公开(公告)号：US07927714B2

公开(公告)日：2011-04-19

申请号：US12194813

申请日：2008-08-20

Applicant: Emily A. Carter ,  Ivan Milas

Inventor： Emily A. Carter ,  Ivan Milas

IPC: B32B15/04 ,  B32B18/00 ,  B05D3/02

CPC classification number: C22C30/00 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/12549 ,  Y10T428/1259 ,  Y10T428/12736 ,  Y10T428/12757 ,  Y10T428/12931 ,  Y10T428/12944 ,  Y10T428/12951

Abstract: A metallic article for high temperature applications such as a turbine engine component is protected by a thermal barrier coating system on the article's metallic substrate. The thermal barrier coating system includes a bond coat layer of aluminum containing alloy on the metal substrate, an alumina layer on the bond coat layer and a ceramic thermal barrier layer on the alumina layer. The bond coat layer is doped with elemental barium that enhances the creep resistance of the alumina layer, thus, minimizing spallation of the ceramic thermal barrier layer.

Abstract translation: 用于高温应用的金属制品，例如涡轮发动机部件，由制品金属基底上的热障涂层系统保护。 热障涂层系统包括在金属基底上的含铝合金的粘合涂层，粘合涂层上的氧化铝层和氧化铝层上的陶瓷热阻层。 键合涂层掺杂有元素钡，其增强氧化铝层的抗蠕变性，从而最小化陶瓷热障层的剥落。

公开(公告)号：US20100047615A1

公开(公告)日：2010-02-25

申请号：US12194813

申请日：2008-08-20

Applicant: Emily A. Carter ,  Ivan Milas

Inventor： Emily A. Carter ,  Ivan Milas

IPC: B32B15/04 ,  B05D3/02

CPC classification number: C22C30/00 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/12549 ,  Y10T428/1259 ,  Y10T428/12736 ,  Y10T428/12757 ,  Y10T428/12931 ,  Y10T428/12944 ,  Y10T428/12951

Abstract: A metallic article for high temperature applications such as a turbine engine component is protected by a thermal barrier coating system on the article's metallic substrate. The thermal barrier coating system includes a bond coat layer of aluminum containing alloy on the metal substrate, an alumina layer on the bond coat layer and a ceramic thermal barrier layer on the alumina layer. The bond coat layer is doped with elemental barium that enhances the creep resistance of the alumina layer, thus, minimizing spallation of the ceramic thermal barrier layer.

Abstract translation: 用于高温应用的金属制品，例如涡轮发动机部件，由制品金属基底上的热障涂层系统保护。 热障涂层系统包括在金属基底上的含铝合金的粘合涂层，粘合涂层上的氧化铝层和氧化铝层上的陶瓷热阻层。 键合涂层掺杂有元素钡，其增强氧化铝层的抗蠕变性，从而最小化陶瓷热障层的剥落。

公开(公告)号：US20230357046A1

公开(公告)日：2023-11-09

申请号：US18143556

申请日：2023-05-04

Applicant: Ellen B. Stechel ,  Emily A. Carter ,  Sai Gautam Gautam Gopalakrishnan ,  Robert B. Wexler

Inventor： Ellen B. Stechel ,  Emily A. Carter ,  Sai Gautam Gautam Gopalakrishnan ,  Robert B. Wexler

IPC: C01G45/12 ,  C01B3/06 ,  C01B32/40

CPC classification number: C01G45/1264 ,  C01B3/063 ,  C01B32/40 ,  C01P2002/50 ,  C01P2002/34

Abstract: A metal-oxide perovskite material having a general formula Ca1-xCexTiyMn1-yO3, where x is in a range of about 0.3 to about 0.35 and y is in a range of about 0.25 to about 0.35. Producing hydrogen and oxygen includes heating the metal-oxide perovskite material; reducing the metal-oxide perovskite material to yield a reduced metal-oxide perovskite material; cooling the reduced metal-oxide perovskite material; and contacting the reduced metal-oxide perovskite material with a re-oxidizing fluid including steam to yield hydrogen and a re-oxidized metal-oxide perovskite material. Producing carbon monoxide and oxygen includes heating the metal-oxide perovskite material; reducing the metal-oxide perovskite material to yield a reduced metal-oxide perovskite material; cooling the reduced metal-oxide perovskite material, and contacting the reduced metal-oxide perovskite material with a re-oxidizing fluid including carbon dioxide to yield carbon monoxide and a re-oxidized metal-oxide perovskite material.

公开(公告)号：US07504355B2

公开(公告)日：2009-03-17

申请号：US10518129

申请日：2003-06-12

Applicant: Emily A. Carter ,  Emily A. Jarvis

Inventor： Emily A. Carter ,  Emily A. Jarvis

IPC: B01J23/00 ,  B01J23/56 ,  B01J23/44 ,  B01J23/42 ,  B01J21/04 ,  B01J32/00

CPC classification number: B01J23/40 ,  B01J21/06 ,  B01J21/063 ,  B01J21/066 ,  B01J23/42 ,  B01J23/44 ,  B01J23/63 ,  B01J23/755 ,  B01J23/83 ,  B01J35/04 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0221 ,  B01J37/0225 ,  B01J37/0238 ,  B01J37/0242 ,  B01J37/0248

Abstract: Catalytic systems are provided that include a metallic catalyst attached to a ceramic support that has alumina as a principal ingredient. The ceramic support is doped with an adhesive agent so that the surface of the support includes the adhesive agent. The adhesive agent is designed to form an open-shell electronic structure at the interface between the metallic catalyst and the support. The open-shell structure promotes extended useful catalyst lifetimes. The adhesive agents are early transition metals that include titanium, zirconium, scandium, hafnium, lanthanum and yttrium. Doping of the ceramic support surface with the adhesive agent also increases the adhesion between the ceramic support and metallic monoliths to which the ceramic support may be attached.

Abstract translation: 提供催化体系，其包括附着在具有氧化铝作为主要成分的陶瓷载体上的金属催化剂。 陶瓷载体掺有粘合剂，使得载体的表面包括粘合剂。 粘合剂被设计成在金属催化剂和载体之间的界面处形成开壳电子结构。 开壳结构促进延长的有用的催化剂寿命。 粘合剂是包括钛，锆，钪，铪，镧和钇的早期过渡金属。 用粘合剂掺杂陶瓷载体表面也增加了陶瓷载体和陶瓷载体可附着的金属整料之间的粘合性。