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    Thermal imaging material
    1.
    发明授权
    Thermal imaging material 失效
    热成像材料

    公开(公告)号：US4808565A

    公开(公告)日：1989-02-28

    申请号：US73889

    申请日：1987-07-07

    Applicant: David R. Whitcomb ,  Jon A. Bjork

    Inventor： David R. Whitcomb ,  Jon A. Bjork

    IPC: B41M5/32 ,  B41M5/18

    CPC classification number: B41M5/3335 ,  B41M5/32 ,  B41M5/3372 ,  B41M5/3377 ,  Y10S428/913 ,  Y10S428/914

    Abstract: Thermographic materials are colorless when unexposed, but provide an intense dark image when thermally addressed. The materials comprise white ferric organophosphate, ferric organophosphinate, or ferric organophosphonate in a clear binder with a colorless catechol or polycatechol held in said binder in solid solution. The choice of substituents on the catechol nucleus can give a change in the color of the thermal image together and provide good near infrared absorption. Use of mixed catechols can give achromatic black images. These combinations of materials show high stability at ambient temperatures.

    Abstract translation: 当未曝光时，热成像材料为无色，但在热处理时可提供强烈的暗影像。 该材料包括白色有机磷酸铁，有机磷酸铁或铁有机膦酸盐，在透明粘合剂中与固体溶液中保持在所述粘合剂中的无色儿茶酚或聚邻苯二酚。 邻苯二酚核上的取代基的选择可以使热图像的颜色变化一起并且提供良好的近红外吸收。 使用混合儿茶酚可以提供无色黑色图像。 这些材料组合在环境温度下显示出高稳定性。

    High speed photothermographic materials with combined chemical sensitizers and methods of using same
    7.
    发明授权
    High speed photothermographic materials with combined chemical sensitizers and methods of using same 失效
    具有组合化学敏化剂的高速光热成像材料及其使用方法

    公开(公告)号：US06423481B1

    公开(公告)日：2002-07-23

    申请号：US09768094

    申请日：2001-01-23

    Applicant: Sharon M. Simpson ,  David R. Whitcomb ,  Steven M. Shor

    Inventor： Sharon M. Simpson ,  David R. Whitcomb ,  Steven M. Shor

    IPC: G03C1498

    CPC classification number: G03C1/49845 ,  G03C1/09 ,  G03C1/49827 ,  G03C1/49854 ,  G03C1/49881 ,  G03C2001/091 ,  G03C2001/096 ,  G03C2001/098

    Abstract: Photothermographic materials have increased photospeed provided by gold(III)-containing chemical sensitizers that are used combination with sulfur- and/or tellurium-containing chemical sensitizers. Increased photographic speed is achieved with minimal increase in Dmin. The gold(III)-containing chemical sensitizers are represented by the following Structure GOLD: Au(III)L′rYq GOLD wherein L′ represents the same or different ligands, each ligand comprising at least one heteroatom that is capable of forming a bond with gold, Y is an anion, r is an integer of from 1 to 8, and q is an integer of from 0 to 3.

    Abstract translation: 光热成像材料具有增加的由含金（III）的化学敏化剂提供的感光速率，其与含硫和/或含碲化学敏化剂结合使用。 以Dmin的最小增加实现提高的照相速度。 含金（III）的化学增感剂由以下结构金表示：其中L'表示相同或不同的配体，每个配体包含至少一个能够与金形成键的杂原子，Y是阴离子，r 为1〜8的整数，q为0〜3的整数。

    Positive-acting thermographic materials
    9.
    发明授权
    Positive-acting thermographic materials 失效
    正效热成像材料

    公开(公告)号：US4910186A

    公开(公告)日：1990-03-20

    申请号：US280569

    申请日：1988-12-06

    Applicant: David R. Whitcomb

    Inventor： David R. Whitcomb

    IPC: B41M5/32

    CPC classification number: B41M5/32 ,  Y10S428/913

    Abstract: A positive-acting thermographic material which is black or dark colored in the unexposed condition turns white or light colored when exposed to elevated temperatures. The material comprises a binder, a dark colored complex of ferric iron with a ligand chosen from organothiophosphorus acids, and a white organophosphorus acid or its alkali or alkaline earth metal salt. At elevated temperatures a double decomposition reaction occurs giving the light colored complex of ferric iron with the organophosphorus acid.

    Abstract translation: 在未暴露的状态下呈黑色或深色的正性温度记录材料在暴露于升高的温度时变为白色或浅色。 该材料包括粘合剂，三价铁与选自有机硫代磷酸的配体的深色络合物，以及白色有机磷酸或其碱金属或碱土金属盐。 在升高的温度下，发生双重分解反应，得到三价铁与有机磷酸的浅色络合物。

    Chelating polymers for modifying metal surface properties
    10.
    发明授权
    Chelating polymers for modifying metal surface properties 失效
    用于改性金属表面性能的螯合聚合物

    公开(公告)号：US4500601A

    公开(公告)日：1985-02-19

    申请号：US527332

    申请日：1983-08-29

    Applicant: David R. Whitcomb

    Inventor： David R. Whitcomb

    IPC: C09D5/00 ,  C09D157/00 ,  B32B15/08 ,  B32B27/14

    CPC classification number: C09D157/00 ,  C09D5/002 ,  Y10T428/2991 ,  Y10T428/31692

    Abstract: A composite structure and method therefor comprises a metal surface which is coated with a polymer incorporating a bidentate chelating functionality. The polymer provides significant and varied chemical modification to the metal surface and is useful, for example, as a protective coating or a priming layer. Bidentate chelating monomers useful in preparing homopolymers and copolymers with ethylenically-unsaturated non-chelating monomers have structures described by the formula ##STR1## in which R.sup.1 is hydrogen, lower alkyl, chlorinated lower alkyl, CN, or ClP is a connecting linkage of chain length up to to about 75 atoms, andQ is a bidentate chelating group having a high affinity for the ions of the metal of the surface involved.

    Abstract translation: 复合结构及其方法包括金属表面，该金属表面涂覆有掺入二齿螯合官能团的聚合物。 聚合物为金属表面提供了显着且多样的化学改性，并且可用作例如保护涂层或底漆层。 用于制备具有烯属不饱和非螯合单体的均聚物和共聚物的双齿螯合单体具有通式为“IMAGE”的结构，其中R 1是氢，低级烷基，氯代低级烷基，CN或Cl P是链的连接键 长度高达约75个原子，Q是对所涉及的表面的金属的离子具有高亲和力的二齿螯合基团。

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