摘要:
Disclosed are random copoly(phosphonate carbonate)s with the high molecular weight and narrow molecular weight distribution exhibiting a superior combination of properties compared to prior art.
摘要:
The invention relates to a polycarbonate composition with improved melt-flowability together with good optical properties and together with good hydrolysis resistance.
摘要:
The invention relates to a polycarbonate composition with improved melt-flowability together with good optical properties and together with good hydrolysis resistance.
摘要:
The present invention relates to an aromatic branched polycarbonate, produced via melt transesterification of a bisphenol with a diaryl carbonate in the presence of a branching agent, wherein the aromatic branched polycarbonate comprises branching point structures and structures of formula (D) wherein X is a single bond, C1- to C6-alkylene, C2- to C5-alkylidene or C5- to C6-cycloalkylidene, optionally substituted by C1- to C6-alkyl; wherein the amount of D in the aromatic branched polycarbonate is in the range of from 5 to 450 mg per kg of the aromatic branched polycarbonate; and wherein the ratio of the total branching point structures to the total structures of the formula D in the aromatic branched polycarbonate is in the range of from 8 to 200.
摘要:
The invention relates to a UV-stabilised melt polycarbonate composition having improved melt flowability while at the same time having good optical properties and at the same time good hydrolytic stability, the composition comprising a melt polycarbonate, at least one UV absorber, at least one phosphine and optionally an aliphatic carboxylic acid ester.
摘要:
The present invention relates to an aromatic branched polycarbonate, produced via melt transesterification of a bisphenol with a diaryl carbonate in the presence of a branching agent, wherein the aromatic branched polycarbonate comprises branching point structures and structures of formula (D) wherein X is a single bond, C1- to C6-alkylene, C2- to C5-alkylidene or C5- to C6-cycloalkylidene, optionally substituted by C1- to C6-alkyl; wherein the amount of D in the aromatic branched polycarbonate is in the range of from 5 to 450 mg per kg of the aromatic branched polycarbonate; and wherein the ratio of the total branching point structures to the total structures of the formula D in the aromatic branched polycarbonate is in the range of from 8 to 200.
摘要:
The present invention relates to a method for automatically determining the relative solution viscosity and/or the melt volume flow rate of a polymer, during a phase of the process for producing the polymer, where the polymer is in a solution with 10 to 20% by weight of the polymer in an organic solvent. The method includes continuously removing a substream of the polymer solution from a component of the process for producing the polymer, wherein the polymer solution is essentially free from inorganic salts; removing a sample having a volume of from 1 to 10 μl from the substream; introducing the sample into a gel permeation chromatography apparatus and determining the gel permeation chromatography data for the polymer; and automatically determining the relative solution viscosity and/or the melt volume flow rate of the polymer from the data obtained from the gel permeation chromatogram, on the basis of calibration relationships.
摘要:
The present invention provides a polycarbonate resin produced by the continuous interfacial process characterized in that after alkaline hydrolysis with sodium hydroxide, the polycarbonate resin contains an amount of 0.01 to 150 ppm of carbamate compounds according to formula (1) said amount measured by high pressure liquid chromatography, wherein R1 and R2 independently of one another denote hydrogen or C1-C12-alkyl, or together denote C4-C12-alkylidene, and R3 and R4 independently of one another denote hydrogen. C1-C12-alkyl or phenyl, or together with the carbon atom to which they are bonded form cyclohexyl or trimethylcyclohexyl, the process comprising phosgene reacting with at least one bisphenol at 8 to 17% molar excess of phosgene relative to the bisphenol.
摘要:
A polycarbonate resin that after alkaline hydrolysis with sodium hydroxide contain an amount of 0.01 to 150 ppm of carbamate compounds according to formula (1) wherein R1 and R2 independently of one another denote hydrogen or C1-C12-alkyl, or together denote C4-C12-alkylidene, and R3 and R4 independently of one another denote hydrogen, C1-C12-alkyl or phenyl, or together with the carbon atom to which they are bonded form cyclohexyl or trimethylcyclohexyl, said amount measured after alkaline hydrolysis with sodium hydroxide by high pressure liquid chromatography.
摘要:
A measurement transmitter having an interface for transmission of measured values via a fieldbus, wherein communication via the fieldbus occurs according to a fieldbus protocol, wherein the number of measured values provided by the measurement transmitter exceeds the number of measured values retrievable by means of a basic command of the fieldbus protocol, wherein the measurement transmitter has a plurality of fieldbus addresses, and wherein a logic unit is provided, which serves so to distribute the measured values among the plurality of fieldbus addresses of the measurement transmitter that the measured values are retrievable via the plurality of fieldbus addresses of the measurement transmitter by means of the basic command.