公