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公开(公告)号:US20170233507A1
公开(公告)日:2017-08-17
申请号:US15504544
申请日:2015-08-14
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Wen Li , Steven A. Best , Robert J. Wittenbrink
IPC: C08F110/02 , C08L23/06 , C08J5/18
CPC classification number: C08F110/02 , C08J5/18 , C08J2323/06 , C08J2423/06 , C08L23/04 , C08L23/06 , C08L23/16 , C08L2203/16 , C08L2205/025 , C08F2500/12 , C08F2500/11 , C08F2500/26
Abstract: Disclosed are polyethylene polymers with good melt strength that can provide enhanced properties for compositions including such polyethylene polymers and films made therefrom.
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公开(公告)号:US20150232589A1
公开(公告)日:2015-08-20
申请号:US14423016
申请日:2013-08-30
Applicant: Exxonmobil Chemical Patents Inc.
Inventor: Steven A. Best , Brian R. Berg
CPC classification number: B32B27/32 , B32B27/08 , B32B27/327 , B32B2250/242 , B32B2270/00 , B32B2307/54 , B32B2307/558 , B32B2307/5825 , B32B2307/584 , C08L23/0815 , Y10T428/31855 , C08L23/06 , C08F210/16 , C08F2500/06 , C08F2500/12 , C08F2500/26 , C08F210/14
Abstract: Ethylene-based copolymers having unusual viscosity performance are described, particularly ethylene-based polymers having about 80.0 to 99.0 wt. % of polymer units derived from ethylene and about 1.0 to about 20.0 wt. % of polymer units derived from one or more C3 to C20 α-olefin comonomers; the ethylene-based polymer having a local maximum loss angle at a complex modulus, G*, of 2.50×104 to 1.00×106 Pa and a local minimum loss angle at a complex modulus, G*, of 1.00×104 to 3.00×104 Pa. The invention also includes articles, such as films, produced from such polymers and methods of making such articles.
Abstract translation: 描述了具有不寻常粘度性能的乙烯基共聚物,特别是具有约80.0至99.0wt。 衍生自乙烯的聚合物单元的%和约1.0至约20.0重量% 衍生自一种或多种C 3 -C 20α-烯烃共聚单体的聚合物单元的%; 在复数模量下的局部最大损耗角G *为2.50×104〜1.00×106Pa的乙烯类聚合物,复数模量的局部最小损耗角G *为1.00×10 4〜3.00×10 4 本发明还包括由这种聚合物制备的制品,例如薄膜,以及制造这种制品的方法。
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公开(公告)号:US20150065656A1
公开(公告)日:2015-03-05
申请号:US14329392
申请日:2014-07-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Mallarie D. McCune , Jianya Cheng , Steven A. Best
IPC: C08L23/08
CPC classification number: C08L23/0815 , C08L2203/16 , C08L23/10 , C08L23/16
Abstract: Polymer compositions that include an ethylene-based polymer and a broad molecular weight distribution propylene-based polymer having a melt strength of 20.0 cN to 200.0 cN; and optionally, a propylene-based elastomer are described. The invention also includes articles, such as films, produced from such compositions and methods of making such compositions and methods of improving melt strength.
Abstract translation: 包含乙烯基聚合物和熔体强度为20.0cN至200.0cN的宽分子量分布丙烯基聚合物的聚合物组合物; 并且任选地描述了基于丙烯的弹性体。 本发明还包括由这些组合物制备的制品,例如薄膜,以及制备这种组合物的方法和提高熔体强度的方法。
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公开(公告)号:US20150038624A1
公开(公告)日:2015-02-05
申请号:US14382812
申请日:2012-12-12
Applicant: Exxonmobil Chemical Patents Inc.
Inventor: Gerd A. Allermann , Danny Van Hoyweghen , Steven A. Best , Anthony Poloso , Nicolas M. De Ketelaere
IPC: C08J3/00 , C09D123/06 , C08J3/20
CPC classification number: C08J3/005 , C08F8/00 , C08F2810/10 , C08F2810/40 , C08J3/20 , C08J2323/06 , C09D123/06 , H01B3/441 , C08F8/50 , C08F8/06 , C08F210/16 , C08F210/14 , C08F2500/12
Abstract: Processes are disclosed for oxygen-tailoring polyethylene, particularly polyethylenes suitable for wire and cable applications. One process includes conveying a first polyethylene having a melt index ≦5.0 and an MWD ≦5.0 through mixing or extrusion apparatus having a feed zone, a melt-mixing zone downstream of the feed zone, and a melt zone downstream of the melt-mixing zone, wherein the temperature of the first polyethylene in the melt zone ranges from about 180° C. to about 300° C.; and contacting the first polyethylene with an amount of an oxygen-containing gas having at least about 20.0 parts by weight oxygen per million per parts by weight of the first polyethylene (ppm (wt) O2). Polyethylene compositions having improved properties, particularly for wire and cable applications are disclosed.
