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    Oxopiperazinyl derivatives and light stabilized compositions
    3.
    发明授权
    Oxopiperazinyl derivatives and light stabilized compositions 失效
    氧哌嗪衍生物和光稳定组合物

    公开(公告)号：US06642383B2

    公开(公告)日：2003-11-04

    申请号：US09855905

    申请日：2001-05-15

    申请人： Dario Lazzari ,  Graziano Zagnoni ,  Mirko Rossi ,  Alessandro Zedda ,  Valerio Borzatta ,  Stephen Mark Andrews

    发明人： Dario Lazzari ,  Graziano Zagnoni ,  Mirko Rossi ,  Alessandro Zedda ,  Valerio Borzatta ,  Stephen Mark Andrews

    IPC分类号： C07D24106

    CPC分类号： G03C1/8155 ,  C07D241/08 ,  C07D403/14 ,  C07D405/12 ,  C07D409/14 ,  C08G63/6856 ,  C08G73/0633 ,  C08K5/3462

    摘要： Compounds of the formula (I) wherein p is zero or 1; q and r, independently of each other, are an integer from 1 to 6; and s is a number ranging from 1 to 8; X is —O— or, when p is 1, X is also a group Rw, Rx, Ry and Rz are, independently of each other, C1-C18alkyl, C5-C12cycloalkyl or C1-C5hydroxyalkyl, especially methyl; R1 is hydrogen; C1-C18alkyl; oxyl; OH; CH2CN; C1-C18alkoxy; C5-C12cycloalkoxy; C3-C8alkenyl; C3-C8alkynyl; C7-C12phenylalkyl; C7-C15phenylalkyl, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; C7-C15phenylalkoxy; C7-C15phenylalkoxy, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; or R1 is C1-C8alkanoyl; C3-C5alkenoyl; C1-C18alkanoyloxy; glycidyl; or a group —CH2CH(OH)—G, in which G is hydrogen, methyl or phenyl; R2 is hydrogen, C1-C8alkyl, C5-C12cycloalkyl or C1-C4hydroxyalkyl; R3, R4, R5 independently of each other are hydrogen, C1-C8alkyl or C5-C12cycloalkyl; and W and other residues are as described in claim 1, are effective stabilizers for organic materials, for example thermoplastic organic polymers, coating compositions or photographic materials.

    摘要翻译： 式（I）的化合物，其中p为0或1; q和r彼此独立地是1至6的整数; 且为1至8的数; X为-O-或当p为1时，X为基团R w，R x，R y和R z彼此独立地为C 1 -C 18烷基，C 5 -C 12环烷基或C 1 -C 18烷基， C5羟烷基，特别是甲基; R1是氢; C1-C18烷基; 氧基 哦; CH2CN; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C7-C12苯基烷基; C7-C15苯基烷基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; C7-C15苯基烷氧基; C7-C15苯基烷氧基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; 或R 1为C 1 -C 8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; 缩水甘油基 或基团-CH 2 CH（OH）-G，其中G是氢，甲基或苯基; R 2是氢，C 1 -C 8烷基，C 5 -C 12环烷基或C 1 -C 4羟烷基; R 3，R 4，R 5彼此独立地是氢，C 1 -C 1-8烷基或C 5 -C 12环烷基; 和W和其它残余物如权利要求1所述，是有机材料的有效稳定剂，例如热塑性有机聚合物，涂料组合物或照相材料。

    Compositions stabilized by dioxopiperazinyl derivatives
    4.
    发明授权
    Compositions stabilized by dioxopiperazinyl derivatives 失效
    由二氧代哌嗪衍生物稳定的组合物

    公开(公告)号：US06762226B2

    公开(公告)日：2004-07-13

    申请号：US10272193

    申请日：2002-10-15

    申请人： Alessandro Zedda ,  Graziano Zagnoni ,  Massimiliano Sala ,  Dario Lazzari ,  Stephen Mark Andrews

    发明人： Alessandro Zedda ,  Graziano Zagnoni ,  Massimiliano Sala ,  Dario Lazzari ,  Stephen Mark Andrews

