公开(公告)号：US08105656B2

公开(公告)日：2012-01-31

申请号：US12092086

申请日：2006-10-05

申请人： Edwin Nun ,  Heike Bergandt ,  Hannelore Armoneit ,  Marie-Theres Wilkes ,  Sigrid Banken ,  Thomas Schrief

发明人： Edwin Nun ,  Heike Bergandt ,  Hannelore Armoneit ,  Marie-Theres Wilkes ,  Sigrid Banken ,  Thomas Schrief

IPC分类号： B05D3/02

CPC分类号： D06M11/77 ,  B05D7/546 ,  C09D183/04 ,  C09D183/06 ,  D06M11/45 ,  D06M11/46 ,  D06M11/49 ,  D06M11/71 ,  D06M11/78 ,  D06M11/79 ,  D06M11/81 ,  D06M11/83 ,  D06M13/507 ,  D06M13/513 ,  Y10T428/31663

摘要： The present invention relates to a method of coating a substrate, comprising the steps of a) providing a substrate, b) applying a composition to at least one side of the substrate, the composition containing an inorganic compound and the inorganic compound containing at least one metal and/or semimetal selected from the group Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, Tl, Si, Ge, Sn, Zn, Pb, Sb, Bi or a mixture thereof and at least one element selected from the group Te, Se, S, O, Sb, As, P, N, C, Ga or a mixture thereof, c) drying the composition applied in step b), d) applying at least one coating to the at least one side of the substrate to which the composition was applied in step b), the coating containing a silane of the general formula (Z1)Si(OR)3, Z1 being R, OR or Gly (Gly is 3-glycidyloxypropyl) and R being an alkyl radical having from 1 to 18 carbon atoms, it being possible for all radicals R to be identical or different, oxide particles selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or a mixture thereof, a polymer, and an initiator, and e) drying the coating applied in step d), and also to a coated substrate obtainable by the above method.

摘要翻译： 本发明涉及一种涂覆基材的方法，包括以下步骤：a）提供基材，b）将组合物施用至基材的至少一侧，所述组合物含有无机化合物和含有至少一种 金属和/或半金属选自Sc，Y，Ti，Zr，Nb，V，Cr，Mo，W，Mn，Fe，Co，B，Al，In，Tl，Si，Ge，Sn，Zn，Pb ，Sb，Bi或其混合物和选自Te，Se，S，O，Sb，As，P，N，C，Ga或其混合物中的至少一种元素，c）干燥步骤b ），d）在步骤b）中将至少一个涂层施加到其上施加组合物的基材的至少一侧，所述涂层含有通式（Z1）Si（OR）3的硅烷，Z1为R ，OR或Gly（Gly是3-缩水甘油氧基丙基），R是具有1至18个碳原子的烷基，所有基团R可以相同或不同，选自氧化物的氧化物颗粒 的Ti，Si，Zr，Al，Y，Sn，Zn，Ce或其混合物，聚合物和引发剂，以及e）干燥步骤d）中施加的涂层，以及可以由上述 方法。

公开(公告)号：US20080280148A1

公开(公告)日：2008-11-13

申请号：US12092086

申请日：2006-10-05

申请人： Edwin Nun ,  Heike Bergandt ,  Hannelore Armoneit ,  Marie-Theres Wilkes ,  Sigrid Banken ,  Thomas Schrief

发明人： Edwin Nun ,  Heike Bergandt ,  Hannelore Armoneit ,  Marie-Theres Wilkes ,  Sigrid Banken ,  Thomas Schrief

IPC分类号： B05D7/00 ,  B32B27/14

CPC分类号： D06M11/77 ,  B05D7/546 ,  C09D183/04 ,  C09D183/06 ,  D06M11/45 ,  D06M11/46 ,  D06M11/49 ,  D06M11/71 ,  D06M11/78 ,  D06M11/79 ,  D06M11/81 ,  D06M11/83 ,  D06M13/507 ,  D06M13/513 ,  Y10T428/31663

