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公开(公告)号:US20170001930A1
公开(公告)日:2017-01-05
申请号:US15038983
申请日:2014-11-14
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor: Jason D. Davis , Ashley J. Poucher , Jörg F.W. Weber , Jonathan J. Watts , Christopher L. Becker
IPC: C07C13/28
CPC classification number: C07C13/28 , C07C2/74 , C07C7/04 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2601/14 , C07C409/14 , C07C39/04 , C07C49/403
Abstract: Disclosed is (i) a process of making phenol and/or cyclohexanone from cyclohexylbenzene including a step of removing methylcyclopentylbenzene from (a) the cyclohexylbenzene feed supplied to the oxidation step and/or (b) the crude phenol product (ii) a phenol composition and (iii) a cyclohexylbenzene composition that can be made using the process.
Abstract translation: 公开了(i)从环己基苯制备苯酚和/或环己酮的方法,包括从(a)供应到氧化步骤的环己基苯进料和/或(b)粗苯酚产物(ii)中除去甲基环戊基苯的步骤,苯酚组合物 和(iii)可以使用该方法制备的环己基苯组合物。
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公开(公告)号:US10053408B2
公开(公告)日:2018-08-21
申请号:US15504217
申请日:2015-08-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Keith H. Kuechler , Jörg F. W. Weber , Ashley J. Poucher , Jason D. Davis , Christopher L. Becker , Jihad M. Dakka
CPC classification number: C07C45/006 , C07C7/005 , C07C7/04 , C07C7/12 , C07C37/74 , C07C37/82 , C07C45/79 , C07C45/82 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04 , C07C13/28
Abstract: Disclosed are processes for making cyclohexanone from a mixture comprising phenol, cyclohexanone, cyclohexylbenzene, and an S-containing component, comprising a step of removing at least a portion of the S-containing component to reduce poisoning of a hydrogenation catalyst used for hydrogenating phenol to cyclohexanone.
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公开(公告)号:US20180065903A1
公开(公告)日:2018-03-08
申请号:US15551839
申请日:2016-01-15
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Keith H. Kuechler , Jörg F.W. Weber , Ashley J. Poucher , Jason D. Davis
CPC classification number: C07C7/08 , C07C7/04 , C07C7/12 , C07C37/80 , C07C37/82 , C07C39/04 , C07C45/79 , C07C45/82 , C07C45/83 , C07C49/403 , C07C2601/14 , C07C13/28
Abstract: In a process for separating a mixture comprising cyclohexanone and phenol, a solid-phase basic material, such as basic ion-exchange resin, is used to remove acid and/or sulfur from the mixture prior to separation. The process results in reduced amount of contamination such as cyclic ethers in the cyclohexanone and/or phenol products.
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公开(公告)号:US20180186715A1
公开(公告)日:2018-07-05
申请号:US15741030
申请日:2016-06-16
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Ashley J. Poucher , Jorg F.W. Weber , Medrado M. Leal
IPC: C07C49/543
CPC classification number: C07C49/543 , C07C45/006 , C07C45/53 , C07C45/82 , C07C2601/14 , C07C49/403
Abstract: Disclosed are novel cyclohexanone compositions, and processes for making such cyclohexanone compositions, from a mixture comprising phenol, cyclohexanone, and cyclohexylbenzene. Such cyclohexanone compositions comprise at least 99 wt % cyclohexanone, at most 0.15 wt % water, and at most 500 wppm combined of certain cyclohexanone impurities selected from the group consisting of: benzene, cyclohexene, pentanal, cyclopentanol, cyclohexanol, and phenol.
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公开(公告)号:US20170275226A1
公开(公告)日:2017-09-28
申请号:US15504217
申请日:2015-08-03
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Keith H. Kuechler , Jörg F.W. Weber , Ashley J. Poucher , Jason D. Davis , Christopher L. Becker , Jihad M. Dakka
CPC classification number: C07C45/006 , C07C7/005 , C07C7/04 , C07C7/12 , C07C37/74 , C07C37/82 , C07C45/79 , C07C45/82 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04 , C07C13/28
Abstract: Disclosed are processes for making cyclohexanone from a mixture comprising phenol, cyclohexanone, cyclohexylbenzene, and an S-containing component, comprising a step of removing at least a portion of the S-containing component to reduce poisoning of a hydrogenation catalyst used for hydrogenating phenol to cyclohexanone.