    IPC分类号： C07D40304

    CPC分类号： C08L55/02 ,  C08K5/34926 ,  C08L59/00 ,  C08L59/02 ,  C08L69/00 ,  C08L2666/14 ,  C08L2666/02

    摘要： Polyoxymethylene, blends of polycarbonate with acrylonitrile-butadiene-styrene terpolymer, and coatings based on a functional acrylate resin and a crosslinking agent, which are stabilized by addition of a compound of the formula I wherein s is from the range 1 to 8; R1, R2, R3 and R4, independently of each other, are C1-C4alkyl, or R1 and R2 or R3 and R4, together with the carbon atom to which they are bound, form a cyclopentyl or cyclohexyl ring; R5 is hydrogen; C1-C18alkyl; oxyl; OH; CH2CN; C1-C18alkoxy; C5-C12cycloalkoxy; C3-C8alkenyl; C3-C8alkynyl; C7-C12phenylalkyl; C7-C15phenylalkyl, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; C7-C15phenylalkoxy; C7-C15phenylalkoxy, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; or R5 is C1-C8alkanoyl; C3-C5alkenoyl; C1-C18alkanoyloxy; glycidyl; or a group —CH2CH(OH)-G, in which G is hydrogen, methyl or phenyl; and A is as described in claim 1, show a good resistance against harmful effects of light, oxygen and heat.

    摘要翻译： 聚甲醛，聚碳酸酯与丙烯腈 - 丁二烯 - 苯乙烯三元共聚物的共混物，以及基于官能丙烯酸酯树脂和交联剂的涂料，其通过加入式I化合物而得到稳定，其中s为1至8; R1，R2 R 3和R 4彼此独立地是C 1 -C 4烷基，或者R 1和R 2或R 3和R 4与它们所连接的碳原子一起形成环戊基或环己基环; R 5是氢; C1-C18烷基; 氧基 哦; CH2CN; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C7-C12苯基烷基; C7-C15苯基烷基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; C7-C15苯基烷氧基; C7-C15苯基烷氧基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; 或R 5为C 1 -C 8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; 缩水甘油基 或基团-CH 2 CH（OH）-G，其中G是氢，甲基或苯基; 和A如权利要求1所述，显示出对光，氧和热的有害影响的良好抵抗性。

    Piperazinone derivatives
    5.
    发明授权
    Piperazinone derivatives 失效
    哌嗪酮衍生物

    公开(公告)号：US07109259B2

    公开(公告)日：2006-09-19

    申请号：US10138986

    申请日：2002-05-03

    申请人： Dario Lazzari ,  Mirko Rossi ,  Graziano Zagnoni ,  Alessandro Zedda ,  Stephen Mark Andrews

    发明人： Dario Lazzari ,  Mirko Rossi ,  Graziano Zagnoni ,  Alessandro Zedda ,  Stephen Mark Andrews

    IPC分类号： C08K5/3452 ,  C08K5/3492 ,  C07D403/14

    CPC分类号： C07D241/06 ,  C07D403/12 ,  C07D403/14 ,  C08K5/34926 ,  G03C1/815 ,  G03C1/8155 ,  G03C7/39244 ,  C08L59/00

    摘要： A compound of the formula (I) wherein n is preferably 3; G1, G2, G3 and G4 are independently of one another e.g. C1–C4alkyl; A1 is e.g. hydrogen or methyl; A2 is e.g. methylene; A3′ and A3″ are e.g. C1–C4alkyl; A4 is e.g. C1–C8alkyl; Y is e.g. a group of the formula (IV)  wherein R1 is e.g. hydrogen or methyl, R2 is e.g. methylene, R3′ and R3″ are e.g. C1–C4alkyl and R4 is e.g. hydrogen or C1–C8alkyl; and Z is e.g. a group of the formula (VI)  with A10′ and A10″ being independently of one another e.g. hydrogen or C1–C4alkyl and A11′ and A11″ being independently of one another e.g. C2–C6alkylene, is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.