摘要： The present invention relates to a method of coating a substrate, comprising the steps of a) providing a substrate, b) applying a composition to at least one side of the substrate, the composition containing an inorganic compound and the inorganic compound containing at least one metal and/or semimetal selected from the group Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, TI, Si, Ge, Sn, Zn, Pb, Sb, Bi or a mixture thereof and at least one element selected from the group Te, Se, S, O, Sb, As, P, N, C, Ga or a mixture thereof, c) drying the composition applied in step b), d) applying at least one coating to the at least one side of the substrate to which the composition was applied in step b), the coating containing a silane of the general formula (Z1)Si(OR)3, Z1 being R, OR or Gly (Gly is 3-glycidyloxypropyl) and R being an alkyl radical having from 1 to 18 carbon atoms, it being possible for all radicals R to be identical or different, oxide particles selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or a mixture thereof, a polymer, and an initiator, and e) drying the coating applied in step d), and also to a coated substrate obtainable by the above method.

摘要翻译： 本发明涉及一种涂覆基材的方法，包括以下步骤：a）提供基材，b）将组合物施用至基材的至少一侧，所述组合物含有无机化合物和含有至少一种 金属和/或半金属选自Sc，Y，Ti，Zr，Nb，V，Cr，Mo，W，Mn，Fe，Co，B，Al，In，TI，Si，Ge，Sn，Zn，Pb ，Sb，Bi或其混合物和选自Te，Se，S，O，Sb，As，P，N，C，Ga或其混合物中的至少一种元素，c）干燥步骤b ），d）在步骤b）中向组合物施加至少一个涂层至所述基材的至少一侧，所述涂层含有通式（Z 1）Si的硅烷 （OR）3，Z 1是R，OR或Gly（Gly是3-缩水甘油氧基丙基），R是具有1至18个碳原子的烷基，它是 所有基团R可能相同或不同，氧化物p 选自Ti，Si，Zr，Al，Y，Sn，Zn，Ce或其混合物的氧化物的物质，聚合物和引发剂，以及e）干燥步骤d）中施加的涂层，以及涂覆 底物可通过上述方法获得。

公开(公告)号：US07993707B2

公开(公告)日：2011-08-09

申请号：US12092084

申请日：2006-08-10

申请人： Edwin Nun ,  Heike Bergandt ,  Hannelore Armoneit ,  Marie-Theres Wilkes ,  Thomas Schrief

发明人： Edwin Nun ,  Heike Bergandt ,  Hannelore Armoneit ,  Marie-Theres Wilkes ,  Thomas Schrief

IPC分类号： B05D3/02

CPC分类号： C09D183/06 ,  C09D183/04 ,  C09D183/08 ,  C08L2666/72 ,  C08L2666/36 ,  C08L2666/34

摘要： The present invention relates to a process for coating substrates, which comprises the steps: a) provision of a substrate, b) application of a composition to at least one surface of the substrate, the composition comprising a silane of the general formula (Z1)Si(OR3), where Z1 is OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 6 carbon atoms and all radicals R can be identical or different, an inert solvent and an initiator and the inert solvent having a boiling point under the drying conditions of step c) which is in a range from 50° C. above to 50° C. below the drying temperature of step c) and the boiling point of the inert solvent under the drying conditions of step c) being at least 80° C., and c) drying of the composition applied in step b) at a drying temperature of from 100° C. to 250° C., and also to a coated substrate obtainable by means of the abovementioned process.

摘要翻译： 本发明涉及一种用于涂覆基材的方法，其包括以下步骤：a）提供基材，b）将组合物施用于基材的至少一个表面，所述组合物包含通式（Z1）的硅烷， Si（OR 3），其中Z 1为OR或Gly（Gly = 3-缩水甘油氧基丙基），R为具有1至6个碳原子的烷基，所有基团R可以相同或不同，惰性溶剂和引发剂和惰性 在步骤c）的干燥条件下具有沸点的溶剂在低于步骤c）的干燥温度的50℃以上至50℃的范围内，并且在干燥条件下的惰性溶剂的沸点 步骤c）为至少80℃，和c）在100℃至250℃的干燥温度下干燥步骤b）中所用的组合物，并且还可以通过使用 上述过程。

