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公开(公告)号:US11891517B2
公开(公告)日:2024-02-06
申请号:US17908769
申请日:2021-03-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Anatoly I. Kramer , Alexander V. Zabula , Elizabeth A. Turner , Raf de Meester , Helge Jaensch , Jeffrey C. Bunquin , Javier Guzman , Emiel de Smit , John S. Coleman , Madelyn Bekker , Roxana Perez Velez
CPC classification number: C08L91/06 , C07C6/04 , C07C7/163 , C07C2531/22
Abstract: Wax compositions may be obtained by providing an olefinic feed comprising a first linear alpha olefin having m carbon atoms and a second linear alpha olefin having n carbon atoms, wherein m and n are independently selected integers each ranging from about 12 to about 100, and the olefinic feed optionally comprises one or more internal olefins and/or one or more branched olefins; contacting the olefinic feed with a metal carbene catalyst in a reactor; forming ethylene and a hydrocarbon substance comprising a linear olefin dimer comprising two carbon atoms less than a sum of m and n; removing the ethylene from the reactor while forming the linear olefin dimer; and isolating a wax composition comprising the linear olefin dimer, a hydrogenated reaction product thereof, or any combination thereof.
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公开(公告)号:US20220176365A1
公开(公告)日:2022-06-09
申请号:US17442710
申请日:2020-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jeffrey C. Bunquin , Joshua J. Willis , Paul F. Keusenkothen , Javier Guzman , Jennifer R. Pena
IPC: B01J35/00 , B01J23/889 , B01J35/08 , B01J6/00 , B01J37/02 , B01J37/00 , C07C1/04 , C07C29/156
Abstract: Disclosed are novel supported nanoparticle compositions, precursors, processes for making supported nanoparticle compositions, processes for making catalyst compositions, and processes for converting syngas. The catalyst composition can comprise nanoparticles comprising metal oxide(s), such as manganese cobalt oxide. This disclosure is particularly useful for converting syngas via the Fischer-Tropsch reactions to make olefins and/or alcohols.
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公开(公告)号:US11857954B2
公开(公告)日:2024-01-02
申请号:US17442710
申请日:2020-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jeffrey C. Bunquin , Joshua J. Willis , Paul F. Keusenkothen , Javier Guzman , Jennifer R. Pena
IPC: B01J35/00 , B01J6/00 , B01J23/889 , B01J35/08 , B01J37/00 , B01J37/02 , C07C1/04 , C07C29/156
CPC classification number: B01J35/0013 , B01J6/001 , B01J23/8892 , B01J35/006 , B01J35/08 , B01J37/0072 , B01J37/0207 , B01J37/0209 , B01J37/0215 , C07C1/0435 , C07C29/156 , C07C2523/84
Abstract: Disclosed are novel supported nanoparticle compositions, precursors, processes for making supported nanoparticle compositions, processes for making catalyst compositions, and processes for converting syngas. The catalyst composition can comprise nanoparticles comprising metal oxide(s), such as manganese cobalt oxide. This disclosure is particularly useful for converting syngas via the Fischer-Tropsch reactions to make olefins and/or alcohols.
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4.
公开(公告)号:US20220161243A1
公开(公告)日:2022-05-26
申请号:US17433641
申请日:2020-02-06
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jeffrey C. Bunquin , Partha Nandi , Paul F. Keusenkothen , Vera Grankina , Robert Panepinto
Abstract: Disclosed are novel catalyst compositions, catalyst precursors, processes for making catalyst precursors, processes for making catalyst compositions, and processes for converting syngas. The catalytic component in the catalyst composition can comprise a metal carbide and/or a metal nitride. This disclosure is particularly useful for converting syngas via the Fischer-Tropsch reactions to make olefins and/or alcohols.
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公开(公告)号:US20240010579A1
公开(公告)日:2024-01-11
申请号:US18042386
申请日:2021-08-10
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jeffrey C. Bunquin , Joshua J. Willis , Partha Nandi , Javier Guzman
CPC classification number: C07C1/044 , B01J23/83 , B01J23/8892 , B01J35/0013 , B01J35/006 , B01J37/18 , B01J37/082 , B01J37/0205 , B01J37/0236 , C07C2523/06 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/04 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/50 , C07C2523/10
Abstract: Fischer-Tropsch processes for converting syngas produces linear alpha olefins at high yield and selectivity in the presence of supported nano-particle catalyst compositions and/or metal carbide/nitride-containing catalyst compositions.
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6.
公开(公告)号:US20230159759A1
公开(公告)日:2023-05-25
申请号:US17908746
申请日:2021-03-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Anatoly I. Kramer , Alexander V. Zabula , Elizabeth A. Turner , Roxana Perez Velez , Helge Jaensch , Jeffrey C. Bunquin , Javier Guzman , Emiel de Smit , John S. Coleman , Madelyn Bekker
IPC: C08L91/06 , C11C5/00 , C09J191/06
CPC classification number: C08L91/06 , C11C5/002 , C09J191/06
Abstract: Wax compositions may be obtained by subjecting one or more linear alpha olefins to olefin metathesis and optionally hydrogenating. The wax compositions comprise: a hydrocarbon substance comprising a linear olefin dimer formed from a first linear alpha olefin having m carbon atoms and a second linear alpha olefin having n carbon atoms, a hydrogenated or partially hydrogenated reaction product of the linear olefin dimer, or any combination thereof, the first linear alpha olefin and the second linear alpha olefin being the same or different, and the linear olefin dimer comprising two carbon atoms less than a sum of m and n; wherein m and n are independently selected integers each ranging from 12 to 100; and wherein the wax composition has a melting point of 25° C. or greater.
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公开(公告)号:US20230127018A1
公开(公告)日:2023-04-27
申请号:US17908769
申请日:2021-03-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Anatoly I. Kramer , Alexander V. Zabula , Elizabeth A. Turner , Raf de Meester , Helge Jaensch , Jeffrey C. Bunquin , Javier Guzman , Emiel de Smit , John S. Coleman , Madelyn Bekker , Roxana Perez Velez
Abstract: Wax compositions may be obtained by providing an olefinic feed comprising a first linear alpha olefin having m carbon atoms and a second linear alpha olefin having n carbon atoms, wherein m and n are independently selected integers each ranging from about 12 to about 100, and the olefinic feed optionally comprises one or more internal olefins and/or one or more branched olefins; contacting the olefinic feed with a metal carbene catalyst in a reactor; forming ethylene and a hydrocarbon substance comprising a linear olefin dimer comprising two carbon atoms less than a sum of m and n; removing the ethylene from the reactor while forming the linear olefin dimer; and isolating a wax composition comprising the linear olefin dimer, a hydrogenated reaction product thereof, or any combination thereof.
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