Coating of film-forming resin and functional flow control copolymer
    1.
    发明授权
    Coating of film-forming resin and functional flow control copolymer 失效
    成膜树脂和功能流动控制共聚物的涂层

    公开(公告)号:US6013733A

    公开(公告)日:2000-01-11

    申请号:US38107

    申请日:1998-03-11

    摘要: Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer. Comonomer (iii) can be present in the copolymer in an effective amount to give the copolymer a hydroxyl number is in the range of about 0 to 100.

    摘要翻译: 可固化的涂料组合物包括液体或颗粒状可固化成膜树脂材料,流动控制剂,其是共聚物和任选的液体树脂材料的载体。 该共聚物来自烷基中至少一个含有1-20个碳原子的非氨基,非羟基和非​​酸官能的丙烯酸酯或甲基丙烯酸烷基酯,和(i)氨基官能的丙烯酸酯和甲基丙烯酸酯的官能单体 有效量使得共聚物的胺值在2-70范围内,或(ii)酸官能丙烯酸酯和甲基丙烯酸酯有效量,以使共聚物的酸值在10至30的范围内。另外, 在丙烯酸​​羟烷基酯和/或甲基丙烯酸羟烷基酯和/或己内酯多元醇单体的共聚物中可以存在官能单体(i)或(ii)另一功能性共聚单体(iii)。 共聚单体(iii)可以以有效的量存在于共聚物中,得到共聚物,羟值在约0-100范围内。

    Coating of film-forming resin and functional flow control copolymer
    2.
    发明授权
    Coating of film-forming resin and functional flow control copolymer 失效
    成膜树脂和功能流动控制共聚物的涂层

    公开(公告)号:US06313224B1

    公开(公告)日:2001-11-06

    申请号:US09437891

    申请日:1999-11-09

    IPC分类号: C08L2304

    摘要: Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer. Comonomer (iii) can be present in the copolymer in an effective amount to give the copolymer a hydroxyl number is in the range of about 0 to 100.

    摘要翻译: 可固化的涂料组合物包括液体或颗粒状可固化成膜树脂材料,流动控制剂,其是共聚物和任选的液体树脂材料的载体。 该共聚物来自烷基中至少一个含有1-20个碳原子的非氨基,非羟基和非​​酸官能的丙烯酸酯或甲基丙烯酸烷基酯,和(i)氨基官能的丙烯酸酯和甲基丙烯酸酯的官能单体 有效量使得共聚物的胺值在2-70范围内,或(ii)酸官能丙烯酸酯和甲基丙烯酸酯有效量,以使共聚物的酸值在10至30的范围内。另外, 在丙烯酸​​羟烷基酯和/或甲基丙烯酸羟烷基酯和/或己内酯多元醇单体的共聚物中可以存在官能单体(i)或(ii)另一功能性共聚单体(iii)。 共聚单体(iii)可以以有效的量存在于共聚物中,得到共聚物,羟值在约0-100范围内。

    Tin carboxylate catalysts for epoxy-acid coating compositions
    3.
    发明授权
    Tin carboxylate catalysts for epoxy-acid coating compositions 失效
    用于环氧酸涂料组合物的羧酸锡催化剂

    公开(公告)号:US06251999B1

    公开(公告)日:2001-06-26

    申请号:US09339394

    申请日:1999-06-23

    IPC分类号: C08F800

    摘要: A catalytic tin carboxylate adduct, which is useful as a catalyst in epoxy-acid coating compositions, is the reaction product of (A) a mono-, di-, or poly-carboxylic acid functional compound and (B) an organotin compound containing one to three aryl groups and at least one halogen or hydroxyl group attached to the tin atom. There is also provided an epoxy-acid coating composition, which incorporates this catalytic tin carboxylate adduct. The epoxy-acid coating composition is advantageous as an automotive topcoat, particularly as a clear coat composition because it exhibits good appearance, durability, stability and generates no, or extremely low levels of benzene during the curing process.