公开(公告)号：US20080292799A1

公开(公告)日：2008-11-27

申请号：US12092084

申请日：2006-08-10

申请人： Edwin Nun ,  Heike Bergandt ,  Hannelore Armoneit ,  Marie-Theres Wilkes ,  Thomas Schrief

发明人： Edwin Nun ,  Heike Bergandt ,  Hannelore Armoneit ,  Marie-Theres Wilkes ,  Thomas Schrief

IPC分类号： B05D3/02

CPC分类号： C09D183/06 ,  C09D183/04 ,  C09D183/08 ,  C08L2666/72 ,  C08L2666/36 ,  C08L2666/34

摘要： The present invention relates to a process for coating substrates, which comprises the steps: a) provision of a substrate, b) application of a composition to at least one surface of the substrate, the composition comprising a silane of the general formula (Z1)Si(OR3), where Z1 is OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 6 carbon atoms and all radicals R can be identical or different, an inert solvent and an initiator and the inert solvent having a boiling point under the drying conditions of step c) which is in a range from 50° C. above to 50° C. below the drying temperature of step c) and the boiling point of the inert solvent under the drying conditions of step c) being at least 80° C., and c) drying of the composition applied in step b) at a drying temperature of from 100° C. to 250° C., and also to a coated substrate obtainable by means of the abovementioned process.

摘要翻译： 本发明涉及一种用于涂覆基材的方法，其包括以下步骤：a）提供基材，b）将组合物施用于基材的至少一个表面，所述组合物包含通式（Z1）的硅烷， Si（OR 3），其中Z 1为OR或Gly（Gly = 3-缩水甘油氧基丙基），R为具有1至6个碳原子的烷基，所有基团R可以相同或不同，惰性溶剂和引发剂和惰性 在步骤c）的干燥条件下具有沸点的溶剂在低于步骤c）的干燥温度的50℃以上至50℃的范围内，并且在干燥条件下的惰性溶剂的沸点 步骤c）为至少80℃，和c）在100℃至250℃的干燥温度下干燥步骤b）中所用的组合物，并且还可以通过使用 上述过程。

公开(公告)号：US08940389B2

公开(公告)日：2015-01-27

申请号：US12300054

申请日：2007-05-09

申请人： Heike Bergandt ,  Liv Randewig ,  Marie-Theres Wilkes

发明人： Heike Bergandt ,  Liv Randewig ,  Marie-Theres Wilkes

IPC分类号： B32B27/08 ,  B05D3/02 ,  B05D3/06 ,  C09D183/08 ,  C09D4/00

CPC分类号： C09D183/08 ,  C09D4/00 ,  Y10T428/31507 ,  Y10T428/31663 ,  C08G77/26

摘要： The present invention relates to a composition which contains a) at least one reaction product of a1) a silane of the general formula in which Y(1)=3-glycidyloxypropyl-, and R1, R2, R3=like or unlike alkyl groups having 1 to 6 carbon atoms, and a2) a silane of the general formula in which Y(2)=N-2-aminoethyl-3-aminopropyl- or NH2(CH2)2NH(CH2)2NH(CH)3, and R′1, R′2, R′3=like or unlike alkyl groups having 1 to 6 carbon atoms, and b) at least one inorganic filler, and c) a solvent having a boiling point at a temperature ≦85° C., and d) water, and e) a catalyst selected from organic and inorganic acids, to a method of producing a surface coating on a polymeric surface by applying the composition of the invention, and to articles having at least one polymeric surface which have the surface coating of the invention, and to their use.

