Abstract:
Provided is a method for manufacturing a nitrogen-containing carbon alloy having a sufficiently high oxygen reduction reaction activity, a nitrogen-containing carbon alloy, and a fuel cell catalyst. The method for manufacturing a nitrogen-containing carbon alloy comprises sintering a precursor which contains a nitrogen-containing compound and an inorganic metal salt, the nitrogen-containing compound having at least one heteroaromatic ring and a conjugated heterocycle, and the conjugated heterocycle having 12 or larger number of ring-forming atoms.
Abstract:
A problem to be solved by the invention is to provide a production method of a nitrogen-containing carbon alloy that has sufficiently high redox activity or has a large number of reaction electrons of redox reaction. A method for producing a nitrogen-containing carbon alloy comprising baking a precursor containing a nitrogen-containing organic compound and an inorganic metal salt containing one or more kinds of Fe, Co, Ni, Mn and Cr, wherein: the precursor satisfies one of the requirements (a) and (b) below, and, the nitrogen-containing organic compound is one of a compound represented by the formula (1) below, a tautomer of the compound, and a salt and hydrate thereof: (a) the precursor contains the inorganic metal salt in an amount exceeding 45% by mass based on the total amount of the nitrogen-containing organic compound and the inorganic metal salt of the precursor, in which the total amount includes the mass of hydrated water in the nitrogen-containing organic compound and the inorganic metal salt, and the amount of the inorganic metal salt includes the mass of hydrated water in the inorganic metal, (b) the precursor further contains a β-diketone metal complex:
Abstract:
A non-aqueous liquid electrolyte for a secondary battery, the non-aqueous liquid electrolyte containing an electrolyte, an organic typical metal compound and an organic solvent, the organic solvent containing the electrolyte and the organic typical metal compound, the organic typical metal compound being contained in the organic solvent in an amount of 1 mol/L or less.
Abstract:
A non-aqueous secondary battery containing: a positive electrode containing a transition metal oxide as an active material thereof; a negative electrode; and a non-aqueous liquid electrolyte containing an electrolyte, an organic solvent, and less than 0.1 mol/L of an organometallic compound containing a transition element or a rare-earth element as a central metal thereof.
Abstract:
A non-aqueous liquid electrolyte for a secondary battery, containing: at least one selected from a carbonate compound having a halogen atom and a sulfur-containing ring compound; an aromatic ketone compound; an organic solvent; and an electrolyte salt, in which, with respect to 100 parts by mass of the organic solvent, the aromatic ketone compound is 0.001 to 10 parts by mass and the at least one selected from a carbonate compound having a halogen atom and a sulfur-containing ring compound is 0.001 to 10 parts by mass, and more than 50% by mass of the whole amount of the organic solvent is composed of a solvent with a melting point of 10° C. or less.
Abstract:
Provided are a non-aqueous electrolyte liquid for a secondary battery, which has excellent lithium ion conductibility and voltage resistance and is suitably used in a lithium secondary battery, and a high output power lithium secondary battery containing this non-aqueous electrolyte liquid for a secondary battery. Disclosed is a non-aqueous electrolyte liquid for a secondary battery containing a metal salt containing an ion of a metal which belongs to Group 1 or Group 2 of the Periodic Table of Elements, and at least one selected from the group consisting of silicon compounds represented by the following formula (1) or formula (2).