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公开(公告)号：US4888131A
公开(公告)日：1989-12-19
申请号：US357233
申请日：1989-05-26
摘要： Synthesis gas is produced by the reaction of light hydrocarbons, primarily methane, in a fluid bed reaction zone of attrition resistant nickel on alpha-alumina catalyst, with steam and oxygen and the conversion level is preserved by limiting the loss of nickel from the reaction and thereby limiting the back reaction of the synthesis gas to form methane in the presence of entrained catalyst in a cooling zone.
摘要翻译： 合成气通过轻烃（主要是甲烷）在α-氧化铝催化剂上的耐磨镍的流化床反应区与蒸汽和氧气反应而产生，通过限制镍从反应中的损失来保持转化水平， 从而限制在冷却区中夹带催化剂存在下合成气的反作用形成甲烷。
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公开(公告)号：US4975180A
公开(公告)日：1990-12-04
申请号：US361617
申请日：1989-06-05
申请人： Paul E. Eberly
发明人： Paul E. Eberly
IPC分类号： B01J27/14 , B01J29/04 , B01J29/06 , B01J29/08 , B01J29/82 , B01J37/04 , C10G11/05 , C10G47/04 , C10G47/16
摘要： A catalytic cracking process is provided wherein a phosphorous containing alumina or an alkaline earth phosphorous containing alumina is added to a catalytic cracking zone for admixture with a zeolite containing cracking catalyst.
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公开(公告)号：US5314612A
公开(公告)日：1994-05-24
申请号：US982935
申请日：1992-11-30
申请人： Paul E. Eberly , William E. Winter
发明人： Paul E. Eberly , William E. Winter
CPC分类号： B01J29/80 , C10G11/05 , B01J2229/42 , B01J29/084 , B01J29/7007
摘要： Disclosed is a fluid catalytic cracking process for producing low emissions fuels. The feedstock is exceptionally low in nitrogen and aromatics and relatively high in hydrogen. The catalyst is a mixture of zeolite Y and zeolite beta (.beta.). The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.
摘要翻译： 公开了用于生产低排放燃料的流化催化裂化方法。 原料的氮气和芳烃特别低，氢气相对较高。 催化剂是沸石Y和沸石β（β）的混合物。 原料可以表征为具有小于约50wppm氮; 大于约13重量％ ％氢; 小于约7.5重量％ ％2+环芳烃芯; 并且不超过约15wt。 ％芳香核心总体。
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4.发明授权
公开(公告)号：US5348642A
公开(公告)日：1994-09-20
申请号：US16398
申请日：1993-02-11
CPC分类号： C10G11/18
摘要： A catalytic cracking process and apparatus wherein particles of cracking catalyst circulate continuously between a reaction zone and a regeneration zone and hot regenerated catalyst from the regeneration zone contacts hydrocarbon feed in the reaction zone to produce cracked hydrocarbon products and spent catalyst. The spent catalyst is recovered and subjected to stripping in a stripping zone to remove strippable material therefrom. The stripped spent catalyst is circulated to the regeneration zone for oxidative exothermic regeneration. Some hot regenerated catalyst is passed directly from the regenerator to the stripping zone via a conduit provided for this purpose. Another hydrocarbon stream is passed into contact with the hot regenerated catalyst in this conduit. The said other hydrocarbon stream is converted to products of enhanced value (e.g., olefins) during contact with catalyst in the conduit, and the said products are recovered. The heat for the conversion is abstracted from the catalyst particles passing via the pipe to the stripping zone. The hot catalyst particles entering the stripping zone from the pipe increase the temperature in the stripping zone, thereby improving the stripping in the stripping zone.
摘要翻译： 一种催化裂化方法和装置，其中裂化催化剂颗粒在反应区和再生区之间连续循环，再生区再热催化剂与反应区中的烃进料接触，产生裂化烃产物和废催化剂。 将废催化剂回收并在汽提区中进行汽提以从其中除去可剥离材料。 汽提的废催化剂循环到再生区进行氧化放热再生。 一些热再生催化剂通过为此目的提供的导管从再生器直接通入汽提区。 使另一种烃流与该导管中的热再生催化剂接触。 所述其它烃流在与导管中的催化剂接触期间被转化为具有增强价值的产物（例如烯烃），并且回收所述产物。 用于转化的热量从通过管道的催化剂颗粒抽吸到汽提区。 从管道进入汽提区的热催化剂颗粒增加汽提区的温度，从而改善汽提区的汽提。
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公开(公告)号：US5318695A
公开(公告)日：1994-06-07
申请号：US982933
申请日：1992-11-30
CPC分类号： C10G11/05
摘要： A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is exceptionally low in nitrogen and aromatics and relatively high in hydrogen. The catalyst is an amorphous silica-alumina or a zeolitic material having a relatively small unit cell size. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.
摘要翻译： 用于生产相对低排放燃料的流化催化裂化方法。 原料的氮气和芳烃特别低，氢气相对较高。 该催化剂是具有相对小的晶胞尺寸的无定形二氧化硅 - 氧化铝或沸石材料。 原料可以表征为具有小于约50wppm氮; 大于约13重量％ ％氢; 小于约7.5重量％ ％2 +环芳烃芯; 并且不超过约15wt。 ％芳香核心总体。
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公开(公告)号：US4977122A
公开(公告)日：1990-12-11
申请号：US361892
申请日：1989-06-05
申请人： Paul E. Eberly
发明人： Paul E. Eberly
CPC分类号： B01J29/084 , B01J29/04 , C10G11/05 , B01J2229/42 , B01J29/82
摘要： A catalyst is provided which comprises a crystalline zeolite, discrete particles of phosphorus containing alumina, particularly an alkaline earth metal phosphate containing alumina, dispersed in a non-zeolitic inorganic oxide matrix. A catalytic cracking process utilizing the catalyst is also provided. Such phosphate treated catalysts exhibit increased attrition resistance.
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公开(公告)号：US3981794A
公开(公告)日：1976-09-21
申请号：US531061
申请日：1974-12-09
申请人： Paul E. Eberly
发明人： Paul E. Eberly
CPC分类号： C10G35/09 , B01J23/6522 , C07C5/417
摘要： A process for converting hydrocarbons to aromatic compounds comprising contacting a paraffinic or olefinic hydrocarbon feedstream, without added hydrogen, with a catalyst comprising from about 0.05 to about 5% of palladium metal and from about 0.1 up to 2% chromium oxides composited with a high surface area support. A preferred process is one for aromatization of such feeds by contact with a catalyst comprised of from about 0.05 to about 5% of palladium metal, from about 0.1 to less than 2% chromium oxide and up to about 4.5% by weight of an alkali metal oxide incorporated therewith to increase the aromatization activity of the catalyst. Catalysts used in accordance with the present invention comprise compositions which include from about 0.05 to about 5% palladium, from about 0.01 to less than 2% chromium oxides and up to about 4.5% of an alkali metal oxide.
摘要翻译： 一种将烃转化为芳族化合物的方法，包括使不含添加氢的链烷烃或烯烃进料流与包含约0.05至约5％的钯金属的催化剂和约0.1至2％的与高表面复合的铬氧化物 区域支持。 优选的方法是通过与由约0.05至约5％的钯金属，约0.1至小于2％的氧化铬和至多约4.5重量％的碱金属的催化剂接触来进行这种进料的芳构化 氧化物，以增加催化剂的芳构化活性。 根据本发明使用的催化剂包括包含约0.05至约5％钯，约0.01至小于2％的氧化铬和至多约4.5％的碱金属氧化物的组合物。
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