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公开(公告)号：US06436278B1
公开(公告)日：2002-08-20
申请号：US09676992
申请日：2000-10-02
IPC分类号： C10G3504
CPC分类号： C10G67/02 , C10G65/043 , C10G65/12 , C10G67/06
摘要： The invention concerns a process for producing gasoline with an improved octane number, optionally accompanied by oil and/or middle distillate production, by conversion-hydroisomerization of the paraffins in the feed using a catalyst containing at least one noble metal deposited on an amorphous acidic support. Isoparaffins are separated from the gasoline cut obtained, and normal paraffins and possibly monobranched paraffins contained in the resulting effluent are isomerized using a catalyst containing at least one hydrodehydrogenating metal and at least one acidic solid. The ensemble of the streams charged with isoparaffins with an improved octane number is sent to the gasoline pool. The residue undergoes catalytic dewaxing.
摘要翻译： 本发明涉及通过使用含有至少一种沉积在无定形酸性载体上的贵金属的催化剂通过进料中的链烷烃的转化 - 加氢异构化来生产具有改进的辛烷值的汽油的方法，任选地伴随着油和/或中间馏分的生产 。 从获得的汽油馏分中分离异链烷烃，并且使用含有至少一种氢化氢化金属和至少一种酸性固体的催化剂将所得流出物中所含的正链烷烃和可能的单链烷烃异构化。 装载有改善的辛烷值的异链烷烃的物流集合被发送到汽油池。 残留物进行催化脱蜡。
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2.发明授权Flexible method for producing oil bases and middle distillates with hydroisomerization-conversion followed by catalytic dewaxing 有权生产油基和中间馏分的加氢异构化转化随后催化脱蜡的灵活方法公开(公告)号：US07267758B2
公开(公告)日：2007-09-11
申请号：US10450397
申请日：2001-12-13
CPC分类号： B01J29/80 , B01J29/064 , B01J29/70 , B01J29/72 , C10G65/043 , C10G65/12
摘要： For producing very high quality base stock and for simultaneously producing high quality middle distillates, successive hydroisomerisation and catalytic dewaxmg steps are employed wherein the hydroisomerisation is carried out in the presence of a catalyst containing at least one noble metal deposited on an amorphous acidic support, the dispersion of the metal being 20%-100%. The support is preferably an amorphous silica-alumina. Catalytic dewaxing is carried out in the presence of a catalyst containing at least one hydrodehydrogenating element (group VIII) and at least one molecular sieve selected from ZBM-30, EU-2 and EU-11.
摘要翻译： 为了生产非常高质量的基础油料并且同时生产高品质的中间馏分物，使用连续加氢异构化和催化脱蜡步骤，其中加氢异构化在含有沉积在无定形酸性载体上的至少一种贵金属的催化剂存在下进行， 金属分散体为20％-100％。 载体优选为无定形二氧化硅 - 氧化铝。 催化脱蜡在含有至少一种脱氢元素（VIII族）和至少一种选自ZBM-30，EU-2和EU-11的分子筛的催化剂存在下进行。
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3.发明授权Flexible method for producing oil bases and distillates by hydroisomerization-conversion on a weakly dispersed catalyst followed by a catalyctic dewaxing 失效通过在弱分散催化剂上进行加氢异构化转化生产油基和馏出物的灵活方法，然后进行催化脱蜡公开(公告)号：US07371315B2
公开(公告)日：2008-05-13
申请号：US10450400
申请日：2001-12-13
申请人： Eric Benazzi , Nathalie Marchal-George , Tivadar Cseri , Pierre Marion , Christophe Gueret , Slavik Kasztelan
发明人： Eric Benazzi , Nathalie Marchal-George , Tivadar Cseri , Pierre Marion , Christophe Gueret , Slavik Kasztelan
IPC分类号： C10G69/02
CPC分类号： C10G65/12 , C10G65/043
摘要： A process for production of very high-quality base oils, and simultaneous production of high-quality middle distillates, comprises the successive stages of hydroisomerization and catalytic dewaxing. The hydroisomerization takes place in the presence of a catalyst containing at least one noble metal deposited on an amorphous acid support, the metal dispersion being less than 20%. The support is preferably an amorphous silica-alumina. The catalytic dewaxing takes place in the presence of a catalyst containing at least one hydrodehydrogenating element (Group VIII) and at least one molecular sieve chosen from ZBM-30, EU-2, and EU-11.
摘要翻译： 用于生产非常优质基础油的方法，以及同时生产高品质中间馏分，包括加氢异构化和催化脱蜡的连续阶段。 加氢异构化在含有沉积在无定形酸载体上的至少一种贵金属的催化剂存在下进行，金属分散体小于20％。 载体优选为无定形二氧化硅 - 氧化铝。 催化脱蜡在含有至少一种氢化脱氢元素（VIII族）和至少一种选自ZBM-30，EU-2和EU-11的分子筛的催化剂存在下进行。
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4.发明授权Catalyst based on a noble metal with low dispersion, and its use in converting hydrocarbon feeds 有权基于低分散度的贵金属的催化剂，以及其用于转化烃原料的用途公开(公告)号：US06660897B1
公开(公告)日：2003-12-09
申请号：US09562478
申请日：2000-05-01
IPC分类号： C07C522
CPC分类号： C10G45/62 , B01J21/12 , B01J23/40 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J37/10
摘要： A catalyst comprising at least one noble metal deposited on an acidic support, wherein the dispersion of the noble metal is less than 20%.
