摘要:
3-Halo-3-hetarylcarboxylic acid derivatives having the formula I ##STR1## in which R is a formyl group, a group CO.sub.2 H or a radical which can be hydrolyzed to COOH, and the remaining substituents have the following meanings: R.sup.2 and R.sup.3 are halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy or C.sub.1 -C.sub.4 -alkylthio; X is nitrogen or CR.sup.13, where R.sup.13 is hydrogen or together with R.sup.3 forms an alkylene or alkenylene chain in which in each case one methylene group is replaced by oxygen; R.sup.4 is an unsubstituted or substituted five- or six-membered heteroaromatic ring which contains one to three nitrogen atoms and/or one sulfur or oxygen atom; R.sup.5 is hydrogen, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl or phenyl; Y is sulfur, oxygen or a single bond; and Z is halogen. The derivatives I having herbicidal and plant-growth regulating properties.
摘要:
3-(Het)arylcarboxylic acid derivatives of the formula I ##STR1## where R is formyl, CO.sub.2 H or a radical hydrolyzable to COOH and the other substituents have the following meanings: R.sup.2 and R.sup.3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio; X is nitrogen or CR.sup.14, where R.sup.14 is hydrogen or, together with R.sup.3, forms an alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen; R.sup.4 is phenyl or naphthyl, each of which is unsubstituted or substituted or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom; R.sup.5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl; R.sup.6 is C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or C.sub.3 -C.sub.4 -cyclo-alkyl, each of which may be mono- or polysubstituted; Y is sulfur, oxygen or a single bond; and Z is sulfur or oxygen; with the proviso that R.sup.6 is not unsubstituted C.sub.1 -C.sub.4 -alkyl when R.sup.4 is unsubstituted phenyl, Z is oxygen and simultaneously R.sup.5 is methyl or hydrogen.
摘要:
Heteroaromatically condensed hydroxypyridonecarboxamides of the structure I ##STR1## where the substituents and the ring Q have the following meanings: R.sup.1 hydrogen, hydroxyl, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy;R.sup.2 hydrogen, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, alkenyloxy, dialkylamino;orR.sup.1, R.sup.2 together denote an alkylene chain with 2-6 members and which may be interrupted by oxygen, sulfur or N-methyl;X oxygen or sulfur;Q a 5- or 6-membered heteroaromatic ring containing from 1 to 3 nitrogen atoms and/or one oxygen or sulfur atom as heteroatoms, and which may be substituted one to three times,and environmentally compatible salts thereof.
摘要翻译:取代基和环Q具有下列含义的结构I(I)的杂芳族缩合羟基吡啶甲酰胺:R 1氢,羟基,取代或未取代的烷基,烯基,炔基,环烷基,烷氧基; R 2氢,取代或未取代的烷基,烯基,炔基,环烷基,烯氧基,二烷基氨基; 或R 1,R 2一起表示具有2-6个成员的亚烷基链,并且其可被氧,硫或N-甲基中断; X氧或硫; Q是含有1至3个氮原子和/或一个氧或硫原子作为杂原子并且可被一至三次取代的5-或6-元杂芳环及其与环境相容的盐。
摘要:
Quinoline-3-carboxamides I ##STR1## where R.sup.1 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, and the organic radicals may be substituted or unsubstituted; R.sup.2 is hydrogen, hydroxyl, alkoxy, alkenyloxy, dialkylamino, alkyl, alkenyl, alkynyl, cycloalkyl, and the organic radicals may be substituted or unsubstituted; or R.sup.1, R.sup.2 together denote an alkylene chain of 4 to 7 members and which may be interrupted by oxygen, sulfur or N-methyl; R.sup.3 -R.sup.6 are hydrogen, alkyl, alkoxy, haloalkyl, haloalkoxy, alkylthio, haloalkylthio, halogen, cyano or nitro; X is oxygen or sulfur; with the proviso that R.sup.2 is not hydrogen, C.sub.1 -C.sub.3 -alkyl, n-butyl, 3-methylbutyl, cyclohexyl, hexyl, heptyl, octyl, 2-chlorobenzyl, 3-(dimethylamino)propyl, 3-(diethylamino)propyl, 2-morpholinoethyl or 2-(3,4-dimethoxyphenyl)ethyl when R.sup.1 and R.sup.3 to R.sup.6 are hydrogen and X is oxygen, and that R.sup.2 is not benzyl when R.sup.1 is methyl, R.sup.3 to R.sup.6 are hydrogen and X is oxygen, and that R.sup.1 and R.sup.2 do not jointly denote morpholino when R.sup.3 to R.sup.6 are hydrogen and X is oxygen.
摘要:
Quinoline-3-carboxamides I ##STR1## where R.sup.1 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, and the organic radicals may be substituted or unsubstituted;R.sup.2 is hydrogen, hydroxyl, alkoxy, alkenyloxy, dialkylamino, alkyl, alkenyl, alkynyl, cycloalkyl, and the organic radicals may be substituted or unsubstituted;orR.sup.1, R.sup.2 together denote an alkylene chain of 4 to 7 members and which may be interrupted by oxygen, sulfur or N-methyl;R.sup.3 -R.sup.6 are hydrogen, alkyl, alkoxy, haloalkyl, haloalkoxy, alkylthio, haloalkylthio, halogen, cyano or nitro;X is oxygen or sulfur;with the proviso that R.sup.2 is not hydrogen, C.sub.1 -C.sub.3 -alkyl, n-butyl, 3-methylbutyl, cyclohexyl, hexyl, heptyl, octyl, 2-chlorobenzyl, 3-(dimethylamino)propyl, 3-(diethylamino)propyl, 2-morpholinoethyl or 2-(3,4-dimethoxyphenyl)ethyl when R.sup.1 and R.sup.3 to R.sup.6 are hydrogen and X is oxygen, and that R.sup.2 is not benzyl when R.sup.1 is methyl, R.sup.3 to R.sup.6 are hydrogen and X is oxygen, and that R.sup.1 and R.sup.2 do not jointly denote morpholino when R.sup.3 to R.sup.6 are hydrogen and X is oxygen.
