公开(公告)号：US20090018244A1

公开(公告)日：2009-01-15

申请号：US12095798

申请日：2006-12-04

申请人： Fabio Polastri ,  Tiziana Poggio ,  Julio A. Abusleme

发明人： Fabio Polastri ,  Tiziana Poggio ,  Julio A. Abusleme

IPC分类号： C08K5/06 ,  C08K5/10 ,  C08K5/05

CPC分类号： C09D127/12 ,  C08K5/04 ,  C08K5/05 ,  C08K5/053 ,  C08K5/06 ,  C09D127/16 ,  C09D127/18 ,  Y10T428/3154 ,  C08L27/12

摘要： A fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer [polymer (F)]; water; less than 15% wt (based on total weight of composition) of a water-soluble solvent mixture [mixture (M)] comprising: at least one alcohol solvent [solvent (A)]; at least one glycol derivative solvent having a boiling point of at least 100° C. [solvent (GD)], wherein the solvent (GD) is a derivative of a compound comprising at least two hydroxyl groups, wherein at least one of the hydroxyl group has been derivatized to yield an ether or an ester bond. Another object of the present invention is a process for manufacturing said composition. Still another object of the invention is the use of the composition of the invention for coating. Still another object of the invention is a coated article, obtained using the composition of the invention.

摘要翻译： 含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物[聚合物（F）]; 水; 包含：至少一种醇溶剂[溶剂（A）];小于15重量％（基于组合物的总重量）的水溶性溶剂混合物[混合物（M） 至少一种沸点为至少100℃的二醇衍生物溶剂[溶剂（GD）]，其中溶剂（GD）是包含至少两个羟基的化合物的衍生物，其中至少一个羟基 已经衍生化得到醚或酯键。 本发明的另一个目的是制备所述组合物的方法。 本发明的另一个目的是使用本发明的组合物进行涂覆。 本发明的另一个目的是使用本发明的组合物获得的涂层制品。

公开(公告)号：US07985790B2

公开(公告)日：2011-07-26

申请号：US12095798

申请日：2006-12-04

申请人： Fabio Polastri ,  Tiziana Poggio ,  Julio A. Abusleme

发明人： Fabio Polastri ,  Tiziana Poggio ,  Julio A. Abusleme

IPC分类号： C08K5/05

CPC分类号： C09D127/12 ,  C08K5/04 ,  C08K5/05 ,  C08K5/053 ,  C08K5/06 ,  C09D127/16 ,  C09D127/18 ,  Y10T428/3154 ,  C08L27/12

摘要： A fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer [polymer (F)]; water; less than 15% wt (based on total weight of composition) of a water-soluble solvent mixture [mixture (M)] comprising: at least one alcohol solvent [solvent (A)]; at least one glycol derivative solvent having a boiling point of at least 100° C. [solvent (GD)], wherein the solvent (GD) is a derivative of a compound comprising at least two hydroxyl groups, wherein at least one of the hydroxyl group has been derivatized to yield an ether or an ester bond.

摘要翻译： 含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物[聚合物（F）]; 水; 包含：至少一种醇溶剂[溶剂（A）];小于15重量％（基于组合物的总重量）的水溶性溶剂混合物[混合物（M） 至少一种沸点为至少100℃的二醇衍生物溶剂[溶剂（GD）]，其中溶剂（GD）是包含至少两个羟基的化合物的衍生物，其中至少一个羟基 已经衍生化得到醚或酯键。

公开(公告)号：US20050209395A1

公开(公告)日：2005-09-22

申请号：US11121079

申请日：2005-05-04

申请人： Fabio Polastri ,  Tiziana Poggio

发明人： Fabio Polastri ,  Tiziana Poggio

IPC分类号： C08J5/18 ,  C08K3/04 ,  C08K3/30 ,  C08L27/18 ,  C08L71/02 ,  C09D127/18 ,  C08K3/00

CPC分类号： C08J5/18 ,  C08J2327/18 ,  C08K3/04 ,  C08K3/30 ,  C08L27/18 ,  C08L71/02 ,  C09D127/18 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31678 ,  Y10T428/31855 ,  Y10T428/31891 ,  C08L2666/22

摘要： Compositions based on PTFE, homopolymer or modified, comprising for 100 parts of the component 1) PTFE: 1) an aqueous nanodispersion of said homopolymer or modified PTFE, having a primary particle diameter from 5 to 100 nm; 2) from 3 to 45 parts by weight of a surfactant or surfactant mixtures; 3) from 0.2 to 20 parts by weight of an organic or inorganic sequestrant, and optionally: 4) from 0 to 60 parts by weight of a solid lubricating compound.

