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公开(公告)号：US20090182172A1
公开(公告)日：2009-07-16
申请号：US12221517
申请日：2008-08-04
IPC分类号： C07F5/02
CPC分类号： G03H1/02 , C07C381/12 , C07F5/027 , G03F7/0045 , G03F7/029 , G03F7/031 , G03F7/038 , G03F7/0755 , G03H2260/12
摘要： The present invention discloses a new class of triarylsulfonium salt photoacid generators (PAGs), which are thermally stable and can be activated by long wavelength UV or visible light. The sulfonium PAGs of the present invention are additionally soluble in monomers that can be polymerized by cationic polymerization chemistry, and mixtures of said sulfonium PAGs and monomers can be stored for long periods of time without undergoing polymerization. Furthermore, typical holographic recording media comprising one of these sulfonium PAGs, polymerizable monomer(s), a sensitizing dye, and a binder can be stored for long periods of time without exhibiting significant loss of recording sensitivity. Preferred sulfonium PAGs of the present invention are sulfonium PAGs substituted with one or more fluoro or fluoroalkyl groups.
摘要翻译： 本发明公开了一类新的三芳基锍盐光致酸发生剂（PAG），它们是热稳定的并且可以通过长波长的紫外或可见光活化。 本发明的锍PAG还可溶于可通过阳离子聚合化学反应聚合的单体，并且所述锍PAG和单体的混合物可以长时间储存而不经历聚合。 此外，包含这些锍PAG，可聚合单体，敏化染料和粘合剂中的一种的典型全息记录介质可以长时间储存，而不会显着降低记录灵敏度。 本发明优选的锍PAG是被一个或多个氟代或氟烷基取代的锍PAG。
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公开(公告)号：US20090042105A1
公开(公告)日：2009-02-12
申请号：US12070913
申请日：2008-02-21
CPC分类号： G03F7/0045 , C09B3/78 , C09B3/82 , G03F7/038 , G03F7/0755 , G11B7/24044 , G11B7/244 , G11B7/246 , G11B7/249
摘要： Photosensitizing dyes are often used in conjunction with a photoacid generator in holographic recording media. Conventional photosensitizing dyes typically are limited by having an appreciable absorption of light when used in a sufficient concentration, such that the intensity of light decreases significantly with penetration into a recording medium. The present invention discloses a number of new 5-alkynyl substituted napthacene photosensitizing dyes that have low extinction coefficients coupled with good sensitizing properties, such that the problems associated with the photosensitizing dyes absorbing light are significantly reduced.
摘要翻译： 光敏染料通常与全息记录介质中的光致酸发生器结合使用。 常规的光敏染料通常在以足够的浓度使用时具有明显的光吸收来限制，使得光的强度随着渗入记录介质而显着降低。 本发明公开了许多具有低消光系数和良好的敏化性能的新的5-炔基取代的萘并茂光敏染料，使得与吸收光的光敏染料相关的问题显着降低。
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公开(公告)号：US07892702B2
公开(公告)日：2011-02-22
申请号：US12070913
申请日：2008-02-21
CPC分类号： G03F7/0045 , C09B3/78 , C09B3/82 , G03F7/038 , G03F7/0755 , G11B7/24044 , G11B7/244 , G11B7/246 , G11B7/249
摘要： Photosensitizing dyes are often used in conjunction with a photoacid generator in holographic recording media. Conventional photosensitizing dyes typically are limited by having an appreciable absorption of light when used in a sufficient concentration, such that the intensity of light decreases significantly with penetration into a recording medium. The present invention discloses a number of new 5-alkynyl substituted napthacene photosensitizing dyes that have low extinction coefficients coupled with good sensitizing properties, such that the problems associated with the photosensitizing dyes absorbing light are significantly reduced.
