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    Farnesene-based macromonomers and methods of making and using the same
    2.
    发明授权
    Farnesene-based macromonomers and methods of making and using the same 有权

    公开(公告)号：US11117988B2

    公开(公告)日：2021-09-14

    申请号：US16719179

    申请日：2019-12-18

    Applicant: Fina Technology, Inc.

    Inventor： Steven K Henning ,  Taejun Yoo ,  Herbert S Chao

    IPC: C08F36/22 ,  C08C19/38 ,  C08F220/18 ,  C08C19/44 ,  C08F136/22 ,  A61K8/81 ,  A61Q19/00 ,  C08F20/18 ,  C09J133/10 ,  C09J147/00 ,  C10M145/14 ,  C10N40/08

    Abstract: A macromonomer precursor is provided that includes a polymeric chain derived from farnesene and a single functional terminal end. The functional terminal end may include a hydroxyl group, an amino group, an epoxy group, an isocyanato group, or a carboxylic acid group. The terminal end of the macromonomer precursor may then be reacted with a (meth)acrylate to form a macromonomer having a (meth)acrylate functionalized terminal end that may be (co)polymerized with radically polymerizable monomers, such as alkyl(meth)acrylate monomers. Alternatively, a copolymer may be obtained by first deriving a poly(meth)acrylate from (meth)acrylate monomers having reactive groups that would allow the macromonomer precursors to be grafted onto the poly(meth)acrylate in a second step. The resulting copolymer may be incorporated as an additive in various formulations, such as a lubricant, a hydraulic fluid, a cosmetic composition, and an adhesive composition.

    Farnesene-based macromonomers and methods of making and using the same
    3.
    发明授权
    Farnesene-based macromonomers and methods of making and using the same 有权

    公开(公告)号：US10544241B2

    公开(公告)日：2020-01-28

    申请号：US15266330

    申请日：2016-09-15

    Applicant: Fina Technology, Inc.

    Inventor： Steven K. Henning ,  Taejun Yoo ,  Herbert S. Chao

    IPC: C08F36/22 ,  A61K8/81 ,  A61Q19/00 ,  C08F20/18 ,  C09J133/10 ,  C09J147/00 ,  C10M145/14 ,  C10N40/08

    Abstract: A macromonomer precursor is provided that includes a polymeric chain derived from farnesene and a single functional terminal end. The functional terminal end may include a hydroxyl group, an amino group, an epoxy group, an isocyanato group, or a carboxylic acid group. The terminal end of the macromonomer precursor may then be reacted with a (meth)acrylate to form a macromonomer having a (meth)acrylate functionalized terminal end that may be (co)polymerized with radically polymerizable monomers, such as alkyl(meth)acrylate monomers. Alternatively, a copolymer may be obtained by first deriving a poly(meth)acrylate from (meth)acrylate monomers having reactive groups that would allow the macromonomer precursors to be grafted onto the poly(meth)acrylate in a second step. The resulting copolymer may be incorporated as an additive in various formulations, such as a lubricant, a hydraulic fluid, a cosmetic composition, and an adhesive composition.

    Epoxidized polyfarnesene and methods for producing the same
    5.
    发明授权
    Epoxidized polyfarnesene and methods for producing the same 有权

    公开(公告)号：US10745503B2

    公开(公告)日：2020-08-18

    申请号：US16104384

    申请日：2018-08-17

    Applicant: FINA TECHNOLOGY, INC.

    Inventor： Herbert Chao ,  Taejun Yoo ,  Sabrina Nehache

    IPC: C08L63/08 ,  C08L63/00 ,  C08G59/34 ,  C08G59/20 ,  C08F236/22 ,  C08F36/22 ,  C08F136/22 ,  C08C19/02 ,  C08G59/02 ,  C08C19/06

    Abstract: Aspects of the present invention relate to polymers, and particularly to farnesene polymers functionalized with one or more oxirane groups and, optionally, one or more hydroxyl groups. According to one aspect of the invention, provided is an epoxidized and optionally hydroxyl-functionalized polyfarnesene. The epoxidized farnesene polymer has at least one of a side chain or a main backbone functionalized with at least one oxirane group and, optionally, at least one terminal end functionalized with a hydroxyl group. In accordance with another aspect of the invention, a method is provided for preparing an epoxidized and optionally hydroxyl-functionalized polyfarnesene. The method includes epoxidizing a farnesene polymer, which may optionally contain one or more terminal hydroxyl groups, to functionalize at least one of a side chain or a main backbone of the farnesene polymer with an oxirane group.

    FARNESENE-BASED MACROMONOMERS AND METHODS OF MAKING AND USING THE SAME
    8.
    发明申请
    FARNESENE-BASED MACROMONOMERS AND METHODS OF MAKING AND USING THE SAME 审中-公开

    公开(公告)号：US20180072826A1

    公开(公告)日：2018-03-15

    申请号：US15266330

    申请日：2016-09-15

    Applicant: Fina Technology, Inc.

    Inventor： Steven K. Henning ,  Taejun Yoo ,  Herbert S. Chao

    IPC: C08F36/22 ,  C08F20/18 ,  A61K8/81 ,  A61Q19/00 ,  C09J147/00 ,  C09J133/10 ,  C10M145/14

    Abstract: A macromonomer precursor is provided that includes a polymeric chain derived from farnesene and a single functional terminal end. The functional terminal end may include a hydroxyl group, an amino group, an epoxy group, an isocyanato group, or a carboxylic acid group. The terminal end of the macromonomer precursor may then be reacted with a (meth)acrylate to form a macromonomer having a (meth)acrylate functionalized terminal end that may be (co)polymerized with radically polymerizable monomers, such as alkyl(meth)acrylate monomers. Alternatively, a copolymer may be obtained by first deriving a poly(meth)acrylate from (meth)acrylate monomers having reactive groups that would allow the macromonomer precursors to be grafted onto the poly(meth)acrylate in a second step. The resulting copolymer may be incorporated as an additive in various formulations, such as a lubricant, a hydraulic fluid, a cosmetic composition, and an adhesive composition.

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