摘要翻译： 基于PTFE，均聚物或改性的组合物，包含100份组分1）PTFE：1）所述均聚物或改性PTFE的水性纳米分散体，其一次粒径为5至100nm; 2）3至45重量份的表面活性剂或表面活性剂混合物; 3）0.2至20重量份的有机或无机螯合剂，以及任选地：4）0至60重量份的固体润滑化合物。

公开(公告)号：US06924036B2

公开(公告)日：2005-08-02

申请号：US10372077

申请日：2003-02-25

申请人： Fabio Polastri ,  Tiziana Poggio

发明人： Fabio Polastri ,  Tiziana Poggio

IPC分类号： C08J5/18 ,  C08K3/04 ,  C08K3/30 ,  C08L27/18 ,  C08L71/02 ,  C09D127/18 ,  B05D1/02 ,  B05D3/02 ,  B32B15/08 ,  B32B27/16

CPC分类号： C08J5/18 ,  C08J2327/18 ,  C08K3/04 ,  C08K3/30 ,  C08L27/18 ,  C08L71/02 ,  C09D127/18 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31678 ,  Y10T428/31855 ,  Y10T428/31891 ,  C08L2666/22

摘要： Compositions based on PTFE, homopolymer or modified, comprising for 100 parts of the component 1) PTFE: 1) an aqueous nanodispersion of said homopolymer or modified PTFE, having a primary particle diameter from 5 to 100 nm; 2) from 3 to 45 parts by weight of a surfactant or surfactant mixtures; 3) from 0.2 to 20 parts by weight of an organic or inorganic sequestrant, and optionally: 4) from 0 to 60 parts by weight of a solid lubricating compound.

公开(公告)号：US20110040039A1

公开(公告)日：2011-02-17

申请号：US11739145

申请日：2007-04-24

申请人： Giovanna Palamone ,  Tiziana Poggio ,  Valeri Kapeliouchko ,  Michele Laus

发明人： Giovanna Palamone ,  Tiziana Poggio ,  Valeri Kapeliouchko ,  Michele Laus

IPC分类号： C08L27/18 ,  B32B5/00 ,  B82Y99/00

CPC分类号： C08F259/08 ,  Y10T428/2998 ,  C08F220/10

摘要： Core-shell particles having a core of at least one tetrafluoroethylene (TFE) polymer and having an average primary particle size of less than 50 nm; and a shell of at least one acrylic polymer having recurring units, more than 50% by moles of which being derived from at least one ethylenically unsaturated monomer having directly bonded to one of the sp2 carbon atoms of the ethylenic unsaturation at least one group of formula: Process for manufacturing core-shell particles. Use as ingredients/additives in polymer compositions, polymer composition and articles containing the same.

摘要翻译： 具有至少一种四氟乙烯（TFE）聚合物的芯并且具有小于50nm的平均一次粒径的核 - 壳颗粒; 和具有重复单元的至少一种丙烯酸类聚合物的壳，大于50摩尔％的至少一种烯键式不饱和单体，其至少一种烯属不饱和单体直接键合到烯属不饱和键的一个sp2碳原子上，至少一个式 制造核 - 壳粒子的方法。 用作聚合物组合物中的成分/添加剂，聚合物组合物和含有它们的物品。

公开(公告)号：US07294276B2

公开(公告)日：2007-11-13

申请号：US11319802

申请日：2005-12-29

申请人： Marco Malvasi ,  Tiziana Poggio ,  Valeri Kapeliouchko

发明人： Marco Malvasi ,  Tiziana Poggio ,  Valeri Kapeliouchko

IPC分类号： C02P1/42 ,  C08L27/12

CPC分类号： C08F6/16 ,  C08J3/03 ,  C08J2327/12 ,  Y10S210/915 ,  C08L27/12

摘要： A process to substantially remove the fluorinated anionic surfactants from fluoropolymer dispersions comprising the following steps: a) addition to the fluoropolymer dispersion of an anionic polyelectrolyte; b) contact of the dispersion with an anionic exchanger; c) separation of the dispersion from the anionic exchanger and recovery of the dispersion substantially fluorinated anionic surfactant free.