摘要翻译： 本发明涉及一种组合物，其含有a）至少一种下列通式的硅烷的反应产物：其中Y（1）= 3-缩水甘油氧基丙基，R1，R2，R3 =相同或不同于具有 1至6个碳原子，和a2）其中Y（2）= N-2-氨基乙基-3-氨基丙基或NH 2（CH 2）2 NH（CH 2）2 NH（CH 3）3和通式 1，R'2，R'3 =类似或不同于具有1至6个碳原子的烷基，以及b）至少一种无机填料，和c）沸点为＆lt; nEE; 85℃的溶剂， 和d）水，以及e）选自有机和无机酸的催化剂，通过应用本发明的组合物在聚合物表面上生产表面涂层的方法，以及具有至少一个具有表面的聚合物表面的制品 本发明的涂层及其用途。

公开(公告)号：US20090162631A1

公开(公告)日：2009-06-25

申请号：US12300054

申请日：2007-05-09

申请人： Heike Bergandt ,  Liv Randewig ,  Marie-Theres Wilkes

发明人： Heike Bergandt ,  Liv Randewig ,  Marie-Theres Wilkes

IPC分类号： B32B27/08 ,  B05D3/02 ,  B05D3/06

CPC分类号： C09D183/08 ,  C09D4/00 ,  Y10T428/31507 ,  Y10T428/31663 ,  C08G77/26

摘要： The present invention relates to a composition which contains a) at least one reaction product of a1) a silane of the general formula in which Y(1)=3-glycidyloxypropyl-, and R1, R2, R3=like or unlike alkyl groups having 1 to 6 carbon atoms, and a2) a silane of the general formula in which Y(2)=N-2-aminoethyl-3-aminopropyl- or NH2 (CH2)2NH(CH2)2NH(CH)3, and R′1, R′2, R′3=like or unlike alkyl groups having 1 to 6 carbon atoms, and b) at least one inorganic filler, and c) a solvent having a boiling point at a temperature ≦85° C., and d) water, and e) a catalyst selected from organic and inorganic acids, to a method of producing a surface coating on a polymeric surface by applying the composition of the invention, and to articles having at least one polymeric surface which have the surface coating of the invention, and to their use.

摘要翻译： 本发明涉及一种组合物，其含有a）至少一种下列通式的硅烷的反应产物：其中Y（1）= 3-缩水甘油氧基丙基，R1，R2，R3 =相同或不同于具有 1至6个碳原子，和a2）其中Y（2）= N-2-氨基乙基-3-氨基丙基或NH 2（CH 2）2 NH（CH 2）2 NH（CH 3）3和通式 1，R'2，R'3 =与具有1至6个碳原子的烷基相似或不同，b）至少一种无机填料，和c）沸点在85℃以下的溶剂， 和d）水，以及e）选自有机和无机酸的催化剂，通过应用本发明的组合物在聚合物表面上生产表面涂层的方法，以及具有至少一个具有表面的聚合物表面的制品 本发明的涂层及其用途。

公开(公告)号：US20080280050A1

公开(公告)日：2008-11-13

申请号：US12093025

申请日：2006-12-07

申请人： Edwin Nun ,  Heike Bergandt ,  Andreas Gutsch ,  Gerhard Geipel

发明人： Edwin Nun ,  Heike Bergandt ,  Andreas Gutsch ,  Gerhard Geipel

IPC分类号： B05D3/02 ,  B32B5/16 ,  D21H19/72 ,  E04F13/12

CPC分类号： H01Q17/00 ,  H05K9/0083 ,  Y10T156/1153 ,  Y10T428/24926 ,  Y10T428/256

摘要： The present invention relates to a method for coating substrates, comprising the steps of: a) preparing a substrate, b) applying a composition onto at least one side of the substrate, the composition containing an inorganic compound, the inorganic compound containing at least one metal and/or semimetal selected from the group Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, Tl, Si, Ge, Sn, Zn, Pb, Sb, Bi or mixtures thereof and at least one element selected from the group Te, Se, S, O, Sb, As, P, N, C, Ga or mixtures thereof, and an electrically conductive substance selected from metals, particulate metals, metal alloys, particulate metal alloys, conductive compounds containing carbon or mixtures thereof, c) drying the composition applied in step b), d) applying at least one coating onto the at least one side of the substrate onto which the composition was applied in step b), the coating containing a silane of the general formula (Z1)Si(OR)3, where Z1 is R, OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 18 carbon atoms and all R may be identical or different, oxide particles selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or mixtures thereof, and an initiator, the coating preferably containing 3-aminopropyltrimethoxysilane and/or 3-aminopropyltriethoxysilane and/or N-2-aminoethyl-3-aminopropyltrimethoxysilane, and e) drying the coating applied in step d), as well as to the coated substrate.

