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公开(公告)号：US4719191A
公开(公告)日：1988-01-12
申请号：US908276
申请日：1986-09-17
CPC分类号： B01J29/049 , C10G11/05
摘要： Pillared interlayered clay products of increased stability and processes for preparing such clay products are provided. The pillared interlayered clays are prepared by reacting a smectite clay, such as montmorillonite, with an aqueous solution of a polymeric cationic hydroxy metal complex, such as aluminum chlorhydroxide and reacting the resulting product with a stability increasing compound selected from the group consisting of silicon, titanium, phosphorus and antimony halides and ethyl silicates.
摘要翻译： 提供了增加稳定性的柱状粘土粘土产品和制备这种粘土产品的方法。 柱状夹层粘土是通过将蒙脱石蒙皂石与聚合阳离子羟基金属络合物如氢氧化铝的水溶液反应制备的，并使所得产物与稳定性增加的化合物反应，所述化合物选自硅， 钛，磷和锑卤化物和硅酸乙酯。
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公开(公告)号：US4775461A
公开(公告)日：1988-10-04
申请号：US146524
申请日：1988-01-21
CPC分类号： C10G11/05 , B01J29/049 , B01J29/06 , B01J29/084 , C10G11/04 , B01J2229/36 , B01J2229/42
摘要： A process for catalytic cracking using a catalyst obtained by preparing pillared interlayered clay materials comprises the steps of contacting a smectite containing material, preferably bentonite, with a solution comprising at least one of ammonium and alkali metal carboxylates and alkali metal carbonates and bicarbonates, plus preferably also alkali metal dithionite; separating the thus-contacted material from the solution; treating the separated material with a solution comprising a polymeric cationic hydroxy metal complex, preferably of aluminum (more preferably, polymeric hydroxy aluminum chloride); separating and finally heating the thus-treated smectite material. The pillared interlayered clay material of this invention can be intimately admixed with zeolite. The pillared interlayered clay material of this invention, with or without zeolite, can be used as catalyst for cracking hydrocarbon-containing oils.
摘要翻译： 使用通过制备柱状夹层粘土材料获得的催化剂进行催化裂化的方法包括以下步骤：将含绿土的材料，优选膨润土与包含铵和碱金属羧酸盐和碱金属碳酸盐和碳酸氢盐中的至少一种的溶液接触， 碱金属连二亚硫酸盐; 将如此接触的材料与溶液分离; 用包含聚合物阳离子羟基金属络合物，优选铝（更优选聚合羟基氯化铝）的溶液处理分离的材料; 分离并最终加热如此处理的蒙皂石材料。 本发明的柱状夹层粘土材料可与沸石紧密混合。 具有或不具有沸石的本发明的柱状层间粘土材料可用作裂解含烃油的催化剂。
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公开(公告)号：US4742033A
公开(公告)日：1988-05-03
申请号：US8711
申请日：1987-01-29
IPC分类号： B01J29/06 , B01J21/16 , B01J29/04 , B01J29/08 , C01B33/26 , C01B33/38 , C01B33/44 , C01B39/00 , C01B39/04 , C01B39/22 , C01B39/24 , C01B39/26 , C10G11/02 , C10G11/04 , C10G11/05 , C10G47/12
CPC分类号： C10G11/05 , B01J29/049 , B01J29/084 , C10G11/04 , B01J2229/36 , B01J2229/42
摘要： A process for preparing pillared interlayered clay materials comprises the steps of contacting a smectite containing material, preferably bentonite, with a solution comprising at least one of ammonium and alkali metal carboxylates and alkali metal carbonates and bicarbonates, plus preferably also alkali metal dithionite; separating the thus-contacted material from the solution; treating the separated material with a solution comprising a polymeric cationic hydroxy metal complex, preferably of aluminum (more preferable, polymeric hydroxy aluminum chloride); separating and finally heating the thus-treated smectite material. The pillared interlayered clay material of this invention can be intimately admixed with zeolite. The pillared interlayered clay material of this invention, with or without zeolite, can be used as catalyst for cracking hydrocarbon-containing oils.
摘要翻译： 用于制备支柱夹层粘土材料的方法包括以下步骤：将含绿土的材料，优选膨润土与包含铵和碱金属羧酸盐和碱金属碳酸盐和碳酸氢盐，还优选碱金属连二亚硫酸盐中的至少一种的溶液接触; 将如此接触的材料与溶液分离; 用包含聚合物阳离子羟基金属络合物，优选铝（更优选聚合羟基氯化铝）的溶液处理分离的材料; 分离并最终加热如此处理的蒙脱石材料。 本发明的柱状夹层粘土材料可与沸石紧密混合。 具有或不具有沸石的本发明的柱状层间粘土材料可用作裂解含烃油的催化剂。
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公开(公告)号：US5362825A
公开(公告)日：1994-11-08
申请号：US912351
申请日：1992-07-13
CPC分类号： B01J29/049 , C08F10/00
摘要： Pillared clay based high activity olefin polymerization catalysts, methods of producing the catalysts and methods of using the catalysts in the polymerization of olefins are provided. The methods of producing the catalysts each basically comprise contacting a pillared clay with the soluble complex produced by heating a mixture of a metal dihalide with a transition metal compound to produce a solid, and then reacting the solid with an organoaluminum halide. The process produces catalyst components shaped like dipyramidal or generally "football"-shaped crystals.