摘要翻译： 从含氟聚合物分散体中大量除去氟化阴离子表面活性剂的方法，包括以下步骤：a）加入阴离子聚电解质的氟聚合物分散体; b）分散体与阴离子交换剂的接触; c）从阴离子交换剂分离分散体并回收分散体基本氟化的阴离子表面活性剂。

公开(公告)号：US06197866B1

公开(公告)日：2001-03-06

申请号：US09318656

申请日：1999-05-25

申请人： Daria Lenti ,  Tiziana Poggio

发明人： Daria Lenti ,  Tiziana Poggio

IPC分类号： C08J300

CPC分类号： C09D127/12 ,  C08L71/02 ,  C09D127/16 ,  C08L2666/14

摘要： Painting composition based on fluoropolymers in an aqueous dispersion, comprising a partially fluorinated non ionic polymeric compound as an additive for the control of the viscosity and in general of the rheological characteristics of the composition itself.

摘要翻译： 基于含氟聚合物的水性分散体中的涂料组合物，其包含部分氟化的非离子聚合化合物作为用于控制粘度的添加剂和通常由组合物本身的流变特性。

公开(公告)号：US20050070659A1

公开(公告)日：2005-03-31

申请号：US10902007

申请日：2004-07-30

申请人： Lin Shiow-Ling ,  David Gibala ,  Anthony Lippl ,  Geoffrey Underwood ,  Tiziana Poggio

发明人： Lin Shiow-Ling ,  David Gibala ,  Anthony Lippl ,  Geoffrey Underwood ,  Tiziana Poggio

IPC分类号： C08K3/00

CPC分类号： C08L27/12 ,  C08L27/18 ,  C08L79/04 ,  C09D127/12 ,  C09D127/18 ,  Y10T428/3154 ,  C08L2666/20

摘要： The present invention relates to a water-based polymer composition, comprising: at least one polymer (P) comprising recurring units (R1), from 0 to at most 25% mol of said recurring units (R1) comprising a carboxylic acid group (in acid or salt form); at least one aromatic polyamic acid (A) comprising recurring units, more than 50% mol of said recurring units comprising at least one aromatic ring and at least one amic acid group and/or imide group [recurring units (R2)], more than 50% mol of recurring units (R2) comprising at least one amic acid group, part or all of the amic acid groups being neutralized by at least one basic compound (B); water; optionally, at least one organic solvent (S) of the aromatic polyamic acid (A), in an amount of less than 20% wt with respect to the weight of the aromatic polyamic acid. The polymer (P) is preferably a fluoropolymer; it can be either a partially fluorinated fluoropolymer, such as ECTFE, or a perfluorinated fluoropolymer such as TFE polymers. The water-based polymer compositions of this invention may be notably found useful for coating applications where organic solvents may not be desired or tolerated.

摘要翻译： 本发明涉及水基聚合物组合物，其包含：至少一种包含重复单元（R1）的至少一种聚合物（P），0至至多25摩尔％的包含羧酸基团的重复单元（R1）（在 酸或盐形式）; 至少一种包含重复单元的芳族聚酰胺酸（A），超过50％摩尔的所述重复单元包含至少一个芳族环和至少一个酰胺基和/或酰亚胺基[重复单元（R 2）]，多于 50％摩尔的包含至少一种酰胺酸基团的重复单元（R2），部分或全部酰胺酸基团被至少一种碱性化合物（B）中和; 水; 任选地，芳族聚酰胺酸（A）的至少一种有机溶剂（S）的用量相对于芳族聚酰胺酸的重量小于20％wt。 聚合物（P）优选为含氟聚合物; 它可以是部分氟化的氟聚合物，例如ECTFE，或全氟化含氟聚合物如TFE聚合物。 本发明的水基聚合物组合物可以显着地用于可能不期望或耐受有机溶剂的涂布应用。

