公开(公告)号：US07267758B2

公开(公告)日：2007-09-11

申请号：US10450397

申请日：2001-12-13

申请人： Eric Benazzi ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Marion ,  Christophe Gueret

发明人： Eric Benazzi ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Marion ,  Christophe Gueret

IPC分类号： C10G73/38 ,  C10G65/02

CPC分类号： B01J29/80 ,  B01J29/064 ,  B01J29/70 ,  B01J29/72 ,  C10G65/043 ,  C10G65/12

摘要： For producing very high quality base stock and for simultaneously producing high quality middle distillates, successive hydroisomerisation and catalytic dewaxmg steps are employed wherein the hydroisomerisation is carried out in the presence of a catalyst containing at least one noble metal deposited on an amorphous acidic support, the dispersion of the metal being 20%-100%. The support is preferably an amorphous silica-alumina. Catalytic dewaxing is carried out in the presence of a catalyst containing at least one hydrodehydrogenating element (group VIII) and at least one molecular sieve selected from ZBM-30, EU-2 and EU-11.

摘要翻译： 为了生产非常高质量的基础油料并且同时生产高品质的中间馏分物，使用连续加氢异构化和催化脱蜡步骤，其中加氢异构化在含有沉积在无定形酸性载体上的至少一种贵金属的催化剂存在下进行， 金属分散体为20％-100％。 载体优选为无定形二氧化硅 - 氧化铝。 催化脱蜡在含有至少一种脱氢元素（VIII族）和至少一种选自ZBM-30，EU-2和EU-11的分子筛的催化剂存在下进行。

公开(公告)号：US07371315B2

公开(公告)日：2008-05-13

申请号：US10450400

申请日：2001-12-13

申请人： Eric Benazzi ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Marion ,  Christophe Gueret ,  Slavik Kasztelan

发明人： Eric Benazzi ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Marion ,  Christophe Gueret ,  Slavik Kasztelan

IPC分类号： C10G69/02

CPC分类号： C10G65/12 ,  C10G65/043

摘要： A process for production of very high-quality base oils, and simultaneous production of high-quality middle distillates, comprises the successive stages of hydroisomerization and catalytic dewaxing. The hydroisomerization takes place in the presence of a catalyst containing at least one noble metal deposited on an amorphous acid support, the metal dispersion being less than 20%. The support is preferably an amorphous silica-alumina. The catalytic dewaxing takes place in the presence of a catalyst containing at least one hydrodehydrogenating element (Group VIII) and at least one molecular sieve chosen from ZBM-30, EU-2, and EU-11.

摘要翻译： 用于生产非常优质基础油的方法，以及同时生产高品质中间馏分，包括加氢异构化和催化脱蜡的连续阶段。 加氢异构化在含有沉积在无定形酸载体上的至少一种贵金属的催化剂存在下进行，金属分散体小于20％。 载体优选为无定形二氧化硅 - 氧化铝。 催化脱蜡在含有至少一种氢化脱氢元素（VIII族）和至少一种选自ZBM-30，EU-2和EU-11的分子筛的催化剂存在下进行。

公开(公告)号：US06602402B1

公开(公告)日：2003-08-05

申请号：US09562286

申请日：2000-05-01

申请人： Eric Benazzi ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Marion ,  Christophe Gueret ,  Slavik Kasztelan

发明人： Eric Benazzi ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Marion ,  Christophe Gueret ,  Slavik Kasztelan

IPC分类号： C10G6512

CPC分类号： C10G65/12 ,  B01J21/12 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J29/064 ,  B01J29/076 ,  B01J29/67 ,  B01J29/7446 ,  B01J29/7484 ,  B01J35/006 ,  B01J35/0066 ,  B01J35/023 ,  C10G45/62 ,  C10G65/043

摘要： An improved process for producing very high quality base stock and for simultaneous production of high quality middle distallates, comprising successive hydroisomerisation and catalystic dewaxing steps wherein hydroisomerisation is carried out in the presence of a catalyst containing at least one noble metal deposited on an amorphous acidic support, the dispersion of the metal being less than 20%. The support is preferably an amorphous silica-alumina. Catalytic dewaxing is carried out in the presence of a catalyst containing at least one hydrodehydrogenating element (group VIII) and at least one molecular sieve (preferably zeolite). The sieve is preferable selected from NU-10, EU-1, EU-13, zeolite and ferrierite.

