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    Room temperature curable polymers and precursors thereof
    2.
    发明授权
    Room temperature curable polymers and precursors thereof 有权
    室温固化聚合物及其前体

    公开(公告)号：US08178645B2

    公开(公告)日：2012-05-15

    申请号：US12668609

    申请日：2008-07-10

    申请人： Paul J. Popa ,  Zenon Lysenko ,  David A. Babb ,  William A. Koonce ,  Gary E. Spilman

    发明人： Paul J. Popa ,  Zenon Lysenko ,  David A. Babb ,  William A. Koonce ,  Gary E. Spilman

    IPC分类号： C08G18/42 ,  C08G63/00 ,  C08G18/71

    CPC分类号： C08G18/4288 ,  C08G18/4269 ,  C08G18/4277 ,  C08G18/718 ,  C08G2190/00 ,  C09J175/06

    摘要： A polyester polyol, referred to hereinafter as a MHMS polyol comprises fatty acid based mer units wherein at least about 80 weight percent of the fatty acid based mer units are from methyl 9 (10) hydroxymethylstearate, or is prepared from an oil having fatty acids or fatty acid esters which are at least about 80 weight percent oleic acid or esters thereof and which has an average hydroxyl functionality of from 1.5 to 4. A reaction product, referred to herein after as MHMS alkoxysilane prepolymer, is produced from at least one such MHMS polyol and at least one isocyanate functional silane. This prepolymer is moisture cured to form a silylated MHMS polymer.

    摘要翻译： 以下称为MHMS多元醇的聚酯多元醇包括脂肪酸基mer单元，其中至少约80重量％的脂肪酸​​基mer单元为9（10）羟甲基硬脂酸甲酯，或由具有脂肪酸或 至少约80重量％的油酸或其酯，并且其平均羟基官能度为1.5-4的脂肪酸酯。本文中称为MHMS烷氧基硅烷预聚物的反应产物由至少一种这样的MHMS 多元醇和至少一种异氰酸酯官能的硅烷。 将该预聚物水分固化以形成甲硅烷基化的MHMS聚合物。

    POLYETHER NATURAL OIL POLYOLS AND POLYMERS THEREOF
    4.
    发明申请
    POLYETHER NATURAL OIL POLYOLS AND POLYMERS THEREOF 审中-公开
    聚醚天然油多元醇及其聚合物

    公开(公告)号：US20110015293A1

    公开(公告)日：2011-01-20

    申请号：US12933293

    申请日：2009-03-20

    申请人： Hongming Ma ,  Jorge Jimenez ,  Dwight D. Latham ,  David A. Babb ,  Imran Munshi ,  Christopher Noakes

    发明人： Hongming Ma ,  Jorge Jimenez ,  Dwight D. Latham ,  David A. Babb ,  Imran Munshi ,  Christopher Noakes

    IPC分类号： C08J9/00 ,  C07C59/147 ,  C08G18/72

    CPC分类号： C08G18/4804 ,  C08G18/4891 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

    摘要： A polyether NOP comprises at least two natural oil moieties separated by a molecular structure having at least about 19 ether groups or by a polyether molecular structure having an equivalent weight of at least about 480, said polyol referred to hereinafter as a polyether NOP. The polyether NOP is preferably prepared by a process comprising admixing at least one polyether initiator having an equivalent weight of at least about 480 or at least about 19 ether groups per active hydrogen group with at least one natural oil or derivative thereof under reaction conditions such that at least one polyether NOP is formed. The invention includes reaction products of the polyether NOP or combinations thereof, optionally and preferably in admixture with at least one other polyol which preferably includes at least one polyether polyol and at least one monomer reactive therewith, preferably at least one polyisocyanate to form a polyurethane, preferably in the form of a foam, especially a high resilience foam. The invention includes articles comprising at least one polyether NOP, at least one polymer thereof, or at least one foam thereof.

