Branched melt polycarbonate with low content of defective structures
    4.
    发明授权
    Branched melt polycarbonate with low content of defective structures 有权
    具有低含量缺陷结构的支化熔融聚碳酸酯

    公开(公告)号:US08487025B2

    公开(公告)日:2013-07-16

    申请号:US13081847

    申请日:2011-04-07

    IPC分类号: C08K5/51

    CPC分类号: C08G64/14 C08G64/307 C08K5/49

    摘要: The present invention relates to an aromatic branched polycarbonate, produced via melt transesterification of a bisphenol with a diaryl carbonate in the presence of a branching agent, wherein the aromatic branched polycarbonate comprises branching point structures and structures of formula (D) wherein X is a single bond, C1- to C6-alkylene, C2- to C5-alkylidene or C5- to C6-cycloalkylidene, optionally substituted by C1- to C6-alkyl; wherein the amount of D in the aromatic branched polycarbonate is in the range of from 5 to 450 mg per kg of the aromatic branched polycarbonate; and wherein the ratio of the total branching point structures to the total structures of the formula D in the aromatic branched polycarbonate is in the range of from 8 to 200.

    摘要翻译: 本发明涉及通过在支化剂存在下通过双酚与碳酸二芳基酯的熔融酯交换制备的芳族支化聚碳酸酯,其中芳族支化聚碳酸酯包含分支点结构和式(D)的结构,其中X是单 键,C 1至C 6亚烷基,C 2至C 5亚烷基或C 5至C 6环烷叉基,任选被C 1至C 6 - 烷基取代; 其中所述芳族支化聚碳酸酯中的D的量在5至450mg / kg所述芳族支化聚碳酸酯的范围内; 并且其中芳族支化聚碳酸酯中总分支点结构与式D的总结构的比例在8至200的范围内。

    BRANCHED MELT POLYCARBONATE WITH LOW CONTENT OF DEFECTIVE STRUCTURES
    6.
    发明申请
    BRANCHED MELT POLYCARBONATE WITH LOW CONTENT OF DEFECTIVE STRUCTURES 有权
    具有低含量缺陷结构的分散熔融聚碳酸酯

    公开(公告)号:US20110251309A1

    公开(公告)日:2011-10-13

    申请号:US13081847

    申请日:2011-04-07

    CPC分类号: C08G64/14 C08G64/307 C08K5/49

    摘要: The present invention relates to an aromatic branched polycarbonate, produced via melt transesterification of a bisphenol with a diaryl carbonate in the presence of a branching agent, wherein the aromatic branched polycarbonate comprises branching point structures and structures of formula (D) wherein X is a single bond, C1- to C6-alkylene, C2- to C5-alkylidene or C5- to C6-cycloalkylidene, optionally substituted by C1- to C6-alkyl; wherein the amount of D in the aromatic branched polycarbonate is in the range of from 5 to 450 mg per kg of the aromatic branched polycarbonate; and wherein the ratio of the total branching point structures to the total structures of the formula D in the aromatic branched polycarbonate is in the range of from 8 to 200.

    摘要翻译: 本发明涉及通过在支化剂存在下通过双酚与碳酸二芳基酯的熔融酯交换制备的芳族支化聚碳酸酯,其中芳族支化聚碳酸酯包含分支点结构和式(D)的结构,其中X是单 键,C 1至C 6亚烷基,C 2至C 5亚烷基或C 5至C 6环烷叉基,任选被C 1至C 6 - 烷基取代; 其中所述芳族支化聚碳酸酯中的D的量在5至450mg / kg所述芳族支化聚碳酸酯的范围内; 并且其中芳族支化聚碳酸酯中总分支点结构与式D的总结构的比例在8至200的范围内。

    METHOD AND APPARATUS FOR CHARACTERIZING POLYMERS
    7.
    发明申请
    METHOD AND APPARATUS FOR CHARACTERIZING POLYMERS 审中-公开
    用于表征聚合物的方法和装置

    公开(公告)号:US20120085151A1

    公开(公告)日:2012-04-12

    申请号:US13251744

    申请日:2011-10-03

    IPC分类号: G01N11/02

    摘要: The present invention relates to a method for automatically determining the relative solution viscosity and/or the melt volume flow rate of a polymer, during a phase of the process for producing the polymer, where the polymer is in a solution with 10 to 20% by weight of the polymer in an organic solvent. The method includes continuously removing a substream of the polymer solution from a component of the process for producing the polymer, wherein the polymer solution is essentially free from inorganic salts; removing a sample having a volume of from 1 to 10 μl from the substream; introducing the sample into a gel permeation chromatography apparatus and determining the gel permeation chromatography data for the polymer; and automatically determining the relative solution viscosity and/or the melt volume flow rate of the polymer from the data obtained from the gel permeation chromatogram, on the basis of calibration relationships.

