公开(公告)号：US3585252A

公开(公告)日：1971-06-15

申请号：US3585252D

申请日：1969-01-17

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KENNEDY JOSEPH P

IPC: C07C1/32 ,  C07C9/00

CPC classification number: C07C1/327 ,  Y10S585/935

Abstract: HIGHLY BRANCHED HYDROCARBONS SUITABLE AS HIGH-OCTANE FUELS CAN BE OBTAINED RAPIDLY AND EFFICIENTLY BY A COUPLING REACTION IN WHICH REACTIVE ORGANO-HALIDES ARE CONTACTED WITH AN ORGANO ALUMINUM, UNDER REACTION CONDITIONS, IN A NON-REACTIVE SOLVENT.

公开(公告)号：US3646166A

公开(公告)日：1972-02-29

申请号：US3646166D

申请日：1970-05-27

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： CANTER NATHAN H ,  KENNEDY JOSEPH P

IPC: C08F255/10 ,  C08F15/00 ,  C08F19/00

CPC classification number: C08F255/10

Abstract: IONIC CROSSLINKIN IS INTRODUCED INTO AN UNCURED BUTYLRUBBER BY HFALOGENATION OF BUTYL RUBBER, DEHYDROHALOGENATION TO FORM CONJUGATED DOUBLE BONDS AND REACTION OF AN ETHYLENICALLY UNSATURATED COMPOUND SUCH AS MALEIC ANHYDRIDE WITH THIS CONJUGATED DOUBLE BOND SYSTEM TO FORM A GRAFT POLYMER. THE GRAFT POLYMER IN THEN REACTED WITH A METALLIC SALT OR AN AMINE TO FORM AN IONIC HYDROCARBON POLYMER USEFUL FOR MOLDED OR EXTRUDED PRODUCTS.

公开(公告)号：US3560459A

公开(公告)日：1971-02-02

申请号：US3560459D

申请日：1969-04-14

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KENNEDY JOSEPH P

IPC: C08F36/04 ,  C08D1/14 ,  C08D3/04 ,  C08D3/06

CPC classification number: C08F36/04 ,  Y10S526/907 ,  C08F4/7096

Abstract: A CATALYST IS PREPARED BY REACTING ALKYL ALUMINUM DIHALIDE IN THE ABSENCE OF A HYDROCARBON SOLVENT, WITH A COBALT SALT TO FORM A BLUE LIQUID COMPLEX. THE CATALYST SO FORMED MAY BE USED TO PREPARE HIGHLY UNSATURATED POLYMERS AND COPOLYMERS OF CATIONICALLY POLYMERIZABLE MONOMERS. THE POLYMERS OF THIS INVENTION ARE RUBBERY HIGH MOLECULAR WEIGHT MATERIALS. THE PREFERRED MONOMERS ARE ISOBUTYLENE AND ISOPRENE. THE PREFERRED ALKYL ALUNIMUM HALIDE IS ALUMINUM ETHYL DIHALIDE AND THE PREFERRED COBALT SALTS ARE COCL2 COBALT BROMIDE AND COBALT ACETONYL ACETONATE.

公开(公告)号：US3484423A

公开(公告)日：1969-12-16

申请号：US3484423D

申请日：1966-01-28

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： BORZEL PAUL ,  KENNEDY JOSEPH P

IPC: C08F8/20 ,  C08F27/03

CPC classification number: C08F8/20 ,  C08F10/00

公开(公告)号：US3694377A

公开(公告)日：1972-09-26

申请号：US3694377D

申请日：1970-12-02

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KENNEDY JOSEPH P ,  BALDWIN FRANCIS P

IPC: C08F10/00 ,  C08F10/10 ,  C08D3/02

CPC classification number: C08F10/00 ,  C08F10/10 ,  C08F4/06 ,  C08F4/14 ,  C08F4/00 ,  C08F4/52

Abstract: A CATALYST SYSTEM FOR PREPARING HOMOPOLYMERS AND COPOLYMERS OF CATIONICALLY POLYMERIZABLE MONOMERS WHEREIN THE CATALYST SYSTEM COMPRISES AN ORGANIC HALIDE PROMOTER AND A CATIONIC CATALYST OF THE TYPE AL(M)2R, WHERE M IS A BRANCHED OR STRAIGHT-CHAIN C1 TO C12 ALKYL AND R IS M, HYDROGEN OR HALOGEN. THE ORGANIC HALIDE MAY BE REPRESENTED BY THE GENERAL FORMULA

