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公开(公告)号：US20150125645A1
公开(公告)日：2015-05-07
申请号：US14596468
申请日：2015-01-14
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jianya Cheng , Pradeep P. Shirodkar , Peijun Jiang , Andrew Takacs
IPC: C08L23/06
CPC classification number: C08F210/18 , C08F4/65908 , C08J5/18 , C08L23/0815 , C08L23/083 , C08L2203/16 , C08L2205/025 , C08L2207/07 , C08L2314/06 , Y10T428/139 , C08F210/14 , C08F236/20 , C08F2500/09 , C08F2500/12 , C08F2500/17 , C08F2500/19 , C08F210/16 , C08F4/65927
Abstract: A crack-resistant article comprising a diene terpolymer, the diene terpolymer comprising (or consisting essentially of) from 0.01 wt % to 10.0 wt % diene derived units, and 1.0 wt % to 20 wt % of C4 to C10 α-olefin derived units based on the weight of the diene terpolymer, wherein the diene terpolymer: a) has a g′vis of less than 0.90; b) has an Mw within a range of from 100,000 g/mol to 500,000 g/mol; c) has an Mw/Mn within the range of from 3.5 to 12.0; and d) an Mz/Mn of greater than 7.0. Inventive articles comprise a blend of a relatively high density linear polyethylene and the diene terpolymer.
Abstract translation: 包含二烯三元共聚物的抗裂性制品，所述二烯三元共聚物包含（或由基本上由0.01重量％至10.0重量％的二烯衍生的单元组成）和1.0重量％至20重量％的C 4至C 10α-烯烃衍生的基于单元 关于二烯三元共聚物的重量，其中二烯三元共聚物：a）具有小于0.90的ag'vis; b）具有在100,000g / mol至500,000g / mol范围内的Mw; c）具有在3.5至12.0范围内的Mw / Mn; 和d）大于7.0的Mz / Mn。 本发明的制品包括相对高密度的线性聚乙烯和二烯三元共聚物的共混物。
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公开(公告)号：US20130209774A1
公开(公告)日：2013-08-15
申请号：US13851752
申请日：2013-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Pradeep P. Shirodkar , Jianya Cheng , Peijun Jiang , Arturo Leyva , Steven A. Best
IPC: C08L23/06
CPC classification number: C08L23/06 , C08F210/14 , C08F210/16 , C08F210/18 , C08L23/08 , C08L23/0815 , C08L2205/025 , C08L2207/07
Abstract: The present invention relates to a cast film comprising a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g′vis of 0.90 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 3.0 or more; d) an Mz/Mn of 7.0 or more; e) a shear thinning ratio of 40 or more; and f) an I21 of 20 dg/min or less; where the film has at least a 10% reduction in neck-in as compared to the same composition formed into a film under the same conditions, except that the branched modifier is absent.
Abstract translation: 本发明涉及一种包含组合物的流延薄膜，该组合物包含大于25wt％（基于组合物的重量）的一种或多种线性乙烯聚合物，其g'vis为0.97以上，Mw为20,000g / mol 或更多和至少0.1重量％的支化改性剂，其中改性剂具有a）g'vis为0.90以下; b）Mw为100,000g / mol以上; c）Mw / Mn为3.0以上; d）Mz / Mn为7.0以上; e）剪切稀化比为40以上; 和f）20dg / min以下的I21; 除了不存在支化改性剂之外，与相同条件下形成膜的相同组合物相比，膜的颈缩度至少降低10％。
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公开(公告)号：US09745461B2
公开(公告)日：2017-08-29
申请号：US14315425
申请日：2014-06-26
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Sunny Jacob , Peijun Jiang , Aspy K. Mehta , Pradeep P. Shirodkar , Armenag H. Dekmezian
CPC classification number: C08L47/00 , C08L23/10 , C08L23/12 , C08L23/145 , C08L23/16 , C08L2312/00 , C08L2314/06 , C08L2666/06
Abstract: A heterogeneous vulcanized polymer blend comprising a continuous phase comprising a thermoplastic polypropylene having a crystallinity of at least 30% and a dispersed phase comprising particles of an elastomeric copolymer dispersed in the continuous phase and having an average particle size of less than 5 micron. The elastomeric copolymer has a crystallinity of less than 20% and is at least partially cross-linked such that no more than about 80 wt % of the elastomeric copolymer is extractable in cyclohexane at 23° C.