摘要翻译： 包含沉积在酸性载体上的至少一种贵金属的催化剂，其中贵金属的分散体小于20％。
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5.发明授权Flexible process for producing base stock and distillates by conversion-hydroisomerisation using a catalyst with low dispersion followed by catalytic dewaxing 失效通过使用低分散体催化脱蜡的催化剂通过转化 - 加氢异构化生产基础油料和馏出物的柔性方法公开(公告)号：US06602402B1
公开(公告)日：2003-08-05
申请号：US09562286
申请日：2000-05-01
申请人： Eric Benazzi , Nathalie Marchal-George , Tivadar Cseri , Pierre Marion , Christophe Gueret , Slavik Kasztelan
发明人： Eric Benazzi , Nathalie Marchal-George , Tivadar Cseri , Pierre Marion , Christophe Gueret , Slavik Kasztelan
IPC分类号： C10G6512
CPC分类号： C10G65/12 , B01J21/12 , B01J23/40 , B01J23/42 , B01J23/44 , B01J29/064 , B01J29/076 , B01J29/67 , B01J29/7446 , B01J29/7484 , B01J35/006 , B01J35/0066 , B01J35/023 , C10G45/62 , C10G65/043
摘要： An improved process for producing very high quality base stock and for simultaneous production of high quality middle distallates, comprising successive hydroisomerisation and catalystic dewaxing steps wherein hydroisomerisation is carried out in the presence of a catalyst containing at least one noble metal deposited on an amorphous acidic support, the dispersion of the metal being less than 20%. The support is preferably an amorphous silica-alumina. Catalytic dewaxing is carried out in the presence of a catalyst containing at least one hydrodehydrogenating element (group VIII) and at least one molecular sieve (preferably zeolite). The sieve is preferable selected from NU-10, EU-1, EU-13, zeolite and ferrierite.
摘要翻译： 一种用于生产非常高质量的基础油料和用于同时生产高质量中间蒸馏物的改进方法，其包括连续加氢异构化和催化脱蜡步骤，其中加氢异构化在含有至少一种沉积在无定形酸性载体上的贵金属的催化剂存在下进行 ，金属的分散度小于20％。 载体优选为无定形二氧化硅 - 氧化铝。 催化脱蜡在含有至少一种氢化脱氢元素（VIII族）和至少一种分子筛（优选沸石）的催化剂存在下进行。 筛子优选选自NU-10，EU-1，EU-13，沸石和镁碱沸石。
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6.发明授权Catalyst that comprises a partially amorphous Y zeolite and its use in hydroconversion of hydrocarbon petroleum feedstocks 有权包含部分无定形Y沸石的催化剂及其在烃类石油原料加氢转化中的用途公开(公告)号：US06387246B1
公开(公告)日：2002-05-14
申请号：US09572970
申请日：2000-05-18
申请人： Eric Benazzi , Jean-Marie Deves , Bernadette Rebours , Frédéric Chaigne , Tivadar Cseri , Slavik Kasztelan
发明人： Eric Benazzi , Jean-Marie Deves , Bernadette Rebours , Frédéric Chaigne , Tivadar Cseri , Slavik Kasztelan
IPC分类号： C01G4718
CPC分类号： B01J29/084 , B01J29/166 , B01J2229/20 , B01J2229/22 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C10G45/12 , C10G47/16
摘要： The invention relates to a catalyst that contains at least one matrix, a partially amorphous Y zeolite, optionally at least one metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table, optionally at least one element that is selected from the group that is formed by phosphorus, boron and silicon, optionally at least one element of group VIIA, and optionally at least one element of group VIIB. The partially amorphous Y zeolite has a peak rate that is less than 0.4, and a crystalline fraction that is expressed relative to a reference zeolite in sodium form and that is less than 60%. The invention also relates to the use of this catalyst in hydroconversion, in particular hydrocracking and hydrorefining of hydrocarbon feedstocks.
摘要翻译： 本发明涉及一种催化剂，其含有至少一种基质，部分无定形Y沸石，任选至少一种金属，其选自由元素周期表第ⅥB族和Ⅷ族金属形成的基团，任选至少 选自由磷，硼和硅形成的基团，任选的ⅦA族的至少一种元素和任选的至少一种ⅦB族元素的一种元素。 部分无定形的Y沸石具有小于0.4的峰值速率和相对于钠形式的参考沸石表达并且小于60％的结晶部分。 本发明还涉及该催化剂在加氢转化中的用途，特别是烃原料的加氢裂化和加氢精制。
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7.发明授权Zeolite ZSM-48 catalyst and method for improving paraffinic feedstock flow point 失效沸石ZSM-48催化剂和改进石蜡原料流动点的方法公开(公告)号：US06984309B2
公开(公告)日：2006-01-10
申请号：US10220427
申请日：2001-03-02
IPC分类号： B01J29/06
CPC分类号： C10G45/64 , B01J29/74 , B01J29/7461 , B01J2229/26 , B01J2229/42
摘要： The invention pertains to a catalyst that consists of a substrate made of at least one matrix and at least one zeolite that is selected from the group composed of the zeolites ZSM-48, EU-11, and ZBM-30, whereby, at the level of the zeolite, at least one noble metal of Group VIII is deposited on said substrate. The noble metal is preferably located on the outer surfaces of the zeolite crystals, and more preferable at the mouths of pores. The invention also pertains to a process for preparing the catalyst and utilizing the catalyst to treat hydrocarbon feedstocks, and especially for improving their pour points.
