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公开(公告)号：US5712350A
公开(公告)日：1998-01-27
申请号：US591162
申请日：1996-01-16
IPC分类号： C08G75/0236 , C08G75/0295 , C08G75/06 , C08G75/20 , C08F283/00 , C08L81/00
CPC分类号： C08G75/0295 , C08G75/0236 , C08G75/20
摘要： Process for oxidizing a polymer containing thioether groups, in which the polymer in solid form in a suspension medium is oxidized with ozone. The polymer obtained is suitable for the production of functional parts on which high demands are made.
摘要翻译： 用于氧化含有硫醚基团的聚合物的方法，其中固体形式的悬浮介质中的聚合物被臭氧氧化。 所得聚合物适用于生产要求高的功能部件。
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2.发明授权
公开(公告)号：US5423902A
公开(公告)日：1995-06-13
申请号：US110586
申请日：1993-08-23
CPC分类号： B01J20/26 , B01D19/0031 , B01D53/66 , C08G75/0204
摘要： A filter material based on a polyarylene thioether having repeating units of the formula--[(Ar.sup.1).sub.n --X)].sub.m --[(Ar.sup.2).sub.i --Y)].sub.j --[(Ar.sup.3).sub.k --Z)].sub.l --[(Ar.sup.4).sub.o --W)].sub.p --(I)in which Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4, W, X, Y and Z, independently of each other, are identical or different, the indices n, m, i, j, k, l, o and p, independently of each other, are zero or integers 1, 2, 3 or 4, their sum being at least 2, Ar.sup.1, Ar.sup.2, Ar.sup.3 and Ar.sup.4 are arylene systems having 6 to 18 carbon atoms, and W, X, Y and Z are divalent linking groups, selected from --SO.sub.2 --, --S--, --SO--, --CO--, --O--, --CO.sub.2 --, or alkylene groups or alkylidene groups having 1 to 6 carbon atoms is suitable for removing ozone from gases or liquids. The removal proceeds quantitatively, no volatile products being formed.
摘要翻译： 基于具有式[[（Ar 1）n X）] m - [（Ar 2）i Y）] j - [（Ar 3）k Z）] - [（Ar 4）o W）] p]的重复单元的聚芳硫醚的过滤材料 - （I）其中Ar1，Ar2，Ar3，Ar4，W，X，Y和Z彼此独立地相同或不同，指数n，m，i，j，k，l，o和p， 彼此独立，为零或整数1,2,3或4，它们的和为至少2，Ar 1，Ar 2，Ar 3和Ar 4为具有6至18个碳原子的亚芳基体系，W，X，Y和Z分别为 选自-SO 2 - ， - S - ， - SO - ， - CO - ， - O - ， - CO 2 - 或具有1至6个碳原子的亚烷基或亚烷基的二价连接基团适用于从气体或 液体。 清除量定量进行，不形成挥发性物质。
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公开(公告)号：US6020442A
公开(公告)日：2000-02-01
申请号：US585267
申请日：1996-01-11
IPC分类号： C08G75/00 , C08G75/0236 , C08G75/0295 , C08G75/06 , C08G75/18 , C08L81/00
CPC分类号： C08G75/0236 , C08G75/0295 , C08G75/18
摘要： Oxidation product of polyarylene sulfides comprising recurring units of the formula.brket open-st.C.sub.6 H.sub.4 --S.brket close-st. (I)in the form of a compound comprising recurring units of the formula.brket open-st..paren open-st.C.sub.6 H.sub.4 --S.paren close-st..sub.a .paren open-st.C.sub.6 H.sub.4 --SO.paren close-st..sub.b .brket close-st.(II)in which the sulfur/oxygen ratio is from 1:0.1 to 1:1, the sum of a and b always being 1 and a and b each being greater than zero or with the proviso that a is zero if b is 1.
摘要翻译： 包含式+ 547 C6H4-S + 548（I）的重复单元的聚亚芳基硫化物的氧化产物为包含式+ 547 +545 C6H4-S + 546a + 545C6H4-SO + 546的重复单元的化合物形式 b + 548（II），其中硫/氧比为1:0.1至1:1，a和b之和始终为1，a和b各自大于零，或者条件是a为0，如果 b为1。
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4.发明授权
公开(公告)号：US5496916A
公开(公告)日：1996-03-05
申请号：US237272
申请日：1994-05-03
IPC分类号： C08G75/00 , C08G75/0236 , C08G75/0295 , C08G75/20 , C08F6/00
CPC分类号： C08G75/0295 , C08G75/0236 , C08G75/20
摘要： Process for preparing a polyarylene sulfone by oxidizing a polyarylene thioether in acetic acid with hydrogen peroxide, the reaction being carried out in the presence of catalytic amounts of concentrated sulfuric acid and/or with the addition of equilibrium per-acids. The reaction products are suitable for producing molded parts having high temperature resistance and high resistance to chemicals.