摘要翻译： 提供了基于柱状粘土的高活性烯烃聚合催化剂，制备催化剂的方法和在烯烃聚合中使用催化剂的方法。 制备催化剂的方法基本上包括使柱状粘土与通过加热金属二卤化物与过渡金属化合物的混合物产生的可溶性络合物接触以产生固体，然后使固体与有机铝卤化物反应。 该方法产生形状如二极体或一般“足球”形晶体的催化剂组分。
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公开(公告)号：US4637991A
公开(公告)日：1987-01-20
申请号：US742815
申请日：1985-06-10
申请人： David R. Battiste , Jesse R. Harris
发明人： David R. Battiste , Jesse R. Harris
CPC分类号： B01J29/049
摘要： Pillared, interlayered clay products suitable as gas separation agents or as substrates for catalyst compositions are prepared by methods that provide an increase in surface area and pore volume as compared to similar products made by prior art methods.
摘要翻译： 与通过现有技术方法制备的类似产品相比，通过提供表面积和孔体积增加的方法制备适合作为气体分离剂或作为催化剂组合物的底物的层间粘土产品。
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6.发明授权
公开(公告)号：US4066712A
公开(公告)日：1978-01-03
申请号：US616720
申请日：1975-09-25
申请人： Jesse R. Harris
发明人： Jesse R. Harris
摘要： Nonaromatic hydrocarbons are converted to aromatic hydrocarbons by contacting with a molecular chromium trioxide-graphite intercalation catalytic compound under dehydrocyclization conditions of temperature and pressure. In one embodiment, normal hexane is converted to benzene in the presence of a graphite-chromium trioxide interlayered complex with good conversion and high selectivity.
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公开(公告)号：US5157006A
公开(公告)日：1992-10-20
申请号：US666813
申请日：1991-03-08
申请人： Jesse R. Harris , Ping C. Liao
发明人： Jesse R. Harris , Ping C. Liao
CPC分类号： C10G11/05 , B01J23/02 , B01J29/088 , B01J29/166 , B01J37/04 , B01J2229/42 , Y10S502/521
摘要： A catalytic cracking composition comprising a physical blend of a cracking catalyst component with alcohol treated Sr(OH).sub.2 and alcohol is used to crack hydrocarbon-containing feedstocks that further contain quantities of vanadium.
摘要翻译： 包含裂化催化剂组分与醇处理的Sr（OH）2和醇的物理共混物的催化裂化组合物用于裂化含有大量钒的含烃原料。
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公开(公告)号：US4536196A
公开(公告)日：1985-08-20
申请号：US358570
申请日：1982-03-16
申请人： Jesse R. Harris
发明人： Jesse R. Harris
CPC分类号： C01B3/505 , B01D53/22 , C01B2203/0405 , C01B2203/048
摘要： A palladium or palladium alloy is coated with a metal, e.g., titanium, and employed for diffusion of hydrogen.
摘要翻译： 钯或钯合金涂覆有金属例如钛，并用于氢的扩散。
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公开(公告)号：US4465589A
公开(公告)日：1984-08-14
申请号：US457340
申请日：1983-01-12
申请人： Semyon J. Kukes , Jesse R. Harris
发明人： Semyon J. Kukes , Jesse R. Harris
摘要： Metals, nitrogen and/or sulfur, particularly vanadium, nickel and nitrogen, are removed from organic compositions, particularly heavy hydrocarbon oils, by contacting the organic composition with a methylating agent, preferably dimethyl sulfate, under conditions sufficient to form a precipitate, including the contaminants, and separating the precipitate from the organic composition as by filtration, decantation, and the like. In another embodiment of the present invention, the treatment with the methylating agent is carried out in conjunction with treatment with an acid gas and water or a solvent, such as a combination of carbon dioxide and water.
摘要翻译： 通过使有机组合物与甲基化剂，优选硫酸二甲酯在足以形成沉淀物的条件下接触，从有机组合物，特别是重质烃油中除去金属，氮和/或硫，特别是钒，镍和氮，包括 污染物，并通过过滤，倾析等将有机组合物中的沉淀物分离出来。 在本发明的另一个实施方案中，用甲基化剂的处理是与酸性气体和水或溶剂如二氧化碳和水的组合一起进行处理进行的。
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10.发明授权
公开(公告)号：US4313013A
公开(公告)日：1982-01-26
申请号：US174468
申请日：1980-08-01
申请人： Jesse R. Harris
发明人： Jesse R. Harris
CPC分类号： B01D53/22 , C01B3/505 , C07C7/144 , C01B2203/0405 , C01B2203/048
摘要： A palladium or palladium alloy hydrogen diffusion membrane which has been treated with silane and/or silicon tetrafluoride is employed to separate hydrogen from a hydrocarbon with which it is in admixture and from which it may have been produced under dehydrogenation conditions in the presence of said membrane.
摘要翻译： 已经用硅烷和/或四氟化硅处理过的钯或钯合金氢扩散膜用于从与其混合的烃分离出氢气，并且可以在脱氢条件下在所述膜存在下产生氢 。
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