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4.发明授权Branched polyethylenes by hydrosilation grafting to improve processability of polyethylene 有权支化聚乙烯通过硅氢化硅烷接枝改善聚乙烯的加工性能公开(公告)号：US09527933B2
公开(公告)日：2016-12-27
申请号：US14031348
申请日：2013-09-19
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Rahul R. Kulkarni , Pradeep P. Shirodkar , Jianya Cheng , Donna J. Crowther
CPC classification number: C08F4/80 , C08F4/65908 , C08F4/65912 , C08F8/42 , C08F10/02 , C08F4/65927
Abstract: This invention relates to blends of polyalphaolefins (PAOs) and polyhydrosilane-modified polyolefins, methods to prepare the blends and methods to prepare polyhydrosilane-modified polyolefins.
Abstract translation: 本发明涉及聚α-烯烃（PAO）和聚氢硅烷改性聚烯烃的共混物，制备共混物的方法和制备聚氢硅烷改性聚烯烃的方法。
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公开(公告)号：US20140309359A1
公开(公告)日：2014-10-16
申请号：US14315451
申请日：2014-06-26
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Peijun Jiang , Armenag Dekmezian , Aspy K. Mehta , Sunny Jacob , Andrew G. Narvaez, Jr. , Pradeep P. Shirodkar , Weiqing Weng
CPC classification number: C08L47/00 , C08F110/06 , C08F210/06 , C08L23/04 , C08L23/083 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/145 , C08L23/16 , C08L91/00 , C08L2205/03 , C08L2205/22 , C08L2207/02 , C08L2308/00 , C08L2312/00 , C08L2666/02 , C08L2666/06 , C08L2666/04 , C08F2/001 , C08F210/18 , C08F236/20 , C08F2500/20
Abstract: A heterogeneous in-situ polymer blend comprising a continuous phase comprising a polypropylene having a crystallinity of at least 30% and a melting point temperature Tm greater than 130° C., and a heat of fusion ΔHf greater than 65 J/g; and a dispersed phase comprising particles of an elastomeric copolymer dispersed in the continuous phase and having an average particle size of less than 5 micron, the elastomeric copolymer comprising ethylene units and 0.001 to 5 wt % diene by weight of the copolymer, and having a crystallinity of less than 20% and being at least partially cross-linked such that the degree of cross-link is at least 20%.
Abstract translation: 一种异相原位聚合物共混物，其包含连续相，其包含具有至少30％的结晶度和大于130℃的熔点温度Tm的聚丙烯和大于65J / g的熔化热; 和包含分散在连续相中并具有小于5微米的平均粒度的弹性共聚物颗粒的分散相，弹性体共聚物包含乙烯单元和0.001至5重量％的二烯重量的共聚物，并具有结晶度 小于20％并且至少部分交联，使得交联度至少为20％。
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Patent Agency Ranking
公开(公告)号：US11180644B2
公开(公告)日：2021-11-23
申请号：US16502256
申请日：2019-07-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jianya Cheng , Pradeep P. Shirodkar , Peijun Jiang , Johannes M. Soulages
IPC: C08L23/08 , C08L23/06 , C08F236/20 , C08F210/18 , C08J5/18 , C08L9/00
Abstract: The present invention relates to a branched modifier and a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g′vis of 0.70 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 4.0 or more; d) a shear thinning ratio of 110 or more, e) a melt strength of 10 cN or more; f) a complex viscosity at 0.1 rad/sec at 190° C. of at least 130,000 Pa·s; and g) a phase angle of Z° or less where Z=138.3G*(−0.142), where G* is the complex modulus reported in Pascals measured at 190° C. and the phase angle units are reported in degrees, wherein the G* is from 1,000 to 1,000,000 Pa.
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公开(公告)号：US09321911B2
公开(公告)日：2016-04-26
申请号：US13851752
申请日：2013-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Pradeep P. Shirodkar , Jianya Cheng , Peijun Jiang , Arturo Leyva , Steven A. Best
IPC: C08L23/08 , C08L23/06 , C08F210/18 , C08F210/14 , C08F210/16
CPC classification number: C08L23/06 , C08F210/14 , C08F210/16 , C08F210/18 , C08L23/08 , C08L23/0815 , C08L2205/025 , C08L2207/07
Abstract: The present invention relates to a cast film comprising a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g′vis of 0.90 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 3.0 or more; d) an Mz/Mn of 7.0 or more; e) a shear thinning ratio of 40 or more; and f) an I21 of 20 dg/min or less; where the film has at least a 10% reduction in neck-in as compared to the same composition formed into a film under the same conditions, except that the branched modifier is absent.