摘要翻译： 一种用于生产非常高质量的基础油料和用于同时生产高质量中间蒸馏物的改进方法，其包括连续加氢异构化和催化脱蜡步骤，其中加氢异构化在含有至少一种沉积在无定形酸性载体上的贵金属的催化剂存在下进行 ，金属的分散度小于20％。 载体优选为无定形二氧化硅 - 氧化铝。 催化脱蜡在含有至少一种氢化脱氢元素（VIII族）和至少一种分子筛（优选沸石）的催化剂存在下进行。 筛子优选选自NU-10，EU-1，EU-13，沸石和镁碱沸石。

公开(公告)号：US06436278B1

公开(公告)日：2002-08-20

申请号：US09676992

申请日：2000-10-02

申请人： Eric Benazzi ,  Pierre-Henri Bigeard ,  Nathalie Marchal-George ,  Tivadar Cseri

发明人： Eric Benazzi ,  Pierre-Henri Bigeard ,  Nathalie Marchal-George ,  Tivadar Cseri

IPC分类号： C10G3504

CPC分类号： C10G67/02 ,  C10G65/043 ,  C10G65/12 ,  C10G67/06

摘要： The invention concerns a process for producing gasoline with an improved octane number, optionally accompanied by oil and/or middle distillate production, by conversion-hydroisomerization of the paraffins in the feed using a catalyst containing at least one noble metal deposited on an amorphous acidic support. Isoparaffins are separated from the gasoline cut obtained, and normal paraffins and possibly monobranched paraffins contained in the resulting effluent are isomerized using a catalyst containing at least one hydrodehydrogenating metal and at least one acidic solid. The ensemble of the streams charged with isoparaffins with an improved octane number is sent to the gasoline pool. The residue undergoes catalytic dewaxing.

摘要翻译： 本发明涉及通过使用含有至少一种沉积在无定形酸性载体上的贵金属的催化剂通过进料中的链烷烃的转化 - 加氢异构化来生产具有改进的辛烷值的汽油的方法，任选地伴随着油和/或中间馏分的生产 。 从获得的汽油馏分中分离异链烷烃，并且使用含有至少一种氢化氢化金属和至少一种酸性固体的催化剂将所得流出物中所含的正链烷烃和可能的单链烷烃异构化。 装载有改善的辛烷值的异链烷烃的物流集合被发送到汽油池。 残留物进行催化脱蜡。

公开(公告)号：US06660897B1

公开(公告)日：2003-12-09

申请号：US09562478

申请日：2000-05-01

申请人： Nathalie Marchal-George ,  Eric Benazzi ,  Tivadar Cseri ,  Slavik Kasztelan

发明人： Nathalie Marchal-George ,  Eric Benazzi ,  Tivadar Cseri ,  Slavik Kasztelan

IPC分类号： C07C522

CPC分类号： C10G45/62 ,  B01J21/12 ,  B01J23/40 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/10

摘要： A catalyst comprising at least one noble metal deposited on an acidic support, wherein the dispersion of the noble metal is less than 20%.

摘要翻译： 包含沉积在酸性载体上的至少一种贵金属的催化剂，其中贵金属的分散体小于20％。

公开(公告)号：US06712953B1

公开(公告)日：2004-03-30

申请号：US09603838

申请日：2000-10-16

申请人： Slavik Kasztelan ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Leyrit ,  Philippe Dascotte ,  Elisabeth Rosenberg

发明人： Slavik Kasztelan ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Leyrit ,  Philippe Dascotte ,  Elisabeth Rosenberg

IPC分类号： B01J2906

CPC分类号： C10G47/20 ,  B01J29/076

摘要： The invention relates to a catalyst that contains at least one matrix, at least one zeolite and at least one hydro-dehydrogenating element that is located at the matrix (deposited on the catalyst or contained in the matrix), in which the zeolite contains in its porous network at least one element of group VIB and/or group VIII. Said hydro-dehydrogenating element preferably belongs to group VIB and/or to group VIII of the periodic table. The catalyst contains at least one promoter element)phosphorus, boron, silicon). The invention also relates to the use of this catalyst for the transformation of hydrocarbon fractions, in particular hydrorefining and hydrocracking