    摘要翻译： 聚醚NOP包含至少两个通过具有至少约19个醚基团的分子结构分开的天然油部分，或通过当量为至少约480的聚醚分子结构，所述多元醇在下文中称为聚醚NOP。 聚醚NOP优选通过包括在反应条件下将每个活性氢基团当量至少约480或至少约19个醚基团的至少一种聚醚引发剂与至少一种天然油或其衍生物混合的方法制备，使得 形成至少一种聚醚NOP。 本发明包括聚醚NOP或其组合的反应产物，任选和优选与至少一种其它多元醇混合，其中多元醇优选包括至少一种聚醚多元醇和至少一种与其反应的单体，优选至少一种多异氰酸酯以形成聚氨酯， 优选为泡沫形式，特别是高弹性泡沫。 本发明包括包含至少一种聚醚NOP，至少一种聚合物或其至少一种泡沫的制品。

    Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom
    6.
    发明授权
    Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom 失效
    包括羟基或静止反应性官能团的膨胀的阴离子化合物及其催化剂活化剂

    公开(公告)号：US06627573B2

    公开(公告)日：2003-09-30

    申请号：US09904422

    申请日：2001-07-12

    申请人： David A. Babb ,  Richard E. Campbell, Jr. ,  David R. Neithamer ,  Grant B. Jacobsen ,  Edmund M. Carnahan

    发明人： David A. Babb ,  Richard E. Campbell, Jr. ,  David R. Neithamer ,  Grant B. Jacobsen ,  Edmund M. Carnahan

    IPC分类号： B01J3000

    CPC分类号： C08F10/00 ,  C07F5/027 ,  C07F5/062 ,  C07F5/066 ,  C07F7/0803 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F210/16 ,  C08F4/61908 ,  C08F4/65908 ,  C08F210/14 ,  C08F2500/12

    摘要： A compound useful as a cocatalyst or cocatalyst component, especially for use as an addition polymerization catalyst compound, corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, said A* having a charge +a, Z* is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites; J* independently each occurrence is a Lewis acid of from 1 to 80, preferably 1 to 60 atoms, not counting hydrogen atoms, coordinated to at least one Lewis base site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is a number from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionality.

    摘要翻译： 用作助催化剂或助催化剂组分的化合物，特别是用作加成聚合催化剂化合物，其对应于下式：其中：A *是不计氢原子的1至80个，优选1至60个原子的阳离子，所述化合物 A *具有电荷+ a，Z *是1至50个，优选1至30个原子的阴离子基团，不计算氢原子，进一步含有两个或更多个路易斯碱基位点; J *各自独立地为路易斯酸 1至80个，优选1至60个原子，不计数氢原子，与Z *的至少一个路易斯碱碱基位点配位，并且任选地两个或多个这样的J *基团可以连接在具有多个路易斯酸官能团的部分中， j是2至12的数字，a，b，c和d是1至3的整数，条件是axb等于cxd，进一步提供A *，Z *或J *中的一个或多个包括 羟基或含有静止反应性官能团的极性基团。

    Process for preparation of fluorinated carbonyl compounds
    7.
    发明授权
    Process for preparation of fluorinated carbonyl compounds 失效
    氟化羰基化合物的制备方法

    公开(公告)号：US5206422A

    公开(公告)日：1993-04-27

    申请号：US775326

    申请日：1991-10-11

    申请人： David A. Babb

    发明人： David A. Babb

    IPC分类号： C07C51/58 ,  C07C67/313

    CPC分类号： C07C51/58 ,  C07C67/313

    摘要： A process for the preparation of fluorinated carbonyl compounds from a fluorinated methyl or ethyl ether using tin tetrachloride as a catalyst. The fluorinated ether is contacted with the tin tetrachloride catalyst at a temperature between 0.degree. C. and 250.degree. C.

