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公开(公告)号:US20100292350A1
公开(公告)日:2010-11-18
申请号:US12778538
申请日:2010-05-12
IPC分类号: C07C27/00
CPC分类号: C10J3/00 , C01B32/40 , C01B32/50 , C10G2/32 , C10G2300/207 , C10G2300/805 , C10G2300/807 , C10J3/482 , C10J3/721 , C10J3/84 , C10J3/86 , C10J2300/0959 , C10J2300/0973 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1678 , C10J2300/1687 , C10J2300/1807 , C10J2300/1846 , C10J2300/1884 , C10J2300/1892 , C10K1/003 , C10K1/004 , C10K1/04 , C10K1/101 , C10K1/102 , C10K1/14 , C10K1/143 , C10K1/16 , C10K1/165 , C10K1/20 , C10K1/32 , C10K3/04 , C10L3/08
摘要: The present invention relates to processes for preparing gaseous products, and in particular methane, via the catalytic hydromethanation of a carbonaceous feedstock in the presence of steam, syngas and an oxygen-rich gas stream.
摘要翻译: 本发明涉及通过在蒸汽,合成气和富氧气流的存在下通过碳质原料的催化氢化来制备气态产物,特别是甲烷的方法。
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2.
公开(公告)号:US08502007B2
公开(公告)日:2013-08-06
申请号:US12562919
申请日:2009-09-18
申请人: Edwin J. Hippo , Vincent G. Reiling , Earl T. Robinson , Pattabhi K. Raman , Jeffery Smith , Charles Mims , Nicholas Charles Nahas
发明人: Edwin J. Hippo , Vincent G. Reiling , Earl T. Robinson , Pattabhi K. Raman , Jeffery Smith , Charles Mims , Nicholas Charles Nahas
IPC分类号: C07C1/04
CPC分类号: C10J3/00 , B01J21/18 , B01J21/20 , B01J23/04 , B01J23/92 , B01J35/0026 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J37/009 , B01J37/0201 , B01J38/72 , C10J3/482 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10L3/08 , Y02P20/52 , Y02P20/584
摘要: The invention provides processes for generating a methane-enriched gas from a gas mixture comprising carbon monoxide and hydrogen such as gas streams generated by gasification of an alkali metal catalyst-loaded carbonaceous feedstock, and a char methanation catalyst useful in such processes.
摘要翻译: 本发明提供从包含一氧化碳和氢气的气体混合物产生富甲烷气体的方法,例如通过加载载有碱金属催化剂的碳质原料气化产生的气流,以及可用于这些方法的焦炭甲烷化催化剂。
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公开(公告)号:US08647402B2
公开(公告)日:2014-02-11
申请号:US12562922
申请日:2009-09-18
申请人: Earl T. Robinson , Francis S. Lau , Pattabhi K. Raman , Vincent G. Reiling , Dwain Dodson , Mustafiz Rahman , Nicholas Charles Nahas
发明人: Earl T. Robinson , Francis S. Lau , Pattabhi K. Raman , Vincent G. Reiling , Dwain Dodson , Mustafiz Rahman , Nicholas Charles Nahas
IPC分类号: B23K35/38
CPC分类号: C10J3/00 , C01B3/586 , C01B2203/0445 , C01B2203/047 , C10G2/32 , C10J3/482 , C10J3/721 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10L3/08 , C10L3/102 , C10L9/10
摘要: The present invention relates to processes and continuous processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam. In one aspect of the invention, the processes comprise at least partially combusting a first carbonaceous feedstock with an oxygen-rich gas stream in an oxygen-blown gasifier, under suitable temperature and pressure, to generate a first gas stream comprising hydrogen, carbon monoxide and superheated steam; and reacting a second carbonaceous feedstock and the first gas stream in a catalytic gasifier in the presence of a gasification catalyst under suitable temperature and pressure to form a second gas stream comprising a plurality of gaseous products comprising methane, carbon dioxide, hydrogen, carbon monoxide and hydrogen sulfide. The processes can comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and in certain embodiments do not recycle carbon monoxide or hydrogen to the gasifier.
