摘要:
A high impact polystyrene (HIPS) is made from styrene monomer and 3 to 20 wt % of an elastomeric component phase including polybutadiene rubber and styrene butadiene copolymer. The HIPS has a 60 degree gloss of 90 or more, a Gardner drop of at least 10 in-lb, and an Izod impact strength of 1.8 ft-lb/in or more. The HIPS can have salami morphology with rubber particle size between 1 and 1.3 microns.
摘要:
A high impact polystyrene (HIPS) is made from styrene monomer and 3 to 20 wt % of an elastomeric component phase including polybutadiene rubber and styrene butadiene copolymer. The HIPS has a 60 degree gloss of 90 or more, a Gardner drop of at least 10 in-lb, and an Izod impact strength of 1.8 ft-lb/in or more. The HIPS can have salami morphology with rubber particle size between 1 and 1.3 microns.
摘要:
A mono-axially oriented polypropylene film with sodium benzoate as a nucleating agent results in reduced shrinkage and increase stretchability. The sodium benzoate ranges up to 1000 ppm. The polypropylene used in making the film preferably has an isotacticity exceeding 97% as determined by C.sup.13 -NMR spectroscopy. The film preferably has a thicknesses of about 0.5 mil to 5.0 mil and, more preferably, about 1.0 mil to 3.0 mil. The sodium benzoate preferably has a purity of 99% and a particle size of from about 1 micron to about 3 microns.
摘要:
A process for producing high impact polystyrene including feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture. Polymerizing the reaction mixture in the first linear flow reactor to a point below the point at which phase inversion occurs to produce a first polymerization mixture and feeding the first polymerization mixture from the first linear flow reactor to a second linear flow reactor. Polymerizing the reaction mixture in the second linear flow reactor to at least a phase inversion point of the mixture to produce a second polymerization mixture and feeding the second polymerization mixture from the second linear flow reactor to at least a third linear flow reactor for post-inversion polymerization of the second polymerization mixture. The product stream can have an ESCR value of at least 10% toughness retained with less than 10 wt % rubber content.
摘要:
Polymer articles and processes of forming polymer articles are described herein. The processes generally include providing a propylene based polymer formed from a metallocene catalyst and melt processing the propylene based polymer to form a polymer article.
摘要:
A polymer blend and a method of making the same are provided. The polymer blend includes an ethylene-propylene (C2-C3) random copolymer and a modifier selected from the group consisting of a metallocene-catalyzed polyethylene-based copolymer, a metallocene-catalyzed polyethylene-based terpolymer, and a syndiotactic polypropylene homopolymer. The polymer blend may also include an organic peroxide for visbreaking the polymer blend. An end use article is made from the foregoing polymer blend. The end use article may be, for example, a film, an injection molded article, a compression molded article, a thermoformed article, and a fiber. The end use article is desirably a film having an Elmendorf tear strength of at least about 300 g/ply in the machine and transverse directions.
摘要:
Using sodium benzoate as an additive or a nucleating agent in polypropylene film, specifically a uni- or mono-axially oriented polypropylene film, up to 1000 ppm reduces shrinkage and increases stretchability.
摘要:
Injection stretch blow molded (ISBM) articles and processes for forming the same are described herein. The articles include a propylene based polymer having a melt flow rate of less than 10 g/10 min.
摘要:
Fibers and articles formed therefrom are described herein. The fibers generally include a first polymer including a first propylene based impact copolymer and a second propylene based polymer.
摘要:
Polyolefin blends and processes for forming polyolefin blends are described herein. The blends generally include a polyolefin and a monomer system including triacrylate monomers. The blends may further include one or more chain transfer agents.