摘要翻译： 光敏染料通常与全息记录介质中的光致酸发生器结合使用。 常规的光敏染料通常在以足够的浓度使用时具有明显的光吸收来限制，使得光的强度随着渗入记录介质而显着降低。 本发明公开了许多具有低消光系数和良好的敏化性能的新的5-炔基取代的萘并茂光敏染料，使得与吸收光的光敏染料相关的问题显着降低。
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4.发明申请SENSITIZER DYES FOR PHOTOACID GENERATING SYSTEMS USING SHORT VISIBLE WAVELENGTHS 审中-公开光敏发生系统的敏感度使用短视觉波长公开(公告)号：US20100039684A1
公开(公告)日：2010-02-18
申请号：US12310126
申请日：2007-08-10
CPC分类号： G03F7/0045 , C07C15/62 , C09B57/00 , C09B69/008 , G03F7/001 , G03F7/038 , G03H1/02 , G03H2001/0264 , G03H2260/12 , G11B7/24044 , G11B7/245 , G11B7/246
摘要： Photosensitizing dyes are often used in conjunction with a photoacid generator in photopolymerizable materials and in holographic recording media. Typical dyes for these materials are used in the region of the visible spectrum for wavelengths greater than about 450 run. The present invention discloses a number of new 1,4-alkynyl substituted napthalene photosensitizing dyes that have suitably low extinction coefficients coupled with good sensitizing properties for use in such materials at wavelengths in the visible spectrum region of about 400 nm.
摘要翻译： 光敏染料通常与可光聚合材料和全息记录介质中的光致酸产生剂结合使用。 这些材料的典型染料用于波长大于约450nm的可见光谱区域。 本发明公开了许多具有合适的低消光系数的新的1,4-炔基取代的萘光敏染料，其具有良好的敏化性能，用于在约400nm的可见光谱区域中的波长处的这种材料。
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公开(公告)号：US06242154B1
公开(公告)日：2001-06-05
申请号：US09210101
申请日：1998-12-11
申请人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Socorro M. Ramos , Stephen G. Stroud , Stephen J. Telfer , Haixin Yang , Roger A. Boggs , Eric S. Kolb
发明人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Socorro M. Ramos , Stephen G. Stroud , Stephen J. Telfer , Haixin Yang , Roger A. Boggs , Eric S. Kolb
IPC分类号： G03C1492
CPC分类号： G03C1/73 , B41M5/30 , G03F7/0045
摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.
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公开(公告)号：US6110638A
公开(公告)日：2000-08-29
申请号：US757195
申请日：1996-11-27
申请人： Roger A. Boggs , Jurgen M. Grasshoff , Eric S. Kolb , John L. Marshall , Richard A. Minns , Socorro M. Ramos , Stephen G. Stroud , Stephen J. Telfer , Haixin Yang
发明人： Roger A. Boggs , Jurgen M. Grasshoff , Eric S. Kolb , John L. Marshall , Richard A. Minns , Socorro M. Ramos , Stephen G. Stroud , Stephen J. Telfer , Haixin Yang
CPC分类号： B41M5/30 , G03C1/73 , G03F7/0045 , Y10S430/115
摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group, followed by loss of a proton from the secondary acid generator to form an unstable intermediate, which then fragments with loss of the second leaving group, accompanied by either (a) loss of a second proton; or (b) addition of a proton-containing nucleophile, followed by loss of a proton, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.
摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸产生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团，然后丢失质子 从次级酸产生器形成不稳定的中间体，然后随着第二离去基团的损失而断裂，伴随着（a）第二质子的损失; 或者（b）加入含质子的亲核试剂，然后与质子组合丢失质子，第二离去基团与质子结合，形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736; 5,441,850和5,453,345。
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公开(公告)号：US06489065B1
公开(公告)日：2002-12-03
申请号：US08649823
申请日：1996-05-17
申请人： Pradeep K. Dhal , Eric S. Kolb , Richard A. Minns
发明人： Pradeep K. Dhal , Eric S. Kolb , Richard A. Minns
IPC分类号： G03H102
CPC分类号： G03H1/02 , G03F7/001 , G03F7/0045 , G03F7/039 , G03H2001/026 , G03H2260/12
摘要： A holographic recording medium comprises (a) an acid generator capable of generating an acid upon exposure to actinic radiation; and (b) a polymer comprising a plurality of high refractive index moieties, a plurality of low refractive index moieties, and a plurality of acid-sensitive linking groups connecting the high and low refractive index moieties. When an interference pattern is formed within this medium, in the light areas of this interference pattern acid is generated by the acid generator and cleaves the acid-sensitive linking groups, thereby causing separation of either the high or the low refractive index moieties from the polymer, and formation of a hologram within the medium.