R1-C(-R2)(-R3)-X

WHEREIN X IS HALOGEN, R1 IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, C1 TO C8 ALKYL, PHENYL AND C2 TO C8 ALKENYL, R3 IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, C1 TO C8 ALKYL, PHENYL, C2 TO C8 ALKENYL AND PHENYLALKYL AND R2 IS SELECTED FROM THE GROUP CONSISTING OF C2 TO C8 ALKYL, C2 TO C8 ALKENYL, PHENYL, PHENYLALKYL, ALKYLPHENYL, C3 TO C10 CYCLOALKYL AND

R1-C(-X)(-R3)-R4-

WHEREIN R1, R3 AND X ARE S DEFINED ABOVE AND R4 IS SELECTED FROM THE GROUP CONSISTING OF PHENYLENE, BIPHENYL, A,W-DIPHENYLALKANE AND -(CH2)N-, WHEREIN N IS AN INTEGER OF FROM 1 TO 10.

公开(公告)号：US3426007A

公开(公告)日：1969-02-04

申请号：US3426007D

申请日：1965-10-21

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KENNEDY JOSEPH P

IPC: C08F10/00 ,  C08F1/28 ,  C08F3/02 ,  C08F15/04

CPC classification number: C08F10/00 ,  C08F4/14

公开(公告)号：US3346514A

公开(公告)日：1967-10-10

申请号：US39338964

申请日：1964-08-31

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： ISAACSON ROBERT B ,  KENNEDY JOSEPH P

IPC: C08G61/02

CPC classification number: C08G61/02

公开(公告)号：US3299028A

公开(公告)日：1967-01-17

申请号：US28288463

申请日：1963-05-24

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KENNEDY JOSEPH P

IPC: C08F10/00

CPC classification number: C08F10/00 ,  C08F4/00

公开(公告)号：US3928297A

公开(公告)日：1975-12-23

申请号：US45710974

申请日：1974-04-01

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： THALER WARREN A ,  BUCKLEY DONALD J ,  KENNEDY JOSEPH P

IPC: C08F210/12 ,  C08L23/22

CPC classification number: C08L23/22 ,  C08F210/12 ,  C08F4/14

Abstract: Substantially gel-free, high molecular weight, high unsaturation copolymers of isobutylene and conjugated dienes having a number average molecular weight of at least 120,000 and a mole percent of unsaturation of at least 5 percent and the process for preparing said polymers which comprises carrying out the polymerization in a homogeneous phase, introducing the catalyst comprising an aluminum halide to the system in a soluble form and carrying the reaction out at a temperature of less than -100*C.

Abstract translation: 具有数均分子量至少为120,000，不饱和摩尔百分数至少为5％的异丁烯和共轭二烯的基本无凝胶的高不饱和共聚物以及制备所述聚合物的方法包括进行 在均相中聚合，将包含卤化铝的催化剂以可溶形式引入体系，并在小于-100℃的温度下进行反应。

公开(公告)号：US3560458A

公开(公告)日：1971-02-02

申请号：US3560458D

申请日：1968-03-13

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KENNEDY JOSEPH P ,  BALDWIN FRANCIS P

IPC: C08F2/00 ,  C08F10/10 ,  C08F36/04 ,  C08F210/12 ,  C08D3/02

CPC classification number: C08F36/04 ,  C08F10/10 ,  C08F210/12 ,  C08F4/06 ,  C08F4/52 ,  C08F4/00

Abstract: A CATALYST SYSTEM FOR PREPARING HOMOPOLMERS AND COPOLYMERS OF CATIONICALLY POLYMERIZABLE MONOMERS WHEREIN THE CATALYST SYSTEM COMPRISES AN ORGANIC HALIDE COCATALYST AND A CATIONIC CATALYST OF THE TYPE AL(M)2R, WHERE M IS A BRANCHED OR STRAIGHT-CHAIN C1 TO C12 ALKYL AND R IS M, HYDROGEN OR HALOGEN.