公开(公告)号：US06696512B2

公开(公告)日：2004-02-24

申请号：US10046883

申请日：2002-01-17

申请人： Tiziana Poggio ,  Enrico Marchese

发明人： Tiziana Poggio ,  Enrico Marchese

IPC分类号： C08K506

CPC分类号： C09D127/12 ,  C08L27/12 ,  C08L27/18 ,  C08L71/02 ,  C09D127/18 ,  Y10T428/3154 ,  C08L2666/14

摘要： Aqueous dispersions of fluoropolymers containing as stabilizer from 1 to 30% by weight with respect to the fluoropolymer, of a non ionic surfactant having the following structure: CH3(CH2)nO(C3H6O)p(CH2CH2O)mH   (I) wherein: n is in the range 8-20, preferably 12-15; m is in the range 5-20, preferably 7-12; p is in the range 1-8, preferably it is 1 or 2.

摘要翻译： 含氟聚合物的水分散体含有相对于含氟聚合物为1至30重量％的非离子表面活性剂，其具有以下结构：其中：n在8-20，优选12-15的范围内; m在 范围5-20，优选7-12; p在1-8范围内，优选为1或2。

公开(公告)号：US08063135B2

公开(公告)日：2011-11-22

申请号：US10902007

申请日：2004-07-30

申请人： Lin Shiow-Ling ,  David Gibala ,  Anthony Lippl ,  Geoffrey Scott Underwood ,  Tiziana Poggio

发明人： Lin Shiow-Ling ,  David Gibala ,  Anthony Lippl ,  Geoffrey Scott Underwood ,  Tiziana Poggio

IPC分类号： C08L79/08 ,  B32B27/28

CPC分类号： C08L27/12 ,  C08L27/18 ,  C08L79/04 ,  C09D127/12 ,  C09D127/18 ,  Y10T428/3154 ,  C08L2666/20

摘要： The present invention relates to a water-based polymer composition, comprising: at least one polymer (P) comprising recurring units (R1), from 0 to at most 25% mol of said recurring units (R1) comprising a carboxylic acid group (in acid or salt form); at least one aromatic polyamic acid (A) comprising recurring units, more than 50% mol of said recurring units comprising at least one aromatic ring and at least one amic acid group and/or imide group [recurring units (R2)], more than 50% mol of recurring units (R2) comprising at least one amic acid group, part or all of the amic acid groups being neutralized by at least one basic compound (B); water; optionally, at least one organic solvent (S) of the aromatic polyamic acid (A), in an amount of less than 20% wt with respect to the weight of the aromatic polyamic acid. The polymer (P) is preferably a fluoropolymer; it can be either a partially fluorinated fluoropolymer, such as ECTFE, or a perfluorinated fluoropolymer such as TFE polymers.The water-based polymer compositions of this invention may be notably found useful for coating applications where organic solvents may not be desired or tolerated.

摘要翻译： 本发明涉及一种水基聚合物组合物，其包含：至少一种包含重复单元（R1）的至少一种聚合物（P），0至至多25摩尔％的包含羧酸基团的重复单元（R1）（在 酸或盐形式）; 至少一种包含重复单元的芳族聚酰胺酸（A），超过50％摩尔的所述重复单元包含至少一个芳族环和至少一个酰胺基和/或酰亚胺基[重复单元（R 2）]，多于 50％摩尔的包含至少一种酰胺酸基团的重复单元（R2），部分或全部酰胺酸基团被至少一种碱性化合物（B）中和; 水; 任选地，芳族聚酰胺酸（A）的至少一种有机溶剂（S）的用量相对于芳族聚酰胺酸的重量小于20％wt。 聚合物（P）优选为含氟聚合物; 它可以是部分氟化的氟聚合物，例如ECTFE，或全氟化含氟聚合物如TFE聚合物。 本发明的水基聚合物组合物可以显着地用于可能不期望或耐受有机溶剂的涂布应用。