摘要翻译: 本发明涉及用于在蒸汽存在下通过碳质原料的催化气化来制备气态产物,特别是甲烷的方法和连续方法。 在本发明的一个方面,该方法包括在合适的温度和压力下,在吹氧气化器中至少部分地将第一含碳原料与富氧气流一起燃烧,以产生包含氢气,一氧化碳和 过热蒸汽 以及在气化催化剂存在下,在合适的温度和压力下使催化气化器中的第二碳质原料与第一气流反应,形成第二气流,其包含多个包含甲烷,二氧化碳,氢气,一氧化碳和 硫化氢。 该方法可以包括使用至少一种催化甲烷化器将气态产物中的一氧化碳和氢气转化成甲烷,并且在某些实施方案中不将一氧化碳或氢气循环到气化器。
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公开(公告)号:US20100179232A1
公开(公告)日:2010-07-15
申请号:US12604695
申请日:2009-10-23
CPC分类号: C10J3/00 , C01B3/12 , C01B3/52 , C01B3/586 , C01B2203/0415 , C01B2203/0445 , C01B2203/047 , C01B2203/0475 , C01B2203/0485 , C10J3/721 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1807 , C10J2300/1884 , C10J2300/1892 , C10K3/04 , C10L3/08 , C10L3/102
摘要: The present invention relates to processes and continuous processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam. In one aspect of the invention, the processes comprise at least partially combusting a first carbonaceous feedstock with an oxygen-rich gas stream, a recycle steam stream, and an aqueous make-up stream in an oxygen-blown gasifier, under suitable temperature and pressure, to generate a first gas stream comprising hydrogen, carbon monoxide and superheated steam; and reacting a second carbonaceous feedstock and the first gas stream in a catalytic gasifier in the presence of a gasification catalyst under suitable temperature and pressure to form a second gas stream comprising a plurality of gaseous products comprising methane, carbon dioxide, hydrogen, carbon monoxide and hydrogen sulfide. The processes can comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and in certain embodiments do not recycle carbon monoxide or hydrogen to the gasifier. Heat energy recovered from the catalytic gasification can be used to generate the recycle steam stream.
摘要翻译: 本发明涉及用于在蒸汽存在下通过碳质原料的催化气化来制备气态产物,特别是甲烷的方法和连续方法。 在本发明的一个方面,所述方法包括在合适的温度和压力下,在吹氧气化器中至少部分地燃烧第一含碳原料与富氧气流,再循环蒸汽流和含水补充料流 以产生包含氢气,一氧化碳和过热蒸汽的第一气流; 以及在气化催化剂存在下,在合适的温度和压力下使催化气化器中的第二碳质原料与第一气流反应,形成第二气流,其包含多个包含甲烷,二氧化碳,氢气,一氧化碳和 硫化氢。 该方法可以包括使用至少一种催化甲烷化器将气态产物中的一氧化碳和氢气转化成甲烷,并且在某些实施方案中不将一氧化碳或氢气循环到气化器。 从催化气化回收的热能可用于产生再循环蒸汽流。
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公开(公告)号:US20100071262A1
公开(公告)日:2010-03-25
申请号:US12562922
申请日:2009-09-18
申请人: Earl T. Robinson , Francis S. Lau , Pattabhi K. Raman , Vincent G. Reiling , Dwain Dodson , Mustafiz Rahman , Nicholas Charles Nahas
发明人: Earl T. Robinson , Francis S. Lau , Pattabhi K. Raman , Vincent G. Reiling , Dwain Dodson , Mustafiz Rahman , Nicholas Charles Nahas
IPC分类号: C10L3/00
CPC分类号: C10J3/00 , C01B3/586 , C01B2203/0445 , C01B2203/047 , C10G2/32 , C10J3/482 , C10J3/721 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10L3/08 , C10L3/102 , C10L9/10
摘要: The present invention relates to processes and continuous processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam. In one aspect of the invention, the processes comprise at least partially combusting a first carbonaceous feedstock with an oxygen-rich gas stream in an oxygen-blown gasifier, under suitable temperature and pressure, to generate a first gas stream comprising hydrogen, carbon monoxide and superheated steam; and reacting a second carbonaceous feedstock and the first gas stream in a catalytic gasifier in the presence of a gasification catalyst under suitable temperature and pressure to form a second gas stream comprising a plurality of gaseous products comprising methane, carbon dioxide, hydrogen, carbon monoxide and hydrogen sulfide. The processes can comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and in certain embodiments do not recycle carbon monoxide or hydrogen to the gasifier.