摘要翻译： 本发明涉及一种涂布基材的方法，包括以下步骤：a）制备基材，b）将组合物施加到基材的至少一侧上，所述组合物含有无机化合物，所述无机化合物含有至少一种 金属和/或半金属选自Sc，Y，Ti，Zr，Nb，V，Cr，Mo，W，Mn，Fe，Co，B，Al，In，Tl，Si，Ge，Sn，Zn，Pb ，Sb，Bi或其混合物和选自Te，Se，S，O，Sb，As，P，N，C，Ga或其混合物中的至少一种元素，以及选自金属，颗粒金属 ，金属合金，颗粒状金属合金，含有碳或其混合物的导电化合物，c）干燥步骤b）中施加的组合物，d）将至少一层涂料施加到其上施用组合物的基材的至少一侧上 步骤b），所述涂层含有通式（Z 1）Si（OR 3）3的硅烷，其中Z 1 R，OR或Gly（Gly = 3-缩水甘油氧丙基），R为具有1至18个碳原子的烷基，全部R可相同或不同，选自Ti，Si， Zr，Al，Y，Sn，Zn，Ce或其混合物和引发剂，该涂层优选含有3-氨基丙基三甲氧基硅烷和/或3-氨基丙基三乙氧基硅烷和/或N-2-氨基乙基-3-氨基丙基三甲氧基硅烷，以及e） 在步骤d）中涂覆的涂层以及涂覆的基材。

公开(公告)号：US08163351B2

公开(公告)日：2012-04-24

申请号：US12067855

申请日：2006-10-05

申请人： Edwin Nun ,  Heike Bergandt

发明人： Edwin Nun ,  Heike Bergandt

IPC分类号： B05D3/02

CPC分类号： C09D4/00 ,  Y10T428/265 ,  C08G77/24 ,  C08G77/04 ,  C08G77/26

摘要： The present invention relates to a process for coating substrates, which comprises the steps: a) provision of a substrate which is not natural stone and/or natural ashlar, b) application of a composition comprising a silane of the general formula (Z1)Si(OR)3, where Z1 is R, OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 18 carbon atoms and all radicals R can be identical or different, oxide particles selected from among the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce and mixtures thereof, with bound organic radicals SiR′3 being present on the surface of the oxide particles, where R′ has the general formula CnX1+2n where n=1 to 20, X=hydrogen and/or fluorine, all radicals R′ can be identical or different and the organic radicals SiR′3 being able to be split off, and an initiator to at least one surface of the substrate and c) drying of the composition applied in step b), and a coated substrate which can be obtained by the abovementioned process.

摘要翻译： 本发明涉及一种涂覆基材的方法，其包括以下步骤：a）提供不是天然石材和/或天然石灰石的基材，b）将包含通式（Z1）Si的硅烷的组合物 （OR）3，其中Z1是R，OR或Gly（Gly = 3-缩水甘油氧基丙基），R是具有1至18个碳原子的烷基，所有基团R可以相同或不同，选自氧化物 的Ti，Si，Zr，Al，Y，Sn，Zn，Ce及其混合物，结合的有机基团SiR'3存在于氧化物颗粒的表面上，其中R'具有通式CnX1 + 2n，其中n = 1至20，X =氢和/或氟，所有基团R'可以相同或不同，并且有机基团SiR'3能够被分离，并且引发剂至基底的至少一个表面，c）干燥 的步骤b）中应用的组合物，以及可以通过上述方法获得的涂布基材。

