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公开(公告)号：US5112795A
公开(公告)日：1992-05-12
申请号：US596228
申请日：1990-10-12
IPC分类号： B01J23/50 , B01J23/66 , B01J23/68 , B01J23/89 , B01J37/02 , C07D301/10 , C07D303/04
CPC分类号： B01J23/66 , C07D301/10 , Y02P20/52
摘要： A process for preparing a supported silver catalyst for the production of alkylene oxide by the vapor phase oxidation of alkylene with an oxygen-containing gas is disclosed and comprises contacting a silver-contacting support with a solution comprising a metal-containing promoter other than alkali metals or alkaline earth metals. The solution is chosen so that the metal-containing promoter has an increased affinity to the silver-containing carrier relative to its affinity to the carrier without silver. Alkene epoxidation catalysts and alkene epoxidation processes are also disclosed.
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2.发明授权Catalytic system for epoxidation of alkenes employing low sodium catalyst supports 失效使用低钠催化剂载体的烯烃的环氧化催化体系
公开(公告)号：US4994587A
公开(公告)日：1991-02-19
申请号：US404560
申请日：1989-09-08
IPC分类号： B01J23/66 , C07D301/10
CPC分类号： B01J23/66 , C07D301/10
摘要： A process is provided for the epoxidation of an alkene in the presence of an oxygen-containing gas which comprises contacting the alkene and the oxygen-containing gas under epoxidation conditions in the presence of at least one efficiency-enhancing gaseous member of a redox-half reaction pair and a solid catalyst, the catalyst comprising a catalytically-effective amount of silver on a solid support and an efficiency-enhancing amount of at least one efficiency-enhancing salt of a member of a redox-half reaction pair, the support having less than about 50 ppm, by weight, of leachable sodium.
摘要翻译： 提供了一种在含氧气体存在下烯烃环氧化的方法，该方法包括在环氧化条件下使烯烃和含氧气体在氧化还原一半的至少一种效能增强气体组分存在下接触 反应对和固体催化剂，所述催化剂在固体载体上包含催化有效量的银，以及提高氧化还原半反应对成员的至少一种效率增强盐的效率提高量，所述载体具有较少 超过约50ppm重量的可浸出钠。
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公开(公告)号：US4134859A
公开(公告)日：1979-01-16
申请号：US779786
申请日：1977-03-21
CPC分类号： C07C45/35 , B01J23/8876 , B01J23/8993 , C07C45/34 , C07C51/252 , B01J2523/00
摘要： A novel catalyst which is devoid of potassium and comprising the elements Mo, Bi, Fe, Si, Ni and/or Co and Ru and/or Sb, and, optionally Cl, is provided for oxidizing alpha,beta-unsaturated monoolefins in the vapor phase with molecular oxygen to produce the corresponding alpha,beta-unsaturated carboxyolic acid and alpha,beta-unsaturated aldehyde. The catalyst can also be used in corresponding ammoxidation reactions.
摘要翻译： 提供一种不含钾并包含元素Mo，Bi，Fe，Si，Ni和/或Co和Ru和/或Sb以及任选Cl的新型催化剂，用于氧化蒸气中的α，β-不饱和单烯烃 与分子氧相产生相应的α，β-不饱和羧酸和α，β-不饱和醛。 该催化剂也可用于相应的氨氧化反应。
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4.发明申请ALUMINA CARRIERS AND SILVER-BASED CATALYSTS FOR THE PRODUCTION OF ALKYLENE OXIDES 审中-公开氧化铝载体和用于生产烷基氧化物的银基催化剂公开(公告)号：US20110082029A1
公开(公告)日：2011-04-07
申请号：US12947446
申请日：2010-11-16
申请人： Erlind M. Thorsteinson , Madan M. Bhasin , Albert Cheng-Yu Liu , Juliana G. Serafin , Seyed R. Seyedmonir , Hwaili Soo
发明人： Erlind M. Thorsteinson , Madan M. Bhasin , Albert Cheng-Yu Liu , Juliana G. Serafin , Seyed R. Seyedmonir , Hwaili Soo
IPC分类号： B01J27/055 , B01J32/00 , B01J37/08 , B01J27/25
CPC分类号： B01J23/50 , B01J21/04 , B01J21/12 , B01J23/66 , B01J23/688 , B01J37/0205 , B01J37/0207 , B01J37/06
摘要： An improved carrier useful for preparing a catalyst having excellent catalytic performance when used in the production of alkylene oxide, such as ethylene oxide. The carrier is obtained by a) impregnating a preformed alpha-alumina carrier with at least one modifier selected from among alkali metal silicates and alkaline earth metal silicates, b) drying the impregnated carrier; and c) calcining dried carrier. The carrier may optionally be washed, prior to being impregnated by conventional catalytic material and/or promoter material.
摘要翻译： 一种改进的载体，可用于制备当用于生产环氧烷烃如环氧乙烷时具有优异催化性能的催化剂。 载体通过以下方法获得：a）用至少一种选自碱金属硅酸盐和碱土金属硅酸盐的改性剂浸渍预制的α-氧化铝载体，b）干燥浸渍的载体; 和c）煅烧干燥的载体。 在用常规催化材料和/或促进剂材料浸渍之前，载体可以任选地被洗涤。
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公开(公告)号：US4994588A
公开(公告)日：1991-02-19
申请号：US401542
申请日：1989-08-31
IPC分类号： B01J23/66 , C07D301/10
CPC分类号： C07D301/10 , B01J23/66
摘要： A process is provided for epoxidation of an alkene in the presence of an oxygen-containing gas which comprises contacting the alkene and the oxygen-containing gas under epoxidation conditions in the presence of at least one gaseous efficiency-enhancing member of a redox-half reaction pair, a performance-enhancing amount of a fluorine-containing substance and a supported silver catalyst comprising a catalytically-effective amount of silver on a solid porous support and at least one efficiency-enhancing salt of a member of a redox-half reaction pair.