摘要翻译： 本发明涉及一种催化剂，其含有至少一种基质，至少一种沸石和位于基质（沉积在催化剂上或包含在基质中）的至少一种氢化脱氢元素，其中沸石中含有 VIB组和/或VIII组的至少一种元素的多孔网络。 所述加氢脱氢元件优选属于元素周期表VIB族和/或VIII族。 催化剂含有至少一种助催化剂元素）磷，硼，硅）。 本发明还涉及该催化剂用于烃馏分转化，特别是加氢精制和加氢裂化的用途

公开(公告)号：US06531051B1

公开(公告)日：2003-03-11

申请号：US09603837

申请日：2000-06-26

申请人： Slavik Kasztelan ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Leyrit ,  Philippe Dascotte ,  Elisabeth Rosenberg

发明人： Slavik Kasztelan ,  Nathalie Marchal-George ,  Tivadar Cseri ,  Pierre Leyrit ,  Philippe Dascotte ,  Elisabeth Rosenberg

IPC分类号： B01J29072

CPC分类号： B01J29/076 ,  C10G47/20

摘要： The invention relates to a catalyst that contains at least one matrix, at least one zeolite and at least one element that is deposited on the catalyst or contained in the matrix and selected from the group that is formed by the elements of groups VIB, VIII and VB, and at least one promoter element (phosphorus, boron, silicon), in which the zeolite contains in its porous network at least one element of group VB. The invention also relates to the use of this catalyst for the transformation of hydrocarbon fractions, in particular hydrorefining and hydrocracking.

摘要翻译： 本发明涉及一种催化剂，其含有至少一种基质，至少一种沸石和至少一种元素，其沉积在催化剂上或包含在基质中并且选自由VIB，VIII族和VIII族元素形成的基团 VB和至少一种助催化剂元素（磷，硼，硅），其中沸石在其多孔网络中含有VB族的至少一种元素。 本发明还涉及该催化剂用于烃馏分转化，特别是加氢精制和加氢裂化的用途。

公开(公告)号：US06387246B1

公开(公告)日：2002-05-14

申请号：US09572970

申请日：2000-05-18

申请人： Eric Benazzi ,  Jean-Marie Deves ,  Bernadette Rebours ,  Frédéric Chaigne ,  Tivadar Cseri ,  Slavik Kasztelan

发明人： Eric Benazzi ,  Jean-Marie Deves ,  Bernadette Rebours ,  Frédéric Chaigne ,  Tivadar Cseri ,  Slavik Kasztelan

IPC分类号： C01G4718

CPC分类号： B01J29/084 ,  B01J29/166 ,  B01J2229/20 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  C10G45/12 ,  C10G47/16

摘要： The invention relates to a catalyst that contains at least one matrix, a partially amorphous Y zeolite, optionally at least one metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table, optionally at least one element that is selected from the group that is formed by phosphorus, boron and silicon, optionally at least one element of group VIIA, and optionally at least one element of group VIIB. The partially amorphous Y zeolite has a peak rate that is less than 0.4, and a crystalline fraction that is expressed relative to a reference zeolite in sodium form and that is less than 60%. The invention also relates to the use of this catalyst in hydroconversion, in particular hydrocracking and hydrorefining of hydrocarbon feedstocks.

摘要翻译： 本发明涉及一种催化剂，其含有至少一种基质，部分无定形Y沸石，任选至少一种金属，其选自由元素周期表第ⅥB族和Ⅷ族金属形成的基团，任选至少 选自由磷，硼和硅形成的基团，任选的ⅦA族的至少一种元素和任选的至少一种ⅦB族元素的一种元素。 部分无定形的Y沸石具有小于0.4的峰值速率和相对于钠形式的参考沸石表达并且小于60％的结晶部分。 本发明还涉及该催化剂在加氢转化中的用途，特别是烃原料的加氢裂化和加氢精制。