    摘要翻译: 可用作环氧 - 酸性涂料组合物中的催化剂的催化锡羧酸盐加合物是(A)单羧酸官能化合物,二羧酸或多羧酸官能化合物与(B)含有一个或多个羧酸官能化合物的有机锡化合物的反应产物 至三个芳基和至少一个与锡原子连接的卤素或羟基。 还提供了一种环氧酸涂料组合物,其包含该催化性羧酸锡加合物。 环氧酸涂料组合物作为汽车面漆是特别有利的,特别是作为透明涂料组合物,因为它在固化过程中表现出良好的外观,耐久性,稳定性和不产生或极低的苯含量。

    Precipitated silica product, dentifrices containing same, and processes
    4.
    发明授权
    Precipitated silica product, dentifrices containing same, and processes 有权
    沉淀二氧化硅产品,含有其的洁齿剂和方法

    公开(公告)号:US07255852B2

    公开(公告)日:2007-08-14

    申请号:US10677294

    申请日:2003-10-03

    IPC分类号: A61K8/00 A61Q11/00 C01B33/12

    摘要: Precipitated silica comprising porous silica particles having a cumulative surface area for all pores having diameters greater than 500 Å of less than 8 m2/g, as measured by mercury intrusion, and a percentage cetylpyridinium chloride (% CPC) Compatibility of greater than about 55%. The precipitated silica product is especially well-adapted for use in dentifrices containing cetylpyridinium chloride, which do not attach to the low surface area silica product in a meaningful level and thus remain available for antimicrobial action. Processes for making the silica product are also provided.

    摘要翻译: 含有多孔二氧化硅颗粒的沉淀二氧化硅颗粒,其具有通过汞侵入测量的直径大于500的小于500m 2的所有孔的累积表面积,和氯化十六烷基吡啶百分比(%CPC) )兼容性大于约55%。 沉淀二氧化硅产品特别适用于含有十六烷基吡啶氯化物的洁齿剂,其不能以有意义的水平附着在低表面积的二氧化硅产品上,因此可用于抗微生物作用。 还提供了制备二氧化硅产物的方法。

    Silica-coated boehmite composites suitable for dentifrices
    5.
    发明授权
    Silica-coated boehmite composites suitable for dentifrices 失效
    二氧化硅涂层勃姆石复合材料适用于洁齿剂

    公开(公告)号:US07166271B2

    公开(公告)日:2007-01-23

    申请号:US10695280

    申请日:2003-10-28

    摘要: Disclosed is a composite material comprising a boehmite substrate coated with a precipitated silica, the composite having a BET specific surface area of from 1 m2/g to 50 m2/g, such that the composite material has a % silica coating parameter value of about 5% to about 50%. Also disclosed is a dentifrice comprising this composite material. When included in a dentifrice composition, the composite material not only provides excellent abrasive and cleaning performance but also has compatibility with other ingredients used in dentifrice formulations, such as fluoride, flavors and cationic species.

    摘要翻译: 公开了一种复合材料,其包括涂覆有沉淀二氧化硅的勃姆石基材,所述复合材料的BET比表面积为1m 2 / g至50m 2 / g ,使得复合材料具有约5%至约50%的%二氧化硅涂层参数值。 还公开了包含该复合材料的洁齿剂。 当包含在洁齿剂组合物中时,复合材料不仅提供优异的磨料和清洁性能,而且还与洁齿剂制剂中使用的其它成分(例如氟化物,香料和阳离子物质)具有相容性。

    Multi-component pigment slurry and method of making the same
    7.
    发明授权
    Multi-component pigment slurry and method of making the same 失效
    多组分颜料浆料及其制备方法

    公开(公告)号:US06074474A

    公开(公告)日:2000-06-13

    申请号:US62353

    申请日:1998-04-17

    CPC分类号: C09D5/028 C09D17/004

    摘要: A multi-component pigment slurry which comprises at least 50% solids. The slurry is formulated to be admixed into paint and coating compositions to promote TiO.sub.2 extension. The slurry includes a structured pigment, a coarse particle size pigment, and a fine particle size pigment. The structured pigment comprises about 20% to about 55% of the slurry by dry weight and has a median particle size diameter of about 0.7.mu. to about 6.0.mu.. The coarse particle size pigment preferably comprises about 20% to about 60% by weight of the slurry and has a median particle size diameter of about 3.0.mu. to about 10.0.mu.. The fine particle size pigment preferably comprises up to about 50% by dry weight of the slurry and has a median particle size diameter of about 0.2.mu. to about 1.0.mu..

    摘要翻译: 包含至少50%固体的多组分颜料浆料。 将浆料配制成混合到涂料和涂料组合物中以促进TiO 2延伸。 浆料包括结构颜料,粗粒度颜料和细粒度颜料。 结构化颜料包含干重约20%至约55%的浆料,其中值粒径直径约为0.7μm至约6.0μm。 粗颗粒颜料优选占浆料重量的约20%至约60%,其中值粒径直径约为3.0μm至约10.0μm。 细粒度颜料优选包含至多约50重量%的浆料,并且具有约0.2μm至约1.0μm的中值粒径直径。