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公开(公告)号：US11702521B2
公开(公告)日：2023-07-18
申请号：US17455579
申请日：2021-11-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Zhenyu Zhu , Jianya Cheng
CPC classification number: C08J5/18 , C08L23/0815 , C08J2323/06 , C08J2323/08 , C08J2423/06 , C08J2423/08 , C08L2203/16 , C08L2205/025 , C08L2207/07 , C08L23/0815 , C08L23/0815 , C08L2205/025
Abstract: Polymer compositions and films are provided. The polymer compositions include (A) 10-50 wt % heterogeneously branched Ziegler-Natta-catalyzed LLDPE polymer having a composition distribution breadth index (CBDI)
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公开(公告)号：US10125247B2
公开(公告)日：2018-11-13
申请号：US15472981
申请日：2017-03-29
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Wen Li , Adriana S. Silva , Jianya Cheng , Periagaram S. Ravishankar
Abstract: A polyethylene composition including the product of the combination of at least one copolymer made from units derived from at least 85 wt % ethylene and a C3 to C10 α-olefin and from 0.10 wt % to 10 wt % of a cyclic-diene terpolymer is provided.
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3.发明授权Branched polyethylenes by hydrosilation grafting to improve processability of polyethylene 有权支化聚乙烯通过硅氢化硅烷接枝改善聚乙烯的加工性能公开(公告)号：US09527933B2
公开(公告)日：2016-12-27
申请号：US14031348
申请日：2013-09-19
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Rahul R. Kulkarni , Pradeep P. Shirodkar , Jianya Cheng , Donna J. Crowther
CPC classification number: C08F4/80 , C08F4/65908 , C08F4/65912 , C08F8/42 , C08F10/02 , C08F4/65927
Abstract: This invention relates to blends of polyalphaolefins (PAOs) and polyhydrosilane-modified polyolefins, methods to prepare the blends and methods to prepare polyhydrosilane-modified polyolefins.
Abstract translation: 本发明涉及聚α-烯烃（PAO）和聚氢硅烷改性聚烯烃的共混物，制备共混物的方法和制备聚氢硅烷改性聚烯烃的方法。
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4.发明申请Method of Forming Dynamically Vulcanized Thermoplastic Elastomer Films and Films Formed Therefrom 审中-公开形成动态硫化热塑性弹性体膜和薄膜的方法公开(公告)号：US20150065625A1
公开(公告)日：2015-03-05
申请号：US14532585
申请日：2014-11-04
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Hari P. Nadella , Peter W. Manders , Porter C. Shannon , Jianya Cheng
CPC classification number: B29C48/385 , B29C48/08 , B29C48/37 , B29C48/40 , B29C48/767 , B29K2021/003 , B29K2105/0038 , B29K2995/0097 , B60C1/0008 , C08J3/005 , C08J5/18 , C08J2300/26 , C08J2321/00 , C08J2323/20 , C08J2400/22 , C08L21/00 , C08L23/20 , C08L23/22 , C08L23/283 , C08L29/04 , C08L31/04 , C08L77/02 , C08L77/06 , C08L79/08 , C08L77/00 , C08L67/00 , C08L33/00 , C08L27/00 , C08L1/00
Abstract: Disclosed herein is a process to form a dynamically vulcanized thermoplastic elastomer film, also referred to as the DVA film, directly from a DVA raw material. The process comprises the steps of: 1) forming a thermoplastic elastomeric material melt comprising an elastomer and a thermoplastic resin in a first mixer under conditions such that the thermoplastic elastomeric material is dynamically vulcanized; 2) passing the thermoplastic elastomeric material melt formed in the first mixer through a second mixer to form a uniformed melt; and 3) passing the thermoplastic elastomeric material melt exiting from the second mixer through a film die to form a thermoplastic elastomer material film.