摘要翻译： 全息记录介质包括（a）能够在暴露于光化辐射时产生酸的酸发生剂; 和（b）包含多个高折射率部分，多个低折射率部分和连接高折射率部分和低折射率部分的多个酸敏感连接基团的聚合物。 当在该介质中形成干涉图案时，在该干涉图形的光区域中，酸由酸产生器产生并切割酸敏感性连接基团，从而导致高分子折射率部分或低折射率部分与聚合物分离 ，以及在介质内形成全息图。
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8.发明授权Electroluminescent polymers, processes for their use, and electroluminescent devices containing these polymers 失效电致发光聚合物，其使用方法和含有这些聚合物的电致发光器件
公开(公告)号：US5414069A
公开(公告)日：1995-05-09
申请号：US12038
申请日：1993-02-01
申请人： William J. Cumming , Russell A. Gaudiana , Richard T. Ingwall , Eric S. Kolb , Parag G. Mehta , Richard A. Minns
发明人： William J. Cumming , Russell A. Gaudiana , Richard T. Ingwall , Eric S. Kolb , Parag G. Mehta , Richard A. Minns
CPC分类号： C08G73/0233 , C08G77/04 , C08G77/26 , C09K11/06
摘要： An electroluminescent polymer comprises a main chain and a plurality of side chains, each of the side chains comprising an electroluminescent group and a flexible spacer connecting the electroluminescent group to the main chain, the spacers and the main chain being such that the electroluminescent groups are not conjugated with one another. The nature of the main chain and the spacer groups can be varied to enhance solubility, film-forming ability and other characteristics of the polymer, without significantly changing the electroluminescent properties of the polymer.
摘要翻译： 电致发光聚合物包括主链和多个侧链，每个侧链包含电致发光基团和连接电致发光基团与主链的柔性间隔物，间隔基和主链使得电致发光基团不是 彼此共轭。 可以改变主链和间隔基团的性质以提高聚合物的溶解度，成膜能力和其它特性，而不显着改变聚合物的电致发光性质。
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公开(公告)号：US06307085B1
公开(公告)日：2001-10-23
申请号：US09627939
申请日：2000-07-28
申请人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Socorro M. Ramos , Stephen G. Stroud , Stephen J. Telfer , Haixin Yang , Roger A. Boggs , Eric S. Kolb
发明人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Socorro M. Ramos , Stephen G. Stroud , Stephen J. Telfer , Haixin Yang , Roger A. Boggs , Eric S. Kolb
IPC分类号： C07F902
CPC分类号： G03C1/73 , B41M5/30 , G03F7/0045
摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.
摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸发生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团以形成亲电子加成的阳离子 涉及在相邻位置处带有质子的不饱和试剂和在相邻位置处含质子的亲核基团，随后试剂上的所述质子损失，第二离去基团被所述亲核基团置换，第二离去基团， 与质子结合形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736; 5,441,850和5,453,345。
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公开(公告)号：US5914213A
公开(公告)日：1999-06-22
申请号：US944284
申请日：1997-10-06
申请人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Socorro M. Ramos , Stephen G. Stroud , Stephen J. Telfer , Haixin Yang , Roger A. Boggs , Eric S. Kolb
发明人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Socorro M. Ramos , Stephen G. Stroud , Stephen J. Telfer , Haixin Yang , Roger A. Boggs , Eric S. Kolb
CPC分类号： G03C1/73 , B41M5/30 , G03F7/0045
摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.
摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸发生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团以形成亲电子加成的阳离子 涉及在相邻位置处带有质子的不饱和试剂和在相邻位置处含质子的亲核基团，随后试剂上的所述质子损失，第二离去基团被所述亲核基团置换，第二离去基团， 与质子结合形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736 5,441,850和5,453,345。
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