摘要:
Reinforced poly(ethylene terephthalate) sheets are thermoformed to articles having one or more surfaces in contact with the mold of such a degree of smoothness that they virtually completely replicate the mold face. When the mold face is completely smooth, the concave imperfections caused by air entrapment in the plastic material account for less than 6% of the surface area. Composite articles consisting of a face member and a backing member are made by thermoforming in a single mold a face member having one or more surfaces in contact with the mold face of such a degree of smoothness that it completely replicates the mold face, and its proportion of concave imperfections is less than about 6% of the surface area. The backing member is bonded in the mold with an adhesive to the face member, and the composite structure is allowed to remain in the mold for a sufficient time to permit subsequent removal without distortion. The initial polymer sheets are less than about 5% crystalline, but the thermoformed article is left in the mold until it crystallizes to the desired degree.
摘要:
Reinforced poly(ethylene terephthalate) sheets are thermoformed to articles having one or more surfaces in contact with the mold of such a degree of smoothness that they virtually completely replicate the mold face. When the mold face is completely smooth, the concave imperfections caused by air entrapment in the plastic material account for less than 6% of the surface area. Composite articles consisting of a face member and a backing member are made by thermoforming in a single mold a face member having one or more surfaces in contact with the mold face of such a degree of smoothness that it completely replicates the mold face, and its proportion of concave imperfections is less than about 6% of the surface area. The backing member is bonded in the mold with an adhesive to the face member, and the composite structure is allowed to remain in the mold for a sufficient time to permit subsequent removal without distortion. The initial polymer sheets are less than about 5% crystalline, but the thermoformed article is left in the mold until it crystallizes to the desired degree.
摘要:
Fiber-reinforced poly(ethylene terephthalate) sheet is laminated to a sheet of amorphous, adhesive copolyester at a temperature at which poly(ethylene terephthalate) is in a molten state. The resulting composite sheet is useful in making thermoformed articles in which one member is bonded to another member, for example, a face member and a backing member. The different members are arranged so that their copolyester layers face each other. Hollow thermoformed articles bonded with amorphous copolyester adhesive exhibit very good bond strength and minimum distortion.
摘要:
A process for extruding a smooth and uniform film or sheet of an ordered poly(ether ketone ketone) having a thickness of about 2.5 to 250 micrometers, wherein the molten extrudate is quenched on a drum maintained at a temperature of about 100.degree.-170.degree. C.
摘要:
(A) A continuous layer of a hydrophobic elastomer having a water vapor transmission rate of 400-2500 gm.mil/m.sup.2 /24 hrs., said hydrophobic elastomer is a copolyetherester having a multiplicity of recurring long-chain ester units and short-chain ester units, said long-chain ester units being represented by the formula ##STR1## and said short-chain ester units being represented by the formula ##STR2## where G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide)glycol having an average molecular weight of about 400-3500, the amount of ethylene oxide groups incorporated in the copolyetherester by the poly(alkylene oxide)glycol is not greater than about 20 weight percent; R is a divalent radical remaining after removal of carboxyl groups from a dicarboxylic acid having a molecular weight less than 300; D is a divalent radical remaining after removal of hydroxyl groups from a diol having a molecular weight less than about 250;(B) a continuous layer of a hydrophilic elastomer having a water vapor transmission rate of at least 3500 gm.mil/m.sup.2 /24 hrs. said hydrophilic elastomer is a copolyetherester having a multiplicity of long-chain ester units and short-chain ester units represented by formulae (I) and (II) above and having the values given above with the proviso that the amount of ethylene oxide groups incorporated in the copolyetherester by the poly(alkylene oxide)glycol is from about 25-68 weight percent andsaid bicomponent film has a separation ratio for water vapor of at least 1.2.
摘要:
A process for the preparation of a laminate, particularly a waterproof moisture vapor permeable laminate, comprising a substrate having on a surface thereof a thermoplastic polymer resin coating and further comprising a peelable release layer in contact with the surface of said thermoplastic polymer resin remote from the substrate, and optionally further comprising a tie layer between the substrate and the thermoplastic polymer resin, said process comprising the steps of forming or providing a substrate layer and providing on a surface thereof a thermoplastic polymer resin coating and a peelable release layer and optionally providing a tie layer between the substrate and the thermoplastic polymer resin coating, characterized in that the thermoplastic polymer resin has a viscosity less than about 3000 Pa.s measured according to the standard ISO11443.
摘要:
A vascular prosthesis is made by wetting a porous polyester fiber tubing with water until it gains close to maximum amount of weight, removing excess liquid from inside the tubing, repeatedly contacting the inside surface of the tubing with a solution of a biocompatible polymer in a water-immiscible solvent to adsorb some solution on the inside surface of the tubing, and removing excess solution, then removing solvent from the adsorbed solution to form a nonporous elastomer coating of the desired thickness on the inside surface of the tubing.
摘要:
A bicomponent film of a hydrophilic copolyester having a WVTR of at least 3500 gm.mil/m.sup.2 /24 hrs. of a poly(etherimide) ester elastomer containing about 25-60 weight percent ethylene oxide units, and a hydrophobic copolyester having a WVTR of 400-2500 gm.mil/m.sup.2 /24 hrs. of a poly(etherimide) ester elastomer or a segmented copolyester elastomer having no more than about 20 weight percent ethylene oxide units in the hydrophobic elastomers, the bicomponent film having a separation ratio for water vapor of at least 1.2 as determined by ASTM/E 96-66 (Procedure BW).
摘要:
Poly(ethylene terephthalate) compositions containing a small amount of a terpolymer of ethylene containing carboxyl groups, which may be partly or completely converted to a divalent metal salt form, and reinforced with a mineral material having an aspect ratio of at least 10 can be formed into sheets which are readily thermoformable at moderate pressures and have very good thermoforming radius ratios.
摘要:
Endovascular stents capable of being cut from a flat piece of material are described. The endovascular stents may be bioabsorbable, multilayered and may have structural configurations allowing them to maintain low profiles in vivo. Methods of manufacturing endovascular stents and methods of using endovascular stents are also described.