摘要:
Heteroaromatically condensed hydroxypyridonecarboxamides of the structure I ##STR1## where the substituents and the ring Q have the following meanings: R.sup.1 hydrogen, hydroxyl, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy;R.sup.2 hydrogen, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, alkenyloxy, dialkylamino; orR.sup.1, R.sup.2 together denote an alkylene chain with 2-6 members and which may be interrupted by oxygen, sulfur or N-methyl;X oxygen or sulfur;Q a 5- or 6-membered heteroaromatic ring containing from 1 to 3 nitrogen atoms and/or one oxygen or sulfur atom as heteroatoms, and which may be substituted one to three times,and environmentally compatible salts thereof.
摘要翻译:取代基和环Q具有下列含义的结构I(I)的杂芳族缩合羟基吡啶甲酰胺:R 1氢,羟基,取代或未取代的烷基,烯基,炔基,环烷基,烷氧基; R 2氢,取代或未取代的烷基,烯基,炔基,环烷基,烯氧基,二烷基氨基; 或R 1,R 2一起表示具有2-6个成员的亚烷基链,并且其可被氧,硫或N-甲基中断; X氧或硫; Q是含有1至3个氮原子和/或一个氧或硫原子作为杂原子并且可被一至三次取代的5-或6-元杂芳环及其与环境相容的盐。
摘要:
Hydroxypyridonecarboxamides of the formula I ##STR1## where: X is oxygen or sulfur;R.sup.1, R.sup.2 independently of each other are hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl or alkoxy, and these organic radicals are substituted or unsubstituted;R.sup.3 is hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, halogen or nitro;R.sup.4 is alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy, alkylthio, phenyl or a 5- or 6-membered heterocyclic, aliphatic or aromatic radical containing from one to three heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, and these radicals are substituted or unsubstituted;with the exception of 6-methyl-4-hydroxypyrid-2-one-3-carboxamide and 6-methyl-4-hydroxypyrid-2-one-3-carboxylic acid-tert-butylamide.
摘要翻译:式I的羟基吡啶甲酰胺(I)其中:X是氧或硫; R 1,R 2彼此独立地是氢,烷基,烯基,炔基,环烷基,环烷基烷基或烷氧基,并且这些有机基团是取代或未取代的; R3是氢,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基,卤素或硝基; R 4是烷基,烯基,炔基,环烷基,烷氧基,烷硫基,苯基或含有1至3个选自氧,硫和氮的杂原子的5或6元杂环,脂族或芳族基团, 是取代或未取代的; 除了6-甲基-4-羟基吡啶-2-酮-3-甲酰胺和6-甲基-4-羟基吡啶-2-酮-3-羧酸 - 叔丁基酰胺之外。
摘要:
Isoxazolines of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.7 -cycloalkyl, substituted or unsubstituted phenyl, or a saturated or unsaturated 5- or 6-membered heterocycle;R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are hydrogen, C.sub.1 -C.sub.4 -alkyl or benzyl andR.sup.7 is substituted or unsubstituted C.sub.2 -C.sub.6 -alkenyl, C.sub.5 -C.sub.7 -cycloalkenyl, phenyl, naphthyl or thienyl,processes for their manufacture, and their use.
摘要:
Isoxazole(isothiazole)-5-carboxamides, having herbicidal activity, of the formula ##STR1## where X is oxygen or sulfur,R.sup.1 is hydrogen, substituted or unsubstituted alkyl, alkoxy, substituted or unsubstituted cycloalkyl, a 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, and which may be substituted, or substituted or unsubstituted phenyl, orR.sup.2 is formyl, 4,5-dihydrooxazol-2-yl or a radical of the formula COYR.sup.5 or CONR.sup.6 R.sup.7.
摘要:
Bithienyl derivatives of the formula Ia ##STR1## where the substituents have the following meanings: R.sup.1, R.sup.2 hydrogen, halogen, nitro, formyl, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.8 -cycloalkoxy, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, substituted or unsubstituted C.sub.1 -C.sub.6 -alkylcarbonyl, substituted or unsubstituted C.sub.3 -C.sub.6 -cycloalkylcarbonyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxycarbonyl and/or phenylcarbonyl;R.sup.3 hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl or C.sub.1 -C.sub.4 -haloalkoxy;A --CSNH.sub.2 ;substituted or unsubstituted oxazol-2-yl, oxazol-5-yl, isoxazol-3-yl, pyrazol-3-yl, pyrazol-5-yl, thiazol-2-yl or a corresponding benzofused radical;methods of manufacturing compounds Ia and agents containing a bithienyl derivative of the general formula I ##STR2## where B is --CSNH.sub.2 ;substituted or unsubstituted pyridyl, quinolinyl, phenyl, naphthyl, furyl, pyrrolyl, pyrazolyl, imidazolyl, oxazolyl, isoxazolyl, thiazolyl or a corresponding benzofused radical.