摘要翻译： 本发明涉及由至少一种基质制成的底物和至少一种选自沸石ZSM-48，EU-11和ZBM-30的沸石组成的催化剂，其中， 的沸石，至少一种VIII族贵金属沉积在所述基材上。 贵金属优选位于沸石晶体的外表面上，更优选在孔口。 本发明还涉及制备催化剂并利用催化剂处理烃原料，特别是改善其倾点的方法。
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8.发明授权公开(公告)号：US06231750B1
公开(公告)日：2001-05-15
申请号：US09344344
申请日：1999-06-25
IPC分类号： C10G4706
CPC分类号： C10G47/16 , B01J27/047 , B01J29/7815 , B01J2229/26 , B01J2229/42
摘要： The invention provides a hydrocracking catalyst comprising at least one mineral matrix, at least one beta zeolite, at least one group VB element or at least one mixed sulphide phase comprising sulphur, optionally at least one group VIB or group VIII element, optionally at least one element selected from the group formed by silicon, boron or phosphorous, and optionally at least one group VIIA element.
摘要翻译： 本发明提供一种加氢裂化催化剂，其包含至少一种矿物基质，至少一种β沸石，至少一种VB族元素或至少一种含硫混合物，任选至少一种VIB族或VIII族元素的混合硫化物，任选至少一种 元素选自由硅，硼或磷形成的基团，以及任选的至少一种VIIA族元素。
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9.发明授权Catalyst comprising a NU-88 zeolite, a group VB element and its use for hydroconverting hydrocarbon-containing petroleum feeds 失效包含NU-88沸石，VB族元素及其用于加氢转化含烃石油原料的催化剂
公开(公告)号：US6136180A
公开(公告)日：2000-10-24
申请号：US253011
申请日：1999-02-19
CPC分类号： C10G47/20 , B01J29/04 , B01J29/78 , C01B39/48 , B01J2229/26 , B01J2229/42
摘要： The invention provides a hydrocracking catalyst comprising at least one NU-88 zeolite, at least one group VB metal, preferably niobium, at least one amorphous or low crystallinity matrix, optionally at least one metal selected from the group formed by group VIB and VIII metals, optionally at least one element selected from the group formed by phosphorous, boron and silicon, and optionally at least one group VIIA element. The invention also relates to the use of the catalyst for hydrocracking hydrocarbon-containing feeds.
摘要翻译： 本发明提供一种加氢裂化催化剂，其包括至少一种NU-88沸石，至少一种VB族金属，优选铌，至少一种无定形或低结晶度基体，任选至少一种选自由VIB族和VIII族金属形成的基团的金属 ，任选的至少一种选自由磷，硼和硅形成的基团，以及任选的至少一种VIIA族元素。 本发明还涉及催化剂用于加氢裂化含烃原料的用途。
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10.发明授权Catalyst comprising a zeolite selected from the group formed by zeolites NU-85, NU-86 and NU-87, an element from group VB and its use in the hydroconversion of hydrocarbon petroleum charges 失效包含选自由沸石NU-85，NU-86和NU-87形成的沸石的沸石，来自VB组的元素及其在烃石油加氢转化中的用途
公开(公告)号：US6123831A
公开(公告)日：2000-09-26
申请号：US320269
申请日：1999-05-27
IPC分类号： B01J29/076 , B01J29/58 , B01J29/78 , C10G47/20 , C10G47/00
摘要： The invention concerns a hydrocracking catalyst comprising at least one amorphous or poorly crystallised matrix of oxide type, at least one element from group VB, preferably niobium, at least one zeolite selected from the group formed by zeolites NU-85, NU-86 and NU-87, and at least one element selected among boron and silicon, optionally P, optionally at least one element selected from the elements from group VIB and group VIII, and/or optionally at least one element from group VIIA. The invention also concerns the use of that catalyst in the hydrocracking of hydrocarbon charges.
摘要翻译： 本发明涉及一种加氢裂化催化剂，其包含至少一种氧化物类型的无定形或不完全结晶的基质，来自VB族的元素，优选铌的至少一种元素，选自由沸石NU-85，NU-86和NU形成的基团中的至少一种沸石 -87，以及选自硼和硅中的至少一种元素，任选地P，任选地至少一种选自VIB族和VIII族元素的元素和/或任选的至少一种来自VIIA族的元素。 本发明还涉及该催化剂在烃装料加氢裂化中的用途。
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