Abstract translation: 本文公开了直接从DVA原料形成动态硫化的热塑性弹性体膜（也称为DVA膜）的方法。 该方法包括以下步骤：1）在使热塑性弹性体材料动态硫化的条件下，在第一混合器中形成包含弹性体和热塑性树脂的热塑性弹性体材料熔体; 2）将在第一混合器中形成的热塑性弹性体材料熔融通过第二混合器以形成均匀的熔体; 和3）将从第二混合器排出的热塑性弹性体材料熔融通过薄膜模头，以形成热塑性弹性体材料薄膜。
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公开(公告)号：US11214659B2
公开(公告)日：2022-01-04
申请号：US14423042
申请日：2013-09-30
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Zhenyu Zhu , Jianya Cheng
Abstract: Polymer compositions including (A) 15.0 to 90.0 wt % of a heterogeneously branched ethylene polymer having polymer units derived from at least one C3-C20 alpha-olefin and having a CBDI
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Patent Agency Ranking
公开(公告)号：US20150125645A1
公开(公告)日：2015-05-07
申请号：US14596468
申请日：2015-01-14
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jianya Cheng , Pradeep P. Shirodkar , Peijun Jiang , Andrew Takacs
IPC: C08L23/06
CPC classification number: C08F210/18 , C08F4/65908 , C08J5/18 , C08L23/0815 , C08L23/083 , C08L2203/16 , C08L2205/025 , C08L2207/07 , C08L2314/06 , Y10T428/139 , C08F210/14 , C08F236/20 , C08F2500/09 , C08F2500/12 , C08F2500/17 , C08F2500/19 , C08F210/16 , C08F4/65927
Abstract: A crack-resistant article comprising a diene terpolymer, the diene terpolymer comprising (or consisting essentially of) from 0.01 wt % to 10.0 wt % diene derived units, and 1.0 wt % to 20 wt % of C4 to C10 α-olefin derived units based on the weight of the diene terpolymer, wherein the diene terpolymer: a) has a g′vis of less than 0.90; b) has an Mw within a range of from 100,000 g/mol to 500,000 g/mol; c) has an Mw/Mn within the range of from 3.5 to 12.0; and d) an Mz/Mn of greater than 7.0. Inventive articles comprise a blend of a relatively high density linear polyethylene and the diene terpolymer.
Abstract translation: 包含二烯三元共聚物的抗裂性制品，所述二烯三元共聚物包含（或由基本上由0.01重量％至10.0重量％的二烯衍生的单元组成）和1.0重量％至20重量％的C 4至C 10α-烯烃衍生的基于单元 关于二烯三元共聚物的重量，其中二烯三元共聚物：a）具有小于0.90的ag'vis; b）具有在100,000g / mol至500,000g / mol范围内的Mw; c）具有在3.5至12.0范围内的Mw / Mn; 和d）大于7.0的Mz / Mn。 本发明的制品包括相对高密度的线性聚乙烯和二烯三元共聚物的共混物。
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公开(公告)号：US20150065656A1
公开(公告)日：2015-03-05
申请号：US14329392
申请日：2014-07-11
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Mallarie D. McCune , Jianya Cheng , Steven A. Best
IPC: C08L23/08
CPC classification number: C08L23/0815 , C08L2203/16 , C08L23/10 , C08L23/16
Abstract: Polymer compositions that include an ethylene-based polymer and a broad molecular weight distribution propylene-based polymer having a melt strength of 20.0 cN to 200.0 cN; and optionally, a propylene-based elastomer are described. The invention also includes articles, such as films, produced from such compositions and methods of making such compositions and methods of improving melt strength.