Abstract translation: 公开了用于氧气聚乙烯,特别是适用于电线和电缆应用的聚乙烯的方法。 一种方法包括通过具有进料区,进料区下游的熔融混合区和熔融区下游的熔融区的混合或挤出装置输送具有熔体指数为< E1和5.0 | MWD&NlE; 5.0的第一聚乙烯, 混合区,其中熔融区中第一聚乙烯的温度为约180℃至约300℃; 并且将第一聚乙烯与一定量的含氧气体接触,所述含氧气体具有至少约20.0重量份的氧每百万重量份的第一聚乙烯(ppm(重量)O 2))。 公开了具有改进的性能,特别是用于电线和电缆应用的聚乙烯组合物。
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公开(公告)号:US20130209774A1
公开(公告)日:2013-08-15
申请号:US13851752
申请日:2013-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Pradeep P. Shirodkar , Jianya Cheng , Peijun Jiang , Arturo Leyva , Steven A. Best
IPC: C08L23/06
CPC classification number: C08L23/06 , C08F210/14 , C08F210/16 , C08F210/18 , C08L23/08 , C08L23/0815 , C08L2205/025 , C08L2207/07
Abstract: The present invention relates to a cast film comprising a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g′vis of 0.90 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 3.0 or more; d) an Mz/Mn of 7.0 or more; e) a shear thinning ratio of 40 or more; and f) an I21 of 20 dg/min or less; where the film has at least a 10% reduction in neck-in as compared to the same composition formed into a film under the same conditions, except that the branched modifier is absent.
Abstract translation: 本发明涉及一种包含组合物的流延薄膜,该组合物包含大于25wt%(基于组合物的重量)的一种或多种线性乙烯聚合物,其g'vis为0.97以上,Mw为20,000g / mol 或更多和至少0.1重量%的支化改性剂,其中改性剂具有a)g'vis为0.90以下; b)Mw为100,000g / mol以上; c)Mw / Mn为3.0以上; d)Mz / Mn为7.0以上; e)剪切稀化比为40以上; 和f)20dg / min以下的I21; 除了不存在支化改性剂之外,与相同条件下形成膜的相同组合物相比,膜的颈缩度至少降低10%。
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公开(公告)号:US09458311B2
公开(公告)日:2016-10-04
申请号:US14329392
申请日:2014-07-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Mallarie D. McCune , Jianya Cheng , Steven A. Best
IPC: C08L23/08
CPC classification number: C08L23/0815 , C08L2203/16 , C08L23/10 , C08L23/16
Abstract: Polymer compositions that include an ethylene-based polymer and a broad molecular weight distribution propylene-based polymer having a melt strength of 20.0 cN to 200.0 cN; and optionally, a propylene-based elastomer are described. The invention also includes articles, such as films, produced from such compositions and methods of making such compositions and methods of improving melt strength.
Abstract translation: 包含乙烯基聚合物和熔体强度为20.0cN至200.0cN的宽分子量分布丙烯基聚合物的聚合物组合物; 并且任选地描述了基于丙烯的弹性体。 本发明还包括由这些组合物制备的制品,如薄膜,以及制备这种组合物的方法以及提高熔体强度的方法。
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公开(公告)号:US11299607B2
公开(公告)日:2022-04-12
申请号:US16082026
申请日:2017-02-08
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Giriprasath Gururajan , Wen Li , David B. Dunaway , Steven A. Best , Etienne R. H. Lernoux
Abstract: Sheets made from metallocene-catalyzed polyethylene polymers, optionally, with other polymers, are disclosed.
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公开(公告)号:US20200291211A1
公开(公告)日:2020-09-17
申请号:US16082026
申请日:2017-02-08
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Giriprasath Gururajan , Wen Li , David B. Dunaway , Steven A. Best , Etienne R.H. Lernoux
Abstract: Sheets made from metallocene-catalyzed polyethylene polymers, optionally, with other polymers, are disclosed.
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公开(公告)号:US20190300664A1
公开(公告)日:2019-10-03
申请号:US16068767
申请日:2017-02-08
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Etienne R.H. Lernoux , Wen Li , Achiel J.M. Van Loon , Steven A. Best , Xiao-Chuan Wang
Abstract: Films made from metallocene-catalyzed polyethylene polymers, optionally, with other polymers, are disclosed.
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公开(公告)号:US10208143B2
公开(公告)日:2019-02-19
申请号:US15504544
申请日:2015-08-14
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Wen Li , Steven A. Best , Robert J. Wittenbrink
IPC: C08F110/02 , C08J5/18 , C08L23/06 , C08L23/04 , C08L23/16
Abstract: Disclosed are polyethylene polymers with good melt strength that can provide enhanced properties for compositions including such polyethylene polymers and films made therefrom.
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