    摘要翻译: 本发明涉及在生产聚合物的方法阶段期间自动确定聚合物的相对溶液粘度和/或熔融体积流动速率的方法,其中聚合物在具有10至20% 聚合物在有机溶剂中的重量。 该方法包括从生产聚合物的方法的组分连续地除去聚合物溶液的子流,其中聚合物溶液基本上不含无机盐; 从子流中除去体积为1至10μl的样品; 将样品引入凝胶渗透色谱装置并测定聚合物的凝胶渗透色谱数据; 并且根据校准关系,根据从凝胶渗透色谱图获得的数据自动确定聚合物的相对溶液粘度和/或熔体体积流速。

    Polycarbonates with good wettability
    8.
    发明授权
    Polycarbonates with good wettability 有权
    具有良好润湿性的聚碳酸酯

    公开(公告)号:US07799889B2

    公开(公告)日:2010-09-21

    申请号:US11312020

    申请日:2005-12-20

    IPC分类号: C08G64/00 C08G63/02

    摘要: The present invention provides a polycarbonate resin produced by the continuous interfacial process characterized in that after alkaline hydrolysis with sodium hydroxide, the polycarbonate resin contains an amount of 0.01 to 150 ppm of carbamate compounds according to formula (1) said amount measured by high pressure liquid chromatography, wherein R1 and R2 independently of one another denote hydrogen or C1-C12-alkyl, or together denote C4-C12-alkylidene, and R3 and R4 independently of one another denote hydrogen. C1-C12-alkyl or phenyl, or together with the carbon atom to which they are bonded form cyclohexyl or trimethylcyclohexyl, the process comprising phosgene reacting with at least one bisphenol at 8 to 17% molar excess of phosgene relative to the bisphenol.

    摘要翻译: 本发明提供了一种通过连续界面方法制备的聚碳酸酯树脂,其特征在于在用氢氧化钠碱化后,聚碳酸酯树脂含有0.01至150ppm根据式(1)的氨基甲酸酯化合物,所述量由高压液体 色谱法,其中R 1和R 2彼此独立地表示氢或C 1 -C 12烷基,或一起表示C 4 -C 12亚烷基,并且R 3和R 4彼此独立地表示氢。 C1-C12烷基或苯基,或与它们所键合的碳原子一起形成环己基或三甲基环己基,该方法包括与相对于双酚的8至17摩尔过量的光气与至少一种双酚反应的方法。

    Polycarbonates with good wettability
    9.
    发明申请
    Polycarbonates with good wettability 有权
    具有良好润湿性的聚碳酸酯

    公开(公告)号:US20060135735A1

    公开(公告)日:2006-06-22

    申请号:US11312020

    申请日:2005-12-20

    IPC分类号: C08G64/00

    摘要: A polycarbonate resin that after alkaline hydrolysis with sodium hydroxide contain an amount of 0.01 to 150 ppm of carbamate compounds according to formula (1) wherein R1 and R2 independently of one another denote hydrogen or C1-C12-alkyl, or together denote C4-C12-alkylidene, and R3 and R4 independently of one another denote hydrogen, C1-C12-alkyl or phenyl, or together with the carbon atom to which they are bonded form cyclohexyl or trimethylcyclohexyl, said amount measured after alkaline hydrolysis with sodium hydroxide by high pressure liquid chromatography.

    摘要翻译: 用氢氧化钠碱性水解后的聚碳酸酯树脂含有0.01〜150ppm的式(1)的氨基甲酸酯化合物,其中R 1和R 2独立地为1 另一个表示氢或C 1 -C 12 - 烷基,或一起表示C 4 -C 12 - 亚烷基 ,R 3和R 4彼此独立地表示氢,C 1 -C 12 - 烷基或 苯基或与它们键合的碳原子一起形成环己基或三甲基环己基,所述量通过高压液相色谱用氢氧化钠碱化后测量。

    MEASUREMENT TRANSMITTER HAVING A PLURALITY OF FIELDBUS ADDRESSES AND METHOD FOR RETRIEVING MEASURED VALUES FROM SUCH A MEASUREMENT TRANSMITTER
    10.
    发明申请
    MEASUREMENT TRANSMITTER HAVING A PLURALITY OF FIELDBUS ADDRESSES AND METHOD FOR RETRIEVING MEASURED VALUES FROM SUCH A MEASUREMENT TRANSMITTER 审中-公开
    具有多个现场总线地址的测量发射机和从这种测量发射机检测测量值的方法

    公开(公告)号:US20130187790A1

    公开(公告)日:2013-07-25

    申请号:US13876917

    申请日:2011-08-25

    IPC分类号: G08C19/00

    摘要: A measurement transmitter having an interface for transmission of measured values via a fieldbus, wherein communication via the fieldbus occurs according to a fieldbus protocol, wherein the number of measured values provided by the measurement transmitter exceeds the number of measured values retrievable by means of a basic command of the fieldbus protocol, wherein the measurement transmitter has a plurality of fieldbus addresses, and wherein a logic unit is provided, which serves so to distribute the measured values among the plurality of fieldbus addresses of the measurement transmitter that the measured values are retrievable via the plurality of fieldbus addresses of the measurement transmitter by means of the basic command.

    摘要翻译: 一种具有用于经由现场总线传输测量值的接口的测量发射机,其中,经由现场总线的通信根据现场总线协议发生,其中由测量发射机提供的测量值的数量超过可通过基本 指示现场总线协议,其中测量发射机具有多个现场总线地址,并且其中提供逻辑单元,其用于在测量发射机的多个现场总线地址之间分配测量值,测量值可通过 通过基本命令测量发射机的多个现场总线地址。