公开(公告)号：US20080261032A1

公开(公告)日：2008-10-23

申请号：US12067855

申请日：2006-10-05

申请人： Edwin Nun ,  Heike Bergandt

发明人： Edwin Nun ,  Heike Bergandt

IPC分类号： B32B9/00 ,  B05D3/02

CPC分类号： C09D4/00 ,  Y10T428/265 ,  C08G77/24 ,  C08G77/04 ,  C08G77/26

摘要： The present invention relates to a process for coating substrates, which comprises the steps: a) provision of a substrate which is not natural stone and/or natural ashlar, b) application of a composition comprising a silane of the general formula (Z1)Si(OR)3, where Z1 is R, OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 18 carbon atoms and all radicals R can be identical or different, oxide particles selected from among the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce and mixtures thereof, with bound organic radicals SiR′3 being present on the surface of the oxide particles, where R′ has the general formula CnX1+2n where n=1 to 20, X=hydrogen and/or fluorine, all radicals R′ can be identical or different and the organic radicals SiR′3 being able to be split off, and an initiator to at least one surface of the substrate and c) drying of the composition applied in step b), and a coated substrate which can be obtained by the abovementioned process.

摘要翻译： 本发明涉及一种用于涂覆基材的方法，其包括以下步骤：a）提供不是天然石材和/或天然石灰石的基材，b）施加包含通式（Z ^{3 存在于氧化物颗粒的表面上，其中R'具有通式C N n X 1 + 2n N其中n = 1至20 ，X =氢和/或氟，所有基团R'可以相同或不同，并且有机基团SiR'3 N能够被分离，引发剂可以与基材的至少一个表面 和c）在步骤b）中施用的组合物的干燥和涂覆的 可以通过上述方法获得的底物。}

公开(公告)号：US20080305702A1

公开(公告)日：2008-12-11

申请号：US12159103

申请日：2006-11-24

申请人： Edwin Nun ,  Heike Bergandt ,  Andreas Gutsch

发明人： Edwin Nun ,  Heike Bergandt ,  Andreas Gutsch

IPC分类号： B32B7/10 ,  B05D3/02

CPC分类号： D06M11/83 ,  A01N59/16 ,  B05D5/00 ,  B05D7/52 ,  D06M11/45 ,  D06M11/46 ,  D06M11/49 ,  D06M11/71 ,  D06M11/77 ,  D06M11/79 ,  D06M11/81 ,  D06M13/507 ,  D06M13/513 ,  D06M16/00 ,  D21H17/59 ,  D21H19/24 ,  D21H19/32 ,  D21H21/36 ,  D21H23/22 ,  Y10T442/2098 ,  A01N25/10 ,  A01N55/00 ,  A01N2300/00

摘要： The present invention relates to a method for coating substrates, comprising the steps: a) provision of a substrate, b) application of a composition to at least one side of the substrate, the composition containing an inorganic compound and the inorganic compound containing at least one metal and/or semi-metal selected from the group consisting of Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, Tl, Si, Ge, Sn, Zn, Pb, Sb, Bi or mixtures thereof and at least one element selected from the group consisting of Te, Se, S, O, Sb, As, P, N, C, Ga or mixtures thereof, c) drying of the composition applied in step b), d) application of at least one coating to the at least one side of the substrate on which the composition was applied in step b), the coating containing a silane of the general formula (Z1)Si(OR)3, where Z1 is R, OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having 1 to 18 carbon atoms and all R may be identical or different, oxide particles which are selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or mixtures thereof, an initiator and optionally zinc, zinc salts, zinc complexes, silver, silver salts and/or complexed silver, and e) drying of the coating applied in step d), f) application of at least one further coating to the at least one side of the substrate on which the coating was applied in step d), the further coating containing a silane of the general formula (Z1)Si(OR)3, where Z1 is R, OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having 1 to 18 carbon atoms and all R may be identical or different, an antimicrobial and/or biocidal substance selected from substances containing Zn, Zn salts, Zn complexes, such as, for example, zinc acetylacetonate, Zr, Ag, Ag salts, Ag complexes, Sn, Sn compounds or mixtures thereof, and an initiator, and g) drying of the further coating applied in step f), and a substrate obtainable by the abovementioned method.