摘要翻译： 通过用过氧化氢氧化乙酸中的聚亚芳基硫醚制备聚亚芳基砜的方法，该反应在催化量的浓硫酸存在下和/或加入平衡过酸进行。 反应产物适用于生产具有耐高温性和高耐化学性的成型部件。
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公开(公告)号：US5593594A
公开(公告)日：1997-01-14
申请号：US396475
申请日：1995-03-02
CPC分类号： B01J20/26 , B01D19/0031 , B01D53/66 , C08G75/0204
摘要： A filter material based on a polyarylene thioether having repeating units of the formula--[(Ar.sup.1).sub.n --X)].sub.m --[(Ar.sup.2).sub.i --Y)].sub.j --[(Ar.sup.3).sub.k --Z)].sub.1 --[(Ar.sup.4).sub.o --W)].sub.p --(I)in which Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4, W, X, Y and Z, independently of each other, are identical or different, the indices n, m, i, j, k, l, o and p, independently of each other, are zero or integers 1, 2, 3 or 4, their sum being at least 2, Ar.sup.1, Ar.sup.2, Ar.sup.3 and Ar.sup.4 are arylene systems having 6 to 18 carbon atoms, and W, X, Y and Z are divalent linking groups, selected from --SO.sub.2 --, --S--, --SO--, --CO--, --O--, --CO.sub.2 --, or alkylene groups or alkylidene groups having 1 to 6 carbon atoms is suitable for removing ozone from gases or liquids. The removal proceeds quantitatively, no volatile products being formed.
摘要翻译： 基于具有式[[（Ar1）nX）] m - [（Ar2）iY）] j - [（Ar3）kZ）] 1 - [（Ar4）oW）] p]的重复单元的聚芳硫醚的过滤材料 - （I）其中Ar1，Ar2，Ar3，Ar4，W，X，Y和Z彼此独立地相同或不同，指数n，m，i，j，k，l，o和p， 彼此独立，为零或整数1,2,3或4，它们的和为至少2，Ar 1，Ar 2，Ar 3和Ar 4为具有6至18个碳原子的亚芳基体系，W，X，Y和Z分别为 选自-SO 2 - ， - S - ， - SO - ， - CO - ， - O - ， - CO 2 - 或具有1至6个碳原子的亚烷基或亚烷基的二价连接基团适用于从气体或 液体。 清除量定量进行，不形成挥发性物质。
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公开(公告)号：US5496917A
公开(公告)日：1996-03-05
申请号：US237271
申请日：1994-05-03
IPC分类号： C08G75/00 , C08G75/0236 , C08G75/0295 , C08G75/06 , C08G75/18 , C08G75/20 , C08L27/12 , C08L81/06 , F16C33/20 , C08F6/00
CPC分类号： F16C33/201 , C08G75/0236 , C08G75/0295 , C08G75/18 , C08G75/20 , C08L27/12 , C08L81/06
摘要： Polyarylene thioethers having recurring units of the formula[--(S--E--).sub.a --(--SO--E--).sub.b --(SO.sub.2 --E).sub.c --](I)in which E are, independently of one another, phenylene, naphthylene or biphenylene, a and c have, independently of one another, values from 0 to less than 1 and b has values from greater than zero to less than 1, with the proviso that the sum of a+b+c is equal to 1 and at least two of the indices are greater than zero, are obtained by oxidation of polyarylene sulfides in two stages, wherein in the first stage a polymer in solid form in a suspension medium is oxidized with ozone and the reaction product obtained is in the second stage reacted in acetic acid with hydrogen peroxide in the presence of catalytic amounts of concentrated sulfuric acid and/or with addition of equilibrium per-acids. The polyarylene thioethers are suitable for the production of molded parts having high temperature resistance and high resistance to chemicals.
摘要翻译： 具有式[ - （SE-）a - （ - SO-E-）b-（SO2-E）c - ]（I）重复单元的聚亚芳基硫醚，其中E彼此独立地为亚苯基，亚萘基或亚苯基 亚联苯，a和c彼此独立地具有0至小于1的值，b具有大于0至小于1的值，条件是a + b + c的和等于1且在 指标中的至少两个大于零，是通过两段式聚亚芳基硫化物的氧化获得的，其中在第一阶段中，悬浮介质中固体形式的聚合物被臭氧氧化，并且所得反应产物在第二阶段中反应 在乙酸中与过氧化氢在催化量的浓硫酸存在下和/或加入平衡过酸。 聚亚芳基硫醚适用于生产具有耐高温性和高耐化学性的成型部件。
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7.发明授权
公开(公告)号：US5292971A
公开(公告)日：1994-03-08
申请号：US17687
申请日：1993-02-12
申请人： Jurgen Kulpe , Heinz Strutz
发明人： Jurgen Kulpe , Heinz Strutz
IPC分类号： C07C29/46 , C07C35/48 , C07C35/52 , C08G63/682 , C07C35/29
CPC分类号： C07C35/52 , C08G63/6826
摘要： Fluorine-substituted vicinal glycols of the formula ##STR1## in which the substituents R.sub.1 to R.sub.4, independently of one another, have the following meanings: R.sub.1 to R.sub.4 =H, fluorine, C.sub.1 - to C.sub.18 -alkyl in which some or all of the hydrogens may be substituted by fluorine, and at least one of the substituents R.sub.1 to R.sub.4 is a completely fluorinated alkyl or an alkyl of the formula--(CH.sub.2).sub.m --(C.sub.n F.sub.2n+1),in which m is 1 or 2, and n is an integer from 1 to 17, and x is 0 or 1.Furthermore, a method for the preparation of the fluorinated vicinal glycols is described. If the fluorinated vicinal glycols are condensed together with dicarboxylic acids, products having enhanced thermal stability are obtained.
摘要翻译： 取代基R 1至R 4彼此独立地具有下列含义的式“IMAGE”的氟取代的连位二醇，其中R 1至R 4 = H，氟，C 1 -C 18烷基，其中部分或全部 氢可以被氟取代，并且至少一个取代基R 1至R 4是完全氟化的烷基或式 - （CH 2）m - （C n F 2n + 1）的烷基，其中m是1或2，n 是1〜17的整数，x为0或1.此外，描述了制备氟化连二醇的方法。 如果氟化连二醇与二羧酸一起冷凝，则获得具有增强的热稳定性的产物。
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公开(公告)号：US5331084A
公开(公告)日：1994-07-19
申请号：US16901
申请日：1993-02-12
申请人： Jurgen Kulpe , Heinz Strutz
发明人： Jurgen Kulpe , Heinz Strutz
IPC分类号： C07D301/14 , C07D303/08 , C07D301/19 , C07D303/04 , C07D303/06
CPC分类号： C07D303/08
摘要： Fluorine-substituted epoxides of the formula ##STR1## in which the substituents R.sub.1 to R.sub.4, independently of one another, have the following meanings:R.sub.1 to R.sub.4 =H, fluorine, C.sub.1 - to C.sub.18 -alkyl in which some or all of the hydrogens may be substituted by fluorine, and at least one of the substituents R.sub.1 to R.sub.4 is a completely fluorinated alkyl or an alkyl of the formula--(CH.sub.2).sub.m --(C.sub.n F.sub.2n+1),in which m is 1 or 2, and n is an integer from 1 to 17, and x is 0 or 1.Furthermore, a method for the preparation of fluorine-substituted epoxides is described.
摘要翻译： 取代基R 1至R 4彼此独立的氟取代的环氧化物具有如下含义：R 1至R 4 = H，氟，C 1至C 18烷基，其中部分或全部氢 可以被氟取代，并且至少一个取代基R 1至R 4是完全氟化的烷基或式 - （CH 2）m - （C n F 2n + 1）的烷基，其中m为1或2，n为 1〜17的整数，x为0或1.此外，描述了制备氟取代的环氧化物的方法。
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公开(公告)号：US08664444B2
公开(公告)日：2014-03-04
申请号：US13817155
申请日：2011-08-18
申请人： Kurt Schalapski , Norman Nowotny , Matthias Eisenacher , Dirk Bermann , Thorsten Kreickmann , Peter Heymanns , Heinz Strutz
发明人： Kurt Schalapski , Norman Nowotny , Matthias Eisenacher , Dirk Bermann , Thorsten Kreickmann , Peter Heymanns , Heinz Strutz
IPC分类号： C07C209/26
CPC分类号： C07B43/04 , B01J21/08 , B01J23/40 , B01J23/70 , B01J23/866 , C07C209/26 , C07C211/07
摘要： A continuous process for producing primary aliphatic amines having 9 to 18 carbon atoms by reaction of corresponding aliphatic aldehydes with ammonia and hydrogen in the presence of a hydrogenation catalyst in the liquid phase, characterized in that the reaction is carried out solventlessly at a molar ratio of aliphatic aldehyde:ammonia of at least 1:30, at a temperature of 100 to 200° C. and at a pressure of 6 to 11 MPa.
摘要翻译： 在液相中在氢化催化剂存在下，通过相应的脂族醛与氨和氢的反应制备具有9至18个碳原子的伯脂肪族胺的连续方法，其特征在于该反应以 脂肪醛：氨至少1:30，温度为100〜200℃，压力为6〜11MPa。
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公开(公告)号：US20130131391A1
公开(公告)日：2013-05-23
申请号：US13810723
申请日：2011-07-28
CPC分类号： C07C29/74 , C07C29/10 , C07C29/80 , C07C29/90 , C07C41/34 , C07C41/42 , C07C41/44 , C07C31/22 , C07C43/132
摘要： The present invention relates to a process for obtaining ditrimethylolpropane and trimethylolpropane-enriched product streams from the high-boiling fractions and residues which are obtained in the distillative purification of trimethylolpropane, wherein an aqueous solution of these fractions and residues is catalytically hydrogenated in the presence of an acidic compound and, after removing solids, contacted both with basic and with acidic ion exchangers. A trimethylolpropane-enriched product stream can be distilled out of the aqueous eluate obtained, leaving ditrimethylolpropane as the distillation residue.
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