公开(公告)号：US20230102416A1

公开(公告)日：2023-03-30

申请号：US17563421

申请日：2021-12-28

申请人： East China University of Science and Technology

发明人： Yanqin WANG ,  Wanjun GUO ,  Shuang XIANG ,  Xiaohui LIU ,  Yong GUO

IPC分类号： B01J23/75 ,  C07C209/78 ,  B01J35/00 ,  B01J37/18 ,  B01J37/03 ,  B01J37/08 ,  B01J23/83 ,  B01J23/882 ,  B01J23/78

摘要： Disclosed is a method for efficiently synthesizing primary amines, which comprises using carbonyl compounds or alcohol compounds as reaction substrate, liquid ammonia or alcohol solutions of ammonia as nitrogen source, and hydrogen as hydrogen source, and reacting in reaction medium catalyzed by a cobalt-based catalyst to obtain the primary amines. Due to high catalytic activity, the method can realize the reductive amination of carbonyl compounds and the hydrogen-borrowing amination of alcohol compounds at low temperatures in a short time to obtain the primary amines with high yield, and is applicable to a wide range of substrates. The obtained primary amines can be used as raw materials with high extra value for producing polymers, medicines, dyes and surfactants. Further, the cobalt-based catalyst has a good industrial application prospect because it is magnetic which can facilitate separation and recycling of the catalyst. Moreover, the inexpensive cobalt-based catalyst can significantly reduce industrialization cost.

公开(公告)号：US20220002216A1

公开(公告)日：2022-01-06

申请号：US17403321

申请日：2021-08-16

申请人： East China University of Science and Technology

发明人： Yanqin WANG ,  Yaxuan JING ,  Yong GUO ,  Xiaohui LIU ,  Ning YAN

IPC分类号： C07C4/06 ,  C07C1/20 ,  C07C1/32

摘要： Disclosed is a method for preparing aromatic hydrocarbons by hydrocracking a polymer containing aromatic rings, which includes reacting the polymer fragment with hydrogen under the action of a catalyst at a temperature of no more than 350° C.; separating a reaction product to obtain the aromatic hydrocarbons. The catalyst comprises a carrier and an active ingredient supported on the carrier, the active ingredient is at least one selected from Ru, Rh, Pt, Pd, Fe, Ni, Cu and Co, the carrier is at least one selected from metal oxide, phosphate, molecular sieve, SiO2 and sulfonated carbon, the metal oxide is at least one selected from Al2O3, Nb2O5, Nb2O5—Al2O3, Nb2O5—SiO2, TiO2, ZrO2, CeO2 and MoO3; the phosphate is at least one selected from NbOPO4 and ZrOPO4; and the molecule sieve is at least one selected from Nb-SBA-15, Nafion, H-ZSM-5, H-Beta and H-Y.

公开(公告)号：US20160168473A1

公开(公告)日：2016-06-16

申请号：US14907327

申请日：2013-07-24

申请人： EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY

发明人： Yanqin WANG ,  Qineng XIA ,  Yu ZHANG ,  Guanzhong LU ,  Jiawen REN ,  Xiaohui LIU ,  Xueqing GONG ,  Yun GUO ,  Yanglong GUO ,  Junsong WANG ,  Zhigang ZHANG ,  Wangcheng ZHAN

IPC分类号： C10G1/06 ,  B01J23/652 ,  C07C29/00 ,  B01J29/48 ,  C10G1/02 ,  C07D313/04 ,  B01J27/053 ,  B01J23/89

CPC分类号： C10G1/06 ,  B01J23/6527 ,  B01J23/8926 ,  B01J27/053 ,  B01J29/48 ,  C07C29/00 ,  C07D313/04 ,  C10G1/02 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G2300/44 ,  Y02P30/20

摘要： Methods and systems for producing one or more alkanes from biomass by hydrodeoxygenation are disclosed. Biomass may be converted to one or more alkanes by heating the biomass with a catalyst mixture that includes a noble metal and at least one of a transition metal and derivative thereof. The catalyst mixture may further include a solid acid. Heating may be performed at a single temperature and pressure.

摘要翻译： 公开了通过加氢脱氧从生物质生产一种或多种烷烃的方法和系统。 通过用包括贵金属和过渡金属及其衍生物中的至少一种的催化剂混合物加热生物质，可以将生物质转化为一种或多种烷烃。 催化剂混合物还可以包括固体酸。 可以在单个温度和压力下进行加热。