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    Electrodepositable coating composition containing diorganotin dicarboxylates
    4.
    发明授权
    Electrodepositable coating composition containing diorganotin dicarboxylates 失效
    含有二羧酸二有机锡的电沉积涂料组合物

    公开(公告)号：US5630922A

    公开(公告)日：1997-05-20

    申请号：US578821

    申请日：1995-12-26

    申请人： Venkatachalam Eswarakrishnan ,  Robert R. Zwack ,  Gregory J. McCollum ,  Raphael O. Kollah ,  Steven R. Zawacky

    发明人： Venkatachalam Eswarakrishnan ,  Robert R. Zwack ,  Gregory J. McCollum ,  Raphael O. Kollah ,  Steven R. Zawacky

    IPC分类号： C08G18/24 ,  C09D5/44 ,  C25D13/00 ,  C08L63/00 ,  C25D15/00

    CPC分类号： C08G18/246 ,  C09D5/4457 ,  C09D5/4492

    摘要： An electrodepositable composition is provided comprising (a) an active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (b) a capped polyisocyanate curing agent; and (c) a diorganotin dicarboxylate; wherein the dicarboxylate is at least one long chain carboxylate having from 14 to 22 carbon atoms and the diorganotin dicarboxylate is present in the electrodepositable composition in an amount of at least 0.01 percent by weight tin based on weight of total solids of the electrodepositable composition. The composition provides improved storage stability without precipitation of dibutyltin oxide, and when electrodeposited over conductive substrates, there is no loss of cure response and appearance properties.

    摘要翻译： 提供一种电沉积组合物，其包含（a）可阴极电解的含活性氢阳离子盐基树脂; （b）封端的多异氰酸酯固化剂; 和（c）二有机锡二羧酸酯; 其中所述二羧酸酯是至少一种具有14至22个碳原子的长链羧酸盐，并且所述可电沉积组合物中的二有机锡二羧酸盐以基于所述可电沉积组合物的总固体重量的至少0.01重量％的锡存在。 该组合物提供改善的储存稳定性而不沉淀二丁基氧化锡，并且当电沉积在导电性基材上时，不会有固化反应和外观性能的损失。

    Electrodepositable coating compositions containing hydroxamic acid and derivatives thereof, and their use in a method of electrodeposition
    7.
    发明授权
    Electrodepositable coating compositions containing hydroxamic acid and derivatives thereof, and their use in a method of electrodeposition 失效
    含有异羟肟酸及其衍生物的电沉积涂料组合物及其在电沉积方法中的用途

    公开(公告)号：US5804051A

    公开(公告)日：1998-09-08

    申请号：US705480

    申请日：1996-08-29

    申请人： Donald W. Boyd ,  Robert R. Zwack ,  Raphael O. Kollah ,  Gregory J. McCollum

    发明人： Donald W. Boyd ,  Robert R. Zwack ,  Raphael O. Kollah ,  Gregory J. McCollum

    IPC分类号： C08G18/16 ,  C09D5/44 ,  C25D13/06 ,  C25D13/10

    CPC分类号： C09D5/4492 ,  C08G18/161 ,  Y10S524/901

    摘要： An electrodepositable composition is provided comprising: (a) active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (b) at least one at least partially capped polyisocyanate curing agent; (c) at least one metal-containing catalyst; and (d) at least one material having the following general formula: ##STR1## wherein R.sub.1 is alkyl or substituted alkyl having 1 to 18 carbon atoms or aryl or substituted aryl; and R.sub.2 is hydrogen, alkyl or substituted alkyl having 1 to 18 carbon atoms or aryl or substituted aryl. The composition can demonstrate enhanced corrosion resistance at low metal catalyst levels without loss of cured film properties or appearance when electrodeposited and cured over conductive substrates.

    摘要翻译： 提供了一种可电沉积的组合物，其包含：（a）可电沉积在阴极上的含活性氢的阳离子盐基树脂; （b）至少一种至少部分封端的多异氰酸酯固化剂; （c）至少一种含金属的催化剂; 和（d）具有以下通式的至少一种材料：其中R1是具有1至18个碳原子的烷基或取代的烷基或芳基或取代的芳基; 并且R 2是氢，具有1至18个碳原子的烷基或取代的烷基或芳基或取代的芳基。 组合物可以在低金属催化剂水平下显示增强的耐腐蚀性，而在电沉积和固化在导电基材上时不损失固化膜性质或外观。

