition) of a crosslinking agent; 5 to 95 weight percent ot a polymer containing functional groups reactive with the crosslinking agent; and 0.01 to 15 weight percent of at least one additive selected from a reaction product of phosporous acid and: at least one diepoxide; at least one diepoxide and at least one anhydride; at least one diepoxide and at least one anhydride, chain extended with at least one diol; at least one monoepoxide and at least one anhydride, chain extended with at least one diepoxide; and mixtures thereof. The additives in the composition prevent thermal oxidation, minimizing visual effects (i.e., yellowing). A multi-component composite coating includes a base coat and a top coat which may be derived from the above curable film-forming composition.
摘要翻译： 交联剂为5〜95重量％（基于组合物中树脂固体重量的总量）的可固化成膜组合物; 5至95重量％的含有与交联剂反应的官能团的聚合物; 和0.01至15重量％的至少一种选自磷酸和：至少一种二环氧化物的反应产物的添加剂; 至少一种二环氧化物和至少一种酸酐; 至少一种二环氧化物和至少一种酸酐，链与至少一种二醇延伸; 至少一种单环氧化物和至少一种酸酐，链与至少一种二环氧化物延伸; 及其混合物。 组合物中的添加剂防止热氧化，使视觉效果最小化（即变黄）。 多组分复合涂层包括底涂层和可以由上述可固化成膜组合物衍生的面漆。
-
10.发明授权Thermosetting compositions containing hydroxy functional polymers prepared by atom transfer radical polymerization 失效含有通过原子转移自由基聚合制备的羟基官能聚合物的热固性组合物公开(公告)号：US06482475B2
公开(公告)日：2002-11-19
申请号：US09934385
申请日：2001-08-21
申请人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
发明人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
IPC分类号： C08G1862
CPC分类号： C08G18/8074 , C08F293/00 , C08F293/005 , C08F2438/01 , C08G18/6229 , C08G2150/20 , C09D153/00 , Y10T428/31504 , C08L2666/02
摘要： A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) capped polyisocyanate crosslinking agent, e.g., a trimer of 1-isocyanato-3,3,5 -trimethyl-5-isocyanatomethylcyclohexane capped with e-caprolactam or 1H-2,5-dimethyl pyrazole, and (b) hydroxy functional polymer, is described. The hydroxy functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.5. The thermosetting compositions of the present invention have utility as powder coatings compositions.
摘要翻译： 一种热固性组合物，其包含（a）封端的多异氰酸酯交联剂，例如用ε-己内酰胺或1H-2封端的1-异氰酸酯基-3,3,5-三甲基-5-异氰酸甲酯基环己烷的三聚体的可共反应的固体颗粒混合物 ，5-二甲基吡唑和（b）羟基官能聚合物。 羟基官能聚合物通过原子转移自由基聚合制备，并且具有明确的聚合物链结构和小于2.5的多分散指数。 本发明的热固性组合物可用作粉末涂料组合物。
-
-
-
-
-
-
-
-
-
搜索结果
35 条记录 (耗时 0.027 秒)