    摘要翻译： 一种使用四氯化锡作为催化剂由氟化甲基或乙醚制备氟化羰基化合物的方法。 氟化醚与四氯化锡催化剂在0℃至250℃的温度下接触。

    Perfluorovinyl compounds
    9.
    发明授权
    Perfluorovinyl compounds 失效
    全氟乙烯基化合物

    公开(公告)号：US5023380A

    公开(公告)日：1991-06-11

    申请号：US364665

    申请日：1989-06-09

    申请人： David A. Babb ,  Bobby R. Ezzell ,  Katherine S. Clement

    发明人： David A. Babb ,  Bobby R. Ezzell ,  Katherine S. Clement

    IPC分类号： C07C41/01 ,  C07C22/08 ,  C07C41/18 ,  C07C43/17 ,  C07C43/174 ,  C07C43/225 ,  C07C65/21 ,  C07C69/92 ,  C07C323/20 ,  C07C391/00 ,  C07C391/02 ,  C07F5/02 ,  C07F7/12 ,  C07F9/50 ,  C08F16/14 ,  C08F16/24 ,  C08F28/00 ,  C08F28/02 ,  C08F30/04

    CPC分类号： C07C43/17 ,  C07C22/08 ,  C07C43/225 ,  C07C65/21 ,  C07C69/92 ,  C07C2103/18

    摘要： Compounds have a structure represented by Formula I:CF.sub.2 =CF-X-R-(X-CF=CF.sub.2).sub.mwherein R represents an unsubstituted or inertly substituted hydrocarbyl group; each X is independently selected from the group consisting of groups having at least one non-carbon atom between R and --CF=CF.sub.2 ; and m is an integer of from 1 to about 3. Polymers formed from such compounds are also prepared. The compounds are preferably prepared by a method by a process comprising the steps of:(a) forming a salt having anion corresponding to a compound of Formula II:HX--R--(XH).sub.m ; wherein X, R and m are as defined for Formula I;(b) reacting the salt with a 1,2-dihalo-1,1,2, 2-tetrafluoroethane wherein the halo groups are iodine, bromine, chlorine or mixtures thereof, at least one halo group being bromine or iodine, to form a compound of Formula III:Z-CF.sub.2 CF.sub.2 -X-R-(X-CF.sub.2 CF.sub.2 - Z).sub.m wherein X, R and m are as defined for Formula I and each Z is independently iodine or bromine;(c) eliminating the halogen atoms represented by Z to form the perfluorovinyl compound represented by Formula I.

    摘要翻译： 化合物具有由式I表示的结构：CF 2 = CF-X-R-（X-CF = CF 2）m其中R表示未取代或惰性取代的烃基; 每个X独立地选自具有至少一个R和-CF = CF 2之间的非碳原子的基团; 并且m为1至约3的整数。还制备由这些化合物形成的聚合物。 化合物优选通过包括以下步骤的方法的方法制备：（a）形成具有对应于式II化合物的阴离子的盐：HX-R-（XH）m; 其中X，R和m如式I所定义; （b）使盐与1,2-二卤代-1,1,2,2-四氟乙烷反应，其中卤素是碘，溴，氯或其混合物，至少一个卤素基团是溴或碘，以形成 式III化合物：Z-CF 2 CF 2 -XR-（X-CF 2 CF 2 - Z）m其中X，R和m如式I所定义，各Z独立地为碘或溴; （c）除去由Z表示的卤素原子，形成由式I表示的全氟乙烯基化合物。

    ISOCYANATE TRIMERISATION CATALYST SYSTEM, A PRECURSOR FORMULATION, A PROCESS FOR TRIMERISING ISOCYANATES, RIGID POLYISOCYANURATE/POLYURETHANE FOAMS MADE THEREFROM, AND A PROCESS FOR MAKING SUCH FOAMS
    10.
    发明申请
    ISOCYANATE TRIMERISATION CATALYST SYSTEM, A PRECURSOR FORMULATION, A PROCESS FOR TRIMERISING ISOCYANATES, RIGID POLYISOCYANURATE/POLYURETHANE FOAMS MADE THEREFROM, AND A PROCESS FOR MAKING SUCH FOAMS 审中-公开

    公开(公告)号：US20170283541A1

    公开(公告)日：2017-10-05

    申请号：US15621171

    申请日：2017-06-13

    申请人： Phillip S. Athey ,  Nathan Wilmot ,  Richard J. Keaton ,  David A. Babb ,  Cecile Boyer ,  Timothy A. Morley

    发明人： Phillip S. Athey ,  Nathan Wilmot ,  Richard J. Keaton ,  David A. Babb ,  Cecile Boyer ,  Timothy A. Morley