    Electrodepositable coating compositions and related methods
    9.
    发明授权
    Electrodepositable coating compositions and related methods 有权
    电沉积涂料组合物及相关方法

    公开(公告)号：US08168700B2

    公开(公告)日：2012-05-01

    申请号：US12346933

    申请日：2008-12-31

    申请人： Venkatachalam Eswarakrishnan ,  Alan J. Kaylo ,  Gregory J. McCollum ,  Ellor James Van Buskirk

    发明人： Venkatachalam Eswarakrishnan ,  Alan J. Kaylo ,  Gregory J. McCollum ,  Ellor James Van Buskirk

    IPC分类号： C08L63/00

    CPC分类号： C08G18/242 ,  C08G18/0814 ,  C08G18/58 ,  C08G18/643 ,  C08G18/8012 ,  C08G18/8019 ,  C08G18/8064 ,  C09D5/4457 ,  C09D5/4492

    摘要： Provided is an electrodepositable coating composition of a resinous phase dispersed in an aqueous medium, the resinous phase including (a) an active hydrogen-containing, cationic salt group-containing resin; and (b) an at least partially blocked polyisocyanate curing agent. The composition contains an organotin catalyst which is or is derived from a dialkyltin compound having the structure (I): [R1][R2]—Sn═O  (I) where R1 and R2 are the same or different, and each independently represents a monovalent hydrocarbon group wherein the sum of the carbon atoms in R1 and R2 is greater than 8. The catalyst is present in an amount sufficient to effect cure at a temperature at or below 340° F. (171.1° C.). Methods of preparing and using the composition also are provided.

    摘要翻译： 提供了一种分散在水性介质中的树脂相的可电沉积涂料组合物，该树脂相包括（a）含活性氢阳离子盐基的树脂; 和（b）至少部分封闭的多异氰酸酯固化剂。 该组合物含有有机锡催化剂，其为具有结构（I）的二烷基锡化合物或其衍生自：其中R 1和R 2相同或不同的[R 1] [R 2] -Sn = O（I），并且各自独立地表示 其中R 1和R 2中的碳原子之和大于8的一价烃基。催化剂的存在量足以在340°F（或171.1℃）或更低的温度下进行固化。 还提供了制备和使用该组合物的方法。

    Electrodepositable coating compositions and related methods
    10.
    发明授权
    Electrodepositable coating compositions and related methods 有权
    电沉积涂料组合物及相关方法

    公开(公告)号：US07497936B2

    公开(公告)日：2009-03-03

    申请号：US10677019

    申请日：2003-10-01

    申请人： Venkatachalam Eswarakrishnan ,  Alan J. Kaylo ,  Gregory J. McCollum ,  Ellor James Van Buskirk

    发明人： Venkatachalam Eswarakrishnan ,  Alan J. Kaylo ,  Gregory J. McCollum ,  Ellor James Van Buskirk

    IPC分类号： C25D13/10

    CPC分类号： C08G18/242 ,  C08G18/0814 ,  C08G18/58 ,  C08G18/643 ,  C08G18/8012 ,  C08G18/8019 ,  C08G18/8064 ,  C09D5/4457 ,  C09D5/4492

    摘要： Provided is an electrodepositable coating composition of a resinous phase dispersed in an aqueous medium, the resinous phase including (a) an active hydrogen-containing, cationic salt group-containing resin; and (b) an at least partially blocked polyisocyanate curing agent. The composition contains an organotin catalyst which is or is derived from a dialkyltin compound having the structure (I): [R1][R2]—Sn═O  (I) where R1 and R2 are the same or different, and each independently represents a monovalent hydrocarbon group wherein the sum of the carbon atoms in R1 and R2 is greater than 8. The catalyst is present in an amount sufficient to effect cure at a temperature at or below 340° F. (171.1° C.). Methods of preparing and using the composition also are provided.

    摘要翻译： 提供了一种分散在水性介质中的树脂相的可电沉积涂料组合物，该树脂相包括（a）含活性氢阳离子盐基的树脂; 和（b）至少部分封闭的多异氰酸酯固化剂。 组合物含有有机锡催化剂，其是具有（I）结构的二烷基锡化合物或其衍生物：<？in-line-formula description =“In-line formula”end =“lead”？> [R1] [R2] -Sn-O（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R1和R2相同或不同，并且各自独立地表示一价烃基，其中总和 的R 1和R 2中的碳原子大于8.催化剂的存在量足以在340°F或低于340°F（171.1℃）的温度下进行固化。 还提供了制备和使用该组合物的方法。