摘要翻译: 本发明涉及用于在蒸汽存在下通过碳质原料的催化气化来制备气态产物,特别是甲烷的方法和连续方法。 在本发明的一个方面,该方法包括在合适的温度和压力下,在吹氧气化器中至少部分地将第一含碳原料与富氧气流一起燃烧,以产生包含氢气,一氧化碳和 过热蒸汽 以及在气化催化剂存在下,在合适的温度和压力下使催化气化器中的第二碳质原料与第一气流反应,形成第二气流,其包含多个包含甲烷,二氧化碳,氢气,一氧化碳和 硫化氢。 该方法可以包括使用至少一种催化甲烷化器将气态产物中的一氧化碳和氢气转化成甲烷,并且在某些实施方案中不将一氧化碳或氢气循环到气化器。
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公开(公告)号:US08268899B2
公开(公告)日:2012-09-18
申请号:US12778538
申请日:2010-05-12
IPC分类号: C07C27/00
CPC分类号: C10J3/00 , C01B32/40 , C01B32/50 , C10G2/32 , C10G2300/207 , C10G2300/805 , C10G2300/807 , C10J3/482 , C10J3/721 , C10J3/84 , C10J3/86 , C10J2300/0959 , C10J2300/0973 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1678 , C10J2300/1687 , C10J2300/1807 , C10J2300/1846 , C10J2300/1884 , C10J2300/1892 , C10K1/003 , C10K1/004 , C10K1/04 , C10K1/101 , C10K1/102 , C10K1/14 , C10K1/143 , C10K1/16 , C10K1/165 , C10K1/20 , C10K1/32 , C10K3/04 , C10L3/08
摘要: The present invention relates to processes for preparing gaseous products, and in particular methane, via the catalytic hydromethanation of a carbonaceous feedstock in the presence of steam, syngas and an oxygen-rich gas stream.
摘要翻译: 本发明涉及通过在蒸汽,合成气和富氧气流的存在下通过碳质原料的催化氢化而制备气态产物,特别是甲烷的方法。
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公开(公告)号:US08202913B2
公开(公告)日:2012-06-19
申请号:US12604695
申请日:2009-10-23
CPC分类号: C10J3/00 , C01B3/12 , C01B3/52 , C01B3/586 , C01B2203/0415 , C01B2203/0445 , C01B2203/047 , C01B2203/0475 , C01B2203/0485 , C10J3/721 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1807 , C10J2300/1884 , C10J2300/1892 , C10K3/04 , C10L3/08 , C10L3/102
摘要: The present invention relates to processes and continuous processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam. In one aspect of the invention, the processes comprise at least partially combusting a first carbonaceous feedstock with an oxygen-rich gas stream, a recycle steam stream, and an aqueous make-up stream in an oxygen-blown gasifier, under suitable temperature and pressure, to generate a first gas stream comprising hydrogen, carbon monoxide and superheated steam; and reacting a second carbonaceous feedstock and the first gas stream in a catalytic gasifier in the presence of a gasification catalyst under suitable temperature and pressure to form a second gas stream comprising a plurality of gaseous products comprising methane, carbon dioxide, hydrogen, carbon monoxide and hydrogen sulfide. The processes can comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and in certain embodiments do not recycle carbon monoxide or hydrogen to the gasifier. Heat energy recovered from the catalytic gasification can be used to generate the recycle steam stream.