公开(公告)号：US06733657B2

公开(公告)日：2004-05-11

申请号：US10045678

申请日：2002-01-15

申请人： Eric Benazzi ,  Tivadar Cseri ,  Magalie Roy-Auberger ,  Patrick Euzen

发明人： Eric Benazzi ,  Tivadar Cseri ,  Magalie Roy-Auberger ,  Patrick Euzen

IPC分类号： C10G4704

CPC分类号： C10G47/12 ,  B01J21/12 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/20

摘要： A hydrocarbon conversion catalyst contains at least one silica-alumina having the following characteristics: A content by weight of silica SiO2 of between 10 and 60% by weight; an Na content less than 300 ppm by weight; a total pore volume of between 0.5 and 1.2 m/g measured by mercury porosimetry; a porosity of said silica-alumina wherein: the volume of mesopores whose diameter is between 40 Å and 150 Å, and whose mean diameter varies between 80 and 120 Å represents between 30 and 80% of the total pore volume, and (ii) the volume of macropores, whose diameter is greater than 500 Å and preferably between 1000 Å and 10,000 Å represents between 20 and 80% of the total pore volume; a specific surface area greater than 200 m2/g, and at least one hydro-dehydrogenating element selected metals of group VIB and group VIII, and optionally phosphorus, boron, silicon, or elements of group VIIA, VIIB or VB.

摘要翻译： 烃转化催化剂含有至少一种具有以下特征的二氧化硅 - 氧化铝：二氧化硅SiO 2的重量含量为10至60重量％; Na含量小于300重量ppm; 通过水银孔率法测量的总孔体积为0.5-1.2m 2 / g; 所述二氧化硅 - 氧化铝的孔隙率，其中直径为介于40和150之间，其平均直径在80和120之间变化的介孔的体积占总孔体积的30至80％，和（ii） 其直径大于500埃，优选在1000埃至10,000埃之间的大孔体积占总孔体积的20至80％; 比表面积大于200m 2 / g，以及至少一种加氢脱氢元素选择VIB族和VIII族的金属，以及任选的磷，硼，硅或VIIA，VIIB或VB族的元素。

公开(公告)号：US07513990B2

公开(公告)日：2009-04-07

申请号：US11220987

申请日：2005-09-08

申请人： Denis Guillaume ,  Sylvie Lopez ,  Tivadar Cseri

发明人： Denis Guillaume ,  Sylvie Lopez ,  Tivadar Cseri

IPC分类号： C10G45/04 ,  B01J27/02 ,  B01J27/04

CPC分类号： C10G45/04 ,  B01J23/85 ,  B01J23/883 ,  B01J27/19 ,  B01J35/1019 ,  B01J37/20 ,  C10G47/06 ,  C10G2300/207 ,  C10G2300/705

摘要： The invention relates to a process for sulfurization of catalysts for hydrotreatment, in particular the catalysts for hydrotreating refractory oxides by sulfurization, in which said catalysts are subjected to a sulfurization stage under a gas atmosphere that contains hydrogen sulfide (H2S), hydrogen (H2), and optionally a cover gas for dilution and in which the H2S/H2 molar ratio is more than 4 and the H2S partial pressure is at least equal to 1 kPa.Said sulfurization stage can be carried out in the hydrotreatment unit (sulfurization in situ) or, prior to the charging of the catalyst, in the hydrotreatment unit (sulfurization ex situ) and is generally carried out at a temperature of less than 600° C., preferably less than 500° C.The invention also relates to the catalysts that are sulfurized by said sulfurization process and their use for hydrorefining and/or hydroconversion/hydrocracking of hydrocarbon feedstocks.

摘要翻译： 本发明涉及用于加氢处理的催化剂的硫化方法，特别是用于通过硫化加氢处理难熔氧化物的催化剂，其中所述催化剂在含有硫化氢（H 2 S），氢气（H 2））的气体气氛下进行硫化阶段， ，以及任选的用于稀释的覆盖气体，其中H 2 S / H 2摩尔比大于4，H 2 S分压至少等于1kPa。 所述硫化阶段可以在加氢处理装置（原位硫化）中进行，或者在加入催化剂之前，在加氢处理装置（非原生硫化）中进行，通常在低于600℃的温度下进行。 优选小于500℃。本发明还涉及通过所述硫化方法硫化的催化剂及其用于烃原料的加氢精制和/或加氢转化/加氢裂化的用途。