    摘要翻译： 式（I）的化合物，其中n优选为3; G 1，G 2，G 3和G 4各自彼此独立地是例如不同的。 C 1 -C 4烷基; 例如，A 1＆lt; 1＆gt; 氢或甲基; A 是例如。 亚甲基 A 3＆lt; 3＆gt;和＆lt; 3＆gt; C 1 -C 4烷基; A 4是例如。 C 1 -C 8烷基; Y是例如 其中R 1为例如式（Ⅳ）的基团。 氢或甲基，R 2是例如。 亚甲基，R 3'和R 3“是例如。 C 1 -C 4烷基和R 4是例如C 1 -C 4烷基。 氢或C 1 -C 8烷基; Z是例如 具有A 10'和A 10“的式（VI）的基团彼此独立地是例如。 氢或C 1 -C 4烷基，A 11和A 11'彼此独立地为氢或C 1 -C 4烷基。 例如 C 2 -C 6亚烷基可用于稳定有机材料以防止由光，热或氧化引起的降解。

    Process for preparing a stabilized polyester
    6.
    发明授权
    Process for preparing a stabilized polyester 失效
    制备稳定聚酯的方法

    公开(公告)号：US07514526B2

    公开(公告)日：2009-04-07

    申请号：US11348664

    申请日：2006-02-07

    申请人： Dirk Simon ,  Dario Lazzari ,  Stephen Mark Andrews ,  Heinz Herbst

    发明人： Dirk Simon ,  Dario Lazzari ,  Stephen Mark Andrews ,  Heinz Herbst

    IPC分类号： C08G63/02 ,  C08G63/16 ,  C08G63/18 ,  C08G63/44 ,  C08G63/68 ,  C08G69/00 ,  C08G18/42 ,  C08G18/48

    CPC分类号： C08K5/0008 ,  C08G63/20 ,  C08L67/02 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L33/00

    摘要： The present invention discloses a process for the preparation of a stabilized polyester that is low in the generation of aldehydes which comprises reacting one or more diacids with one or more diols in an esterification process, and/or one or more diesters with one or more diols in a transesterification process in the presence of an effective amount of a stabilizer selected from the group consisting of (a) a polyhydric alcohol which is for example poly(ethylene-co-vinyl alcohol), poly(styrene-co-allyl alcohol), maltitol, isomalt, sorbitol, xylitol, sucrose, mucic acid dibutylester, mucic acid di(phenyl-1-ethyl)ester, pentaerythritol or dipentaerythritol; (b) a compound of the formula II which is for example di-iso-octyl-phosphinic acid; (c) a sterically hindered amine which is for example Tinuvin 123 or Tinuvin 622; (d) a polyacrylamide, an anionic acrylic polymer or a cationic acrylamide copolymer; or (e) a hydroxylamine and/or a nitrone. Such polyesters, for example PET, when extrusion compounded exhibit a lower residual acetaldehyde content than does PET alone when similarly treated. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, pharmaceuticals, beverages and most especially water.

    摘要翻译： 本发明公开了一种制备稳定的聚酯的方法，所述聚酯的生成量低，其包括在酯化过程中使一种或多种二酸与一种或多种二醇反应，和/或一种或多种二酯与一种或多种二醇 在有效量的选自以下的稳定剂的酯交换过程中：（a）多元醇，例如聚（乙烯 - 共 - 乙烯醇），聚（苯乙烯 - 共 - 烯丙醇）， 麦芽糖醇，异麦芽酮糖醇，山梨糖醇，木糖醇，蔗糖，粘酸二丁酯，粘酸二（苯基-1-乙基）酯，季戊四醇或二季戊四醇; （b）式II化合物，其为例如二异辛基次膦酸; （c）空间位阻胺，例如Tinuvin 123或Tinuvin 622; （d）聚丙烯酰胺，阴离子丙烯酸类聚合物或阳离子丙烯酰胺共聚物; 或（e）羟胺和/或硝酮。 当类似处理时，当挤出复合时，这种聚酯，例如PET显示出比单独的PET更低的残留乙醛含量。 本发明涉及用于制造瓶子或容器的任何聚酯，其又用于储存消费材料，特别是食品，药物，饮料，特别是水。