Abstract translation: 包含乙烯基聚合物和熔体强度为20.0cN至200.0cN的宽分子量分布丙烯基聚合物的聚合物组合物; 并且任选地描述了基于丙烯的弹性体。 本发明还包括由这些组合物制备的制品，例如薄膜，以及制备这种组合物的方法和提高熔体强度的方法。
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公开(公告)号：US20130209774A1
公开(公告)日：2013-08-15
申请号：US13851752
申请日：2013-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Pradeep P. Shirodkar , Jianya Cheng , Peijun Jiang , Arturo Leyva , Steven A. Best
IPC: C08L23/06
CPC classification number: C08L23/06 , C08F210/14 , C08F210/16 , C08F210/18 , C08L23/08 , C08L23/0815 , C08L2205/025 , C08L2207/07
Abstract: The present invention relates to a cast film comprising a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g′vis of 0.90 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 3.0 or more; d) an Mz/Mn of 7.0 or more; e) a shear thinning ratio of 40 or more; and f) an I21 of 20 dg/min or less; where the film has at least a 10% reduction in neck-in as compared to the same composition formed into a film under the same conditions, except that the branched modifier is absent.
Abstract translation: 本发明涉及一种包含组合物的流延薄膜，该组合物包含大于25wt％（基于组合物的重量）的一种或多种线性乙烯聚合物，其g'vis为0.97以上，Mw为20,000g / mol 或更多和至少0.1重量％的支化改性剂，其中改性剂具有a）g'vis为0.90以下; b）Mw为100,000g / mol以上; c）Mw / Mn为3.0以上; d）Mz / Mn为7.0以上; e）剪切稀化比为40以上; 和f）20dg / min以下的I21; 除了不存在支化改性剂之外，与相同条件下形成膜的相同组合物相比，膜的颈缩度至少降低10％。
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公开(公告)号：US08497325B2
公开(公告)日：2013-07-30
申请号：US13628477
申请日：2012-09-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Mun F. Tse , Peijun Jiang , Jianya Cheng
CPC classification number: C08L23/06 , C08F210/16 , C08J5/18 , C08J2323/06 , C08J2423/08 , C08L23/04 , C08L23/08 , C08L23/0807 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2314/06 , C08L2666/02 , C08L2666/06 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/20 , C08F2500/26
Abstract: This invention relates to a film comprising a blend composition comprising: 1) a linear ethylene containing polymer, such as a LLDPE, a HDPE or the like; and at least 1 weight percent of an in-reactor polymer blend comprising: (a) a first ethylene containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol; and (b) a second ethylene containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.
Abstract translation: 本发明涉及包含共混组合物的膜，其包含：1）含线性乙烯的聚合物，例如LLDPE，HDPE等; 和至少1重量％的反应器内聚合物共混物，其包含：（a）密度大于0.90g / cm 3和Mw大于20,000g / mol的第一含乙烯聚合物; 和（b）密度小于0.90g / cm 3的第二含乙烯聚合物，其中聚合物共混物具有至少90℃的Tm（DSC第二熔体），小于0.92g / cm 3的密度， 并且第一和第二聚合物的密度相差至少1％。
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公开(公告)号：US10563027B2
公开(公告)日：2020-02-18
申请号：US16054827
申请日：2018-08-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jianya Cheng , Adriana S. Silva , Peijun Jiang , Wen Li , Alexander I. Norman
IPC: C08L23/06 , C08J5/18 , B29C48/10 , B29C48/00 , B29C48/88 , C08L23/08 , C08F210/18 , B29K9/00 , B29K409/00 , C08F4/659 , C08F4/6592
Abstract: A method of forming a finished film comprising extruding a molten polyethylene comprising a diene terpolymer modifier through a die opening to form a film, wherein the diene-terpolymer modifier is a terpolymer comprising ethylene-derived units, C3 to C10 α-olefin derived units, and diene-derived units; causing the film to progress in a direction away from the die opening; cooling the film at a distance from the die opening, the distance adjusted to allow relaxation of the molten polyethylene prior to solidification and/or crystallization upon cooling; and isolating a finished film therefrom. Desirably, the polyethylene is a linear low density polyethylene, and the die and cooling is suitable for forming a blown film.
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