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公开(公告)号:US20170057895A1
公开(公告)日:2017-03-02
申请号:US15038988
申请日:2014-11-20
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jason D. Davis , Ashley J. Poucher , Jörg F.W. Weber , Jonathan J. Watts , Christopher L. Becker
IPC: C07C37/08 , C09K3/00 , C07C407/00
CPC classification number: C07C37/08 , C07C2/74 , C07C37/80 , C07C39/04 , C07C45/53 , C07C407/00 , C07C2601/14 , C09K3/00 , C07C49/403 , C07C13/28 , C07C409/14
Abstract: Disclosed is (i) a process of making phenol and/or cyclohexanone from cyclohexylbenzene including a step of removing methylcyclopentylbenzene from (a) the cyclohexylbenzene feed supplied to the oxidation step and/or (b) the crude phenol product (ii) a phenol composition and (iii) a cyclohexylbenzene composition that can be made using the process.
Abstract translation: 公开了(i)从环己基苯制备苯酚和/或环己酮的方法,包括从(a)供应到氧化步骤的环己基苯进料和/或(b)粗苯酚产物(ii)中除去甲基环戊基苯的步骤,苯酚组合物 和(iii)可以使用该方法制备的环己基苯组合物。
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公开(公告)号:US20200123089A1
公开(公告)日:2020-04-23
申请号:US16621123
申请日:2018-04-24
Applicant: ExxonMobil Chemical Patents inc.
Inventor: Kendele S. Galvan , Christopher L. Becker , Jörg F.W. Weber , Ashley J. Poucher
Abstract: Disclosed are processes for making cyclohexanone from a feed mixture comprising cyclohexylbenzene, cyclohexanone, phenol, 3-cylclohexenone and optionally 2-cyclohexenone, comprising feeding the feed mixture to a first distillation column and hydrogenating a fraction from the first distillation column in a hydrogenation reactor separate from the first distillation in the presence of a hydrogenation catalyst under hydrogenation conditions. A cyclohexanone-rich upper effluent comprising 3-cyclohexenone and 2-cyclohexenone at low concentrations can be obtained from the first distillation column.
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公开(公告)号:US10294178B2
公开(公告)日:2019-05-21
申请号:US15551839
申请日:2016-01-15
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Keith H. Kuechler , Jörg F. W. Weber , Ashley J. Poucher , Jason D. Davis
IPC: C07C7/08 , C07C7/04 , C07C7/12 , C07C37/80 , C07C37/82 , C07C39/04 , C07C45/79 , C07C45/82 , C07C45/83 , C07C49/403
Abstract: In a process for separating a mixture comprising cyclohexanone and phenol, a solid-phase basic material, such as basic ion-exchange resin, is used to remove acid and/or sulfur from the mixture prior to separation. The process results in reduced amount of contamination such as cyclic ethers in the cyclohexanone and/or phenol products.
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公开(公告)号:US10259759B2
公开(公告)日:2019-04-16
申请号:US15038983
申请日:2014-11-14
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jason D. Davis , Ashley J. Poucher , Jörg F. W. Weber , Jonathan J. Watts , Christopher L. Becker
Abstract: Disclosed is (i) a process of making phenol and/or cyclohexanone from cyclohexylbenzene including a step of removing methylcyclopentylbenzene from (a) the cyclohexylbenzene feed supplied to the oxidation step and/or (b) the crude phenol product (ii) a phenol composition and (iii) a cyclohexylbenzene composition that can be made using the process.
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公开(公告)号:US09908829B2
公开(公告)日:2018-03-06
申请号:US15038975
申请日:2014-11-14
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jason D. Davis , Ashley J. Poucher , Jörg F. W. Weber , Jonathan J. Watts , Christopher L. Becker
IPC: C07C45/53 , C07C37/08 , C07C407/00 , C07C2/74 , C07C37/80
CPC classification number: C07C37/08 , C07C2/74 , C07C37/80 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C2601/16 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
Abstract: Disclosed is (i) a process of making phenol and/or cyclohexanone from cyclohexylbenzene including a step of removing methylcyclopentylbenzene from (a) the cyclohexylbenzene feed supplied to the oxidation step and/or (b) the crude phenol product (ii) a phenol composition and (iii) a cyclohexylbenzene composition that can be made using the process.
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