摘要翻译： 提供了一种在含氧气体存在下烯烃环氧化的方法，该方法包括在氧化还原反应的至少一种气体效率增强成分存在下，在环氧化条件下使烯烃和含氧气体接触 一对性能提高量的含氟物质和负载型银催化剂，其包含在固体多孔载体上的催化有效量的银和至少一种氧化还原半反应对成员的效率增强盐。
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6.发明授权
公开(公告)号：US4339355A
公开(公告)日：1982-07-13
申请号：US841056
申请日：1977-10-11
CPC分类号： C07C51/252 , B01J23/28 , B01J23/34 , B01J23/8877 , C07C51/25 , B01J2523/00
摘要： A novel catalyst comprising the elements Mo, V and Nb is provided for oxidizing alpha-beta unsaturated aliphatic aldehydes in the vapor phase with molecular oxygen to produce the corresponding alpha-beta unsaturated carboxylic acid.
摘要翻译： 提供了包含元素Mo，V和Nb的新型催化剂，用于在气相中用分子氧氧化α-β-不饱和脂族醛以产生相应的α-β-不饱和羧酸。
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公开(公告)号：US5504053A
公开(公告)日：1996-04-02
申请号：US502187
申请日：1990-04-03
IPC分类号： B01J23/66 , B01J20060101 , B01J23/06 , B01J23/68 , B01J27/053 , C07D301/10 , C22B20060101 , B01J23/50
CPC分类号： B01J23/68 , C07D301/10 , Y02P20/52
摘要： Catalysts for the production of alkylene oxide by the epoxidation of alkene with oxygen comprise a silver impregnated support containing a sufficient amount of manganese component to enhance at least one of activity and/or efficiency and/or stability as compared to a similar catalyst which does not contain manganese component.
摘要翻译： 用于通过用氧环氧化烯烃生产环氧烷的催化剂包含含有足够量的锰组分的银浸渍载体，以增加活性和/或效率和/或稳定性中的至少一种，与不使用的类似催化剂相比，活性和/或效率和/或稳定性中的至少一种 含锰成分。
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公开(公告)号：US5187140A
公开(公告)日：1993-02-16
申请号：US556828
申请日：1990-07-23
IPC分类号： B01J20060101 , B01J23/50 , B01J23/66 , B01J23/68 , B01J27/055 , B01J27/12 , B01J27/128 , B01J27/135 , B01J27/138 , B01J35/02 , B01J35/10 , B01J37/02 , C07D301/10
CPC分类号： C07D301/10 , B01J23/50 , B01J23/66 , B01J35/0026 , B01J35/1009 , B01J35/1042
摘要： Catalysts for the epoxidation of alkene, especially ethylene, to the corresponding alkylene oxide, e.g., ethylene oxide, which catalysts contain a high silver content on carriers having a high surface area and a high pore volume are disclosed. Methods for making and using such catalysts are also disclosed.
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9.发明授权Process for preparing unsaturated acids with Mo, V, Nb, Fe-containing catalysts 失效用含Mo，V，Nb，Fe的催化剂制备不饱和酸的方法
公开(公告)号：US4415752A
公开(公告)日：1983-11-15
申请号：US142706
申请日：1980-04-22
IPC分类号： B01J23/00 , B01J23/887 , C07C51/25 , C07C57/055
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8877 , B01J23/8878 , B01J2523/00
摘要： A novel catalyst comprising the elements Mo, V and Nb, and an oxidation process, is provided for oxidizing alpha-beta unsaturated aliphatic aldehydes in the vapor phase with molecular oxygen to produce the corresponding alpha-beta unsaturated carboxylic acid.
摘要翻译： 提供了包含元素Mo，V和Nb以及氧化过程的新型催化剂，用于在气相中用分子氧氧化α-β-不饱和脂族醛以产生相应的α-β-不饱和羧酸。
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公开(公告)号：US4333858A
公开(公告)日：1982-06-08
申请号：US146221
申请日：1980-05-05
IPC分类号： B01J23/00 , B01J23/28 , B01J23/34 , B01J23/887 , B01J37/02 , C07C51/25 , B01J23/16 , B01J23/84
CPC分类号： C07C51/252 , B01J23/002 , B01J23/28 , B01J23/34 , B01J23/8877 , B01J2523/00 , B01J37/0215 , B01J37/0236
摘要： A novel catalyst comprising the elements Mo, V and Ti, and an oxidation process, is provided for oxidizing alpha beta unsaturated aliphatic aldehydes in the vapor phase with molecular oxygen to produce the corresponding alpha-beta unsaturated carboxylic acid.
摘要翻译： 提供了包含元素Mo，V和Ti的新型催化剂和氧化方法，用于在气相中用分子氧氧化αβ不饱和脂族醛以产生相应的α-β-不饱和羧酸。
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