Abstract translation: 本发明涉及包含组合物的流延薄膜，该组合物包含大于25wt％（基于组合物的重量）的一种或多种线性乙烯聚合物，其具有0.97以上的Mw和20,000g / mol的Mw， 更多和至少0.1重量％的支化改性剂，其中改性剂的a'ag'vis为0.90以下; b）Mw为100,000g / mol以上; c）Mw / Mn为3.0以上; d）Mz / Mn为7.0以上; e）剪切稀化比为40以上; 和f）20dg / min以下的I21; 除了不存在支化改性剂之外，与相同条件下形成膜的相同组合物相比，膜的颈缩度至少降低10％。
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8.发明申请HDPE Modified Polyethylene Blown Film Compositions Having Excellent Bubble Stability 审中-公开具有优异泡沫稳定性的HDPE改性聚乙烯吹膜组合物公开(公告)号：US20140155553A1
公开(公告)日：2014-06-05
申请号：US14086450
申请日：2013-11-21
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Pradeep P. Shirodkar , Jianya Cheng , Rahul R. Kulkarni
IPC: C08L23/08
CPC classification number: C08L23/0815 , C08J5/18 , C08J2323/08 , C08J2423/06 , C08L23/06 , C08L2203/16 , C08L2207/062
Abstract: The present invention relates to polyethylene compositions comprising one or more ethylene polymers and one or more HDPE modifiers, in particular, this invention further relates to polyethylene blends comprising one or more ethylene polymers and one or more HDPE modifiers, wherein the modifier has: 1) a density of greater than 0.94 g/cc; 2) a Mw/Mn greater than 5; 3) a melt index (ASTM 1238, 190° C., 2.16 kg) of less than 0.7 dg/min; and 4) a g′vis of 0.96 or less.
Abstract translation: 本发明涉及包含一种或多种乙烯聚合物和一种或多种HDPE改性剂的聚乙烯组合物，特别地，本发明还涉及包含一种或多种乙烯聚合物和一种或多种HDPE改性剂的聚乙烯共混物，其中改性剂具有：1） 密度大于0.94g / cc; 2）Mw / Mn大于5; 3）小于0.7dg / min的熔体指数（ASTM 1238,190℃，2.16kg）; 和4）g'vis为0.96以下。
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9.发明申请Branched Polyethylenes by Hydrosilation Grafting to Improve Processability of Polyethylene 有权支化聚乙烯通过氢化接枝改善聚乙烯的加工性能公开(公告)号：US20140088213A1
公开(公告)日：2014-03-27
申请号：US14031348
申请日：2013-09-19
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Rahul R. Kulkarni , Pradeep P. Shirodkar , Jianya Cheng , Donna J. Crowther
CPC classification number: C08F4/80 , C08F4/65908 , C08F4/65912 , C08F8/42 , C08F10/02 , C08F4/65927
Abstract: This invention relates to blends of polyalphaolefins (PAOs) and polyhydrosilane-modified polyolefins, methods to prepare the blends and methods to prepare polyhydrosilane-modified polyolefins.
Abstract translation: 本发明涉及聚α-烯烃（PAO）和聚氢硅烷改性聚烯烃的共混物，制备共混物的方法和制备聚氢硅烷改性聚烯烃的方法。
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公开(公告)号：US20130224463A1
公开(公告)日：2013-08-29
申请号：US13851769
申请日：2013-03-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Pradeep P. Shirodkar , Jianya Cheng , Peijun Jiang
CPC classification number: C08L23/06 , B32B5/00 , C08F210/14 , C08F210/16 , C08F210/18 , C08J5/18 , C08J2323/08 , C08L23/08 , C08L23/0815 , C08L2203/16 , C08L2205/025 , C08L2207/07 , C08F236/20 , C08F2500/09 , C08F2500/12 , C08F2500/17 , C08F2500/19
Abstract: The present invention relates to a blown film comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g′vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g′vis of 0.90 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 3.0 or more; d) an Mz/Mn of 7.0 or more; e) optionally, an Mz of 2,000,000 g/mol or less; and f) a shear thinning ratio of 40 or more.
Abstract translation: 本发明涉及包含大于25重量％（基于组合物重量）的一种或多种g'vis为0.97以上且Mw为20,000g / mol以上的线性乙烯聚合物的吹塑薄膜，以及 至少0.1重量％的支化改性剂，其中改性剂具有a）g'vis为0.90以下; b）Mw为100,000g / mol以上; c）Mw / Mn为3.0以上; d）Mz / Mn为7.0以上; e）任选地，200,000g / mol或更少的Mz; f）剪切稀化比为40以上。
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