    IPC分类号： C08G18/02 ,  C08G18/18 ,  C08G18/09

    CPC分类号： C08G18/022 ,  C08G18/092 ,  C08G18/168 ,  C08G18/1875 ,  C08G2101/0025 ,  C08G2105/02

    摘要： The instant invention provides an isocyanate trimerisation catalyst system, a precursor formulation, a process for trimerising isocyanates, rigid foams made therefrom, and a process for making such foams. The trimerisation catalyst system comprises: (a) a phosphatrane cation; and (b) an isocyanate-trimer inducing anion; wherein said trimerisation catalyst system has a trimerisation activation temperature in the range of equal to or less than 73° C. The precursor formulation comprises (1) at least 25 percent by weight of polyol, based on the weight of the precursor formulation; (2) less than 15 percent by weight of a trimerisation catalyst system, based on the weight of the precursor formulation, comprising; (a) a phosphatrane cation; and (c) an isocyanate-trimer inducing anion; wherein said trimerisation catalyst system has a trimerisation activation temperature in the range of equal to or less than 73° C.; and (4) optionally one or more surfactants, one or more flame retardants, water, one or more antioxidants, one or more auxiliary blowing agents, one or more urethane catalysts, one or more auxiliary trimerisation catalysts, or combinations thereof. The process for trimerisation of isocyanates comprises the steps of: (1) providing one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof; (2) providing a trimerisation catalyst system comprising; (a) an phosphatrane cation; and (b) an isocyanate-trimer inducing anion; (c) wherein said trimerisation catalyst system has a trimerisation activation temperature in the range of equal to or less than 73° C.; (3) trimerising said one or more monomers in the presence of said trimerisation catalyst; (4) thereby forming an isocyanurate ring. The process for making the PIR foam comprises the steps of: (1) providing one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof; (2) providing polyol; (3) providing a trimerisation catalyst system comprising; (a) a phosphatrane cation; and (b) an isocyanate-trimer inducing anion; wherein said trimerisation catalyst system has a trimerisation activation temperature in the range of equal to or less than 73° C.; and (4) optionally providing one or more surfactants, one or more flame retardants, water, one or more antioxidants, one or more auxiliary blowing agents, one or more urethane catalysts, one or more auxiliary trimerisation catalysts, or combinations thereof; (5) contacting said one or more monomers, and said polyol, and optionally said one or more surfactants, and optionally said one or more flame retardants, and optionally said water, and optionally said one or more antioxidants, and optionally said one or more auxiliary blowing agents in the presence of said trimerisation catalyst system and optionally said one or more urethane catalysts, and optionally said one or more auxiliary trimerisation catalysts; (6) thereby forming said polyisocyanurate/polyurethane rigid foam. The PIR foam comprises the reaction product of one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof with polyol in the presence of a trimerisation catalyst system comprising a phosphatrane cation, and an isocyanate-trimer inducing anion, and optionally one or more surfactants, optionally one or more flame retardants, optionally water, optionally one or more antioxidants, optionally one or more auxiliary blowing agents, optionally one or more additional urethane catalysts, and optionally one or more auxiliary trimerisation catalysts, or optionally combinations thereof, wherein the trimerisation catalyst system has a trimerisation activation temperature in the range of equal to or less than 73° C.The PIR foam comprises the reaction product of one or more monomers selected from the group consisting of an isocyanate, a diisocyanate, a triisocyanate, oligomeric isocyanate, a salt of any thereof, and a mixture of any thereof with polyol in the presence of a trimerisation catalyst system comprising a phosphatrane cation, and an isocyanate-trimer inducing anion, and optionally one or more surfactants, optionally one or more flame retardants, optionally water, optionally one or more antioxidants, optionally one or more auxiliary blowing agents, optionally one or more additional polyurethane catalysts, and optionally one or more auxiliary trimerisation catalysts, or optionally combinations thereof, wherein the PIR foam has a polyisocyanurate trimer ratio (Abs1410/Abs1595) of at least 5 at a depth of 12 mm from the rising surface of the rigid foam, measured via ATR-FTIR spectroscopy.