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    PASSIVATION OF A HOMOGENEOUS HYDROGENATION CATALYST FOR THE PRODUCTION OF ETHYLENE GLYCOL
    3.
    发明申请
    PASSIVATION OF A HOMOGENEOUS HYDROGENATION CATALYST FOR THE PRODUCTION OF ETHYLENE GLYCOL 有权
    用于生产乙烯甘油的均质加氢催化剂的钝化

    公开(公告)号：US20130253230A1

    公开(公告)日：2013-09-26

    申请号：US13428333

    申请日：2012-03-23

    申请人： David William Norman ,  Jonathan Michael Penney ,  Peter Borden Mackenzie

    发明人： David William Norman ,  Jonathan Michael Penney ,  Peter Borden Mackenzie

    IPC分类号： C07C29/136

    CPC分类号： C07C29/147 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/2409 ,  B01J2231/643 ,  B01J2531/821 ,  B01J2540/10 ,  Y02P20/52 ,  Y02P20/582 ,  C07C31/202

    摘要： A process for making ethylene glycol by feeding reactants including 1,2-dioxygenated organic compounds, an organometallic homogeneous catalyst, and hydrogen to a hydrogenation reactor, reacting at least a portion of the reactants with hydrogen in the presence of the organometallic homogeneous catalyst to produce a reaction product mixture containing ethylene glycol, and passivating the catalyst by contacting the catalyst with a carbon monoxide to thereby suppress the formation of by-product diols other thatn the ethylene glycol primary product, and suppress the formation of by-product tetrols and by-product glycolaldehyde acetals; and separating at least a portion of the ethylene glycol from the reaction product mixture.

    摘要翻译： 通过将包括1,2-二氧化有机化合物，有机金属均相催化剂和氢的反应物加入到氢化反应器中来制备乙二醇的方法，使至少一部分反应物与氢在有机金属均相催化剂存在下反应，生成 含有乙二醇的反应产物混合物，并通过使催化剂与一氧化碳接触来钝化催化剂，从而抑制乙二醇一级产物以外的副产物二醇的形成，并抑制副产物四环和副产物的形成， 产品乙二醇缩醛; 以及从反应产物混合物中分离出至少一部分乙二醇。

    Passivation of a homogeneous hydrogenation catalyst for the production of ethylene glycol
    4.
    发明授权
    Passivation of a homogeneous hydrogenation catalyst for the production of ethylene glycol 有权
    钝化用于生产乙二醇的均相氢化催化剂

    公开(公告)号：US08969632B2

    公开(公告)日：2015-03-03

    申请号：US13428333

    申请日：2012-03-23

    申请人： David William Norman ,  Jonathan Michael Penney ,  Peter Borden Mackenzie

    发明人： David William Norman ,  Jonathan Michael Penney ,  Peter Borden Mackenzie

    IPC分类号： C07C29/149 ,  C07C29/141 ,  C07C29/145

    CPC分类号： C07C29/147 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/2409 ,  B01J2231/643 ,  B01J2531/821 ,  B01J2540/10 ,  Y02P20/52 ,  Y02P20/582 ,  C07C31/202

    摘要： A process for making ethylene glycol by feeding reactants including 1,2-dioxygenated organic compounds, an organometallic homogeneous catalyst, and hydrogen to a hydrogenation reactor, reacting at least a portion of the reactants with hydrogen in the presence of the organometallic homogeneous catalyst to produce a reaction product mixture containing ethylene glycol, and passivating the catalyst by contacting the catalyst with a carbon monoxide to thereby suppress the formation of by-product diols other that the ethylene glycol primary product, and suppress the formation of by-product tetrols and by-product glycolaldehyde acetals; and separating at least a portion of the ethylene glycol from the reaction product mixture.

    摘要翻译： 通过将包括1,2-二氧化有机化合物，有机金属均相催化剂和氢的反应物加入到氢化反应器中来制备乙二醇的方法，使至少一部分反应物与氢在有机金属均相催化剂存在下反应，生成 含有乙二醇的反应产物混合物，并通过使催化剂与一氧化碳接触来钝化催化剂，从而抑制副产物二醇的形成，而不是乙二醇一级产物，并抑制副产物四环和副产物的形成 产品乙二醇缩醛; 以及从反应产物混合物中分离出至少一部分乙二醇。

    CATALYSTS AND PROCESSES FOR PREPARING ALDEHYDES
    6.
    发明申请
    CATALYSTS AND PROCESSES FOR PREPARING ALDEHYDES 有权
    催化剂和制备ALDEHYDES的方法

    公开(公告)号：US20130324767A1

    公开(公告)日：2013-12-05

    申请号：US13485033

    申请日：2012-05-31

    申请人： David William Norman ,  Joost Nicolaas Hendrik Reek ,  Tatiana Renee Marie-Louise Besset

    发明人： David William Norman ,  Joost Nicolaas Hendrik Reek ,  Tatiana Renee Marie-Louise Besset

    IPC分类号： C07C45/49

    CPC分类号： C07C45/50 ,  Y02P20/582 ,  C07C47/02

    摘要： Use of a unique supramolecular assembly of a pyridylphosphine ligand and a metal centered porphyrin complex is shown to give unprecedented selectivities to branched aldehydes via rhodium catalyzed hydroformylation of unsubstituted linear alpha-olefins such as propylene and 1-octene. Increasing the syngas pressure is shown to have a beneficial effect on branched aldehyde selectivity as is increasing the ratio of carbon monoxide to hydrogen used in the hydroformylation reaction.

    摘要翻译： 显示使用吡啶基膦配体和金属中心卟啉络合物的独特超分子组装体，通过未取代的直链α-烯烃（如丙烯和1-辛烯）的铑催化加氢甲酰基化，为支化醛提供前所未有的选择性。 显示合成气压力的增加对支链醛选择性具有有益的作用，因为增加加氢甲酰化反应中使用的一氧化碳与氢的比例。