摘要翻译: 本发明涉及用于在蒸汽存在下通过碳质原料的催化气化来制备气态产物,特别是甲烷的方法和连续方法。 在本发明的一个方面,该方法包括在合适的温度和压力下,在吹氧气化器中至少部分地燃烧第一含碳原料与富氧气流,再循环蒸汽流和含水补充料流 以产生包含氢气,一氧化碳和过热蒸汽的第一气流; 以及在气化催化剂存在下,在合适的温度和压力下使催化气化器中的第二碳质原料与第一气流反应,形成第二气流,其包含多个包含甲烷,二氧化碳,氢气,一氧化碳和 硫化氢。 该方法可以包括使用至少一种催化甲烷化器将气态产物中的一氧化碳和氢气转化成甲烷,并且在某些实施方案中不将一氧化碳或氢气循环到气化器。 从催化气化回收的热能可用于产生再循环蒸汽流。
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公开(公告)号:US20100121125A1
公开(公告)日:2010-05-13
申请号:US12562919
申请日:2009-09-18
申请人: Edwin J. Hippo , Vincent G. Reiling , Earl T. Robinson , Pattabhi K. Raman , Jeffery Smith , Charles Mims , Nicholas Charles Nahas
发明人: Edwin J. Hippo , Vincent G. Reiling , Earl T. Robinson , Pattabhi K. Raman , Jeffery Smith , Charles Mims , Nicholas Charles Nahas
IPC分类号: C07C1/04
CPC分类号: C10J3/00 , B01J21/18 , B01J21/20 , B01J23/04 , B01J23/92 , B01J35/0026 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J37/009 , B01J37/0201 , B01J38/72 , C10J3/482 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0973 , C10J2300/0986 , C10J2300/1662 , C10J2300/1671 , C10J2300/1675 , C10J2300/1687 , C10J2300/1807 , C10J2300/1884 , C10L3/08 , Y02P20/52 , Y02P20/584
摘要: The invention provides processes for generating a methane-enriched gas from a gas mixture comprising carbon monoxide and hydrogen such as gas streams generated by gasification of an alkali metal catalyst-loaded carbonaceous feedstock, and a char methanation catalyst useful in such processes.
摘要翻译: 本发明提供从包含一氧化碳和氢气的气体混合物产生富甲烷气体的方法,例如通过加载载有碱金属催化剂的碳质原料气化产生的气流,以及可用于这些方法的焦炭甲烷化催化剂。
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9.
公开(公告)号:US08192716B2
公开(公告)日:2012-06-05
申请号:US12415050
申请日:2009-03-31
CPC分类号: C10J3/82 , C01B3/12 , C01B3/34 , C01B3/50 , C01B3/52 , C01B2203/0205 , C01B2203/0283 , C01B2203/04 , C01B2203/0405 , C01B2203/0415 , C01B2203/0435 , C01B2203/0445 , C01B2203/046 , C01B2203/0465 , C01B2203/0475 , C01B2203/048 , C01B2203/0485 , C01B2203/1241 , C01B2203/147 , C10J3/00 , C10J3/482 , C10J3/72 , C10J3/721 , C10J2300/0903 , C10J2300/094 , C10J2300/0959 , C10J2300/0966 , C10J2300/0973 , C10J2300/1662 , C10J2300/1687 , C10J2300/1807 , C10J2300/1823 , C10J2300/1846 , C10J2300/1853 , C10K3/04 , C10L3/10
摘要: Processes for the catalytic conversion of a carbonaceous composition into a gas stream comprising methane are provided, where a sour shift reaction is used to remove carbon monoxide gas stream produced by the gasification process. The incorporation of the sour shift reaction provides an efficient and cost-effective means of eliminating carbon monoxide from the gas stream. In addition, the sour shift reaction also generates additional hydrogen, thus increasing the amount of hydrogen produced from the gasification process.
摘要翻译: 提供了将碳质组合物催化转化成包含甲烷的气流的方法,其中使用酸转移反应来除去由气化过程产生的一氧化碳气流。 引入酸转移反应提供了从气流中除去一氧化碳的有效且成本有效的手段。 此外,酸转化反应还产生额外的氢,从而增加从气化过程产生的氢气的量。
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公开(公告)号:US20120102836A1
公开(公告)日:2012-05-03
申请号:US13284139
申请日:2011-10-28
IPC分类号: C10L3/08
CPC分类号: C10J3/463 , C01B3/586 , C01B32/40 , C01B32/50 , C01B2203/0283 , C01B2203/0405 , C01B2203/0415 , C01B2203/042 , C01B2203/043 , C01B2203/0445 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/0485 , C01B2203/0495 , C01B2203/147 , C10J2300/093 , C10J2300/0973 , C10J2300/0986 , C10J2300/1807 , C10J2300/1838 , C10L3/08
摘要: The present invention relates to processes for hydromethanating a carbonaceous feedstock to a methane-enriched synthesis gas, where an oxygen-rich gas stream and the carbonaceous feedstock are fed into a fluidized-bed hydromethanation reactor at a specified zone in order to assist in heat management within the hydromethanation reactor.
摘要翻译: 本发明涉及将含碳原料氢化成富甲烷合成气的方法,其中富氧气流和含碳原料在特定区域进料到流化床水化反应器中,以帮助热管理 在水文反应堆内。
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