摘要:
Oxidation product of polyarylene sulfides comprising recurring units of the formula.brket open-st.C.sub.6 H.sub.4 --S.brket close-st. (I)in the form of a compound comprising recurring units of the formula.brket open-st..paren open-st.C.sub.6 H.sub.4 --S.paren close-st..sub.a .paren open-st.C.sub.6 H.sub.4 --SO.paren close-st..sub.b .brket close-st.(II)in which the sulfur/oxygen ratio is from 1:0.1 to 1:1, the sum of a and b always being 1 and a and b each being greater than zero or with the proviso that a is zero if b is 1.
摘要:
Process for oxidizing a polymer containing thioether groups, in which the polymer in solid form in a suspension medium is oxidized with ozone. The polymer obtained is suitable for the production of functional parts on which high demands are made.
摘要:
A filter material based on a polyarylene thioether having repeating units of the formula--[(Ar.sup.1).sub.n --X)].sub.m --[(Ar.sup.2).sub.i --Y)].sub.j --[(Ar.sup.3).sub.k --Z)].sub.l --[(Ar.sup.4).sub.o --W)].sub.p --(I)in which Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4, W, X, Y and Z, independently of each other, are identical or different, the indices n, m, i, j, k, l, o and p, independently of each other, are zero or integers 1, 2, 3 or 4, their sum being at least 2, Ar.sup.1, Ar.sup.2, Ar.sup.3 and Ar.sup.4 are arylene systems having 6 to 18 carbon atoms, and W, X, Y and Z are divalent linking groups, selected from --SO.sub.2 --, --S--, --SO--, --CO--, --O--, --CO.sub.2 --, or alkylene groups or alkylidene groups having 1 to 6 carbon atoms is suitable for removing ozone from gases or liquids. The removal proceeds quantitatively, no volatile products being formed.
摘要翻译:基于具有式[[(Ar 1)n X)] m - [(Ar 2)i Y)] j - [(Ar 3)k Z)] - [(Ar 4)o W)] p]的重复单元的聚芳硫醚的过滤材料 - (I)其中Ar1,Ar2,Ar3,Ar4,W,X,Y和Z彼此独立地相同或不同,指数n,m,i,j,k,l,o和p, 彼此独立,为零或整数1,2,3或4,它们的和为至少2,Ar 1,Ar 2,Ar 3和Ar 4为具有6至18个碳原子的亚芳基体系,W,X,Y和Z分别为 选自-SO 2 - , - S - , - SO - , - CO - , - O - , - CO 2 - 或具有1至6个碳原子的亚烷基或亚烷基的二价连接基团适用于从气体或 液体。 清除量定量进行,不形成挥发性物质。
摘要:
A method for removing oxides of nitrogen from gases and liquids by contacting a NO.sub.x containing gas or liquid with a polyarylene thioether filter material and a solid oxidizing agent having an electron potential greater than 0.96 V, wherein the solid oxidizing agent oxidizes NO into NO.sub.2 which is removed by the polyarylene thioether filter material.
摘要:
Fluorine-substituted vicinal glycols of the formula ##STR1## in which the substituents R.sub.1 to R.sub.4, independently of one another, have the following meanings: R.sub.1 to R.sub.4 =H, fluorine, C.sub.1 - to C.sub.18 -alkyl in which some or all of the hydrogens may be substituted by fluorine, and at least one of the substituents R.sub.1 to R.sub.4 is a completely fluorinated alkyl or an alkyl of the formula--(CH.sub.2).sub.m --(C.sub.n F.sub.2n+1),in which m is 1 or 2, and n is an integer from 1 to 17, and x is 0 or 1.Furthermore, a method for the preparation of the fluorinated vicinal glycols is described. If the fluorinated vicinal glycols are condensed together with dicarboxylic acids, products having enhanced thermal stability are obtained.
摘要:
A foamed polyarylene sulfide according to the invention has a density which is reduced by at least 50% compared with the theoretical density of nonfoamed material, and is expediently produced by subjecting a polyarylene sulfoxide as such or a mixture of one or more polyarylene sulfides with a polyarylene sulfoxide to heat treatment. The temperature of the heat treatment is in the range from 250.degree. to 400.degree. C.
摘要:
Fluorine-substituted epoxides of the formula ##STR1## in which the substituents R.sub.1 to R.sub.4, independently of one another, have the following meanings:R.sub.1 to R.sub.4 =H, fluorine, C.sub.1 - to C.sub.18 -alkyl in which some or all of the hydrogens may be substituted by fluorine, and at least one of the substituents R.sub.1 to R.sub.4 is a completely fluorinated alkyl or an alkyl of the formula--(CH.sub.2).sub.m --(C.sub.n F.sub.2n+1),in which m is 1 or 2, and n is an integer from 1 to 17, and x is 0 or 1.Furthermore, a method for the preparation of fluorine-substituted epoxides is described.
摘要:
An abrasion-resistant fluoropolymer mixture comprising(A) from 75 to 99% by weight of a fluorocarbon polymer(B) from 1 to 25% by weight of an oxidized polyarylene sulfide and, based on the sum (A)+(B),(C) from 0 to 15% by weight of a filler,is used for the production of feed pipes for Bowden cables which are pressure-resistant and abrasion-resistant.
摘要:
A foamed polyarylene sulfide according to the invention has a density which is reduced by at least 50% compared with the theoretical density of nonfoamed material, and is expediently produced by subjecting a polyarylene sulfoxide as such or a mixture of one or more polyarylene sulfides with a polyarylene sulfoxide to heat treatment. The temperature of the heat treatment is in the range from 250.degree. to 400.degree. C.
摘要:
Mixtures of fluoropolymers and oxidized polyarylene sulfides A polymer mixture of A) at least one fluoropolymer in a proportion of from 50 to 99% by weight and B) at least one polyarylene sulfone or polyarylene compound containing at least two of the bridges --S--, --SO-- and --SO.sub.2 -- or a mixture of the two in a proportion of from 1 to 50% by weight, where the sum of components A) and B) is always 100% by weight. This mixture is used for the production of sliding bearings or gasket materials having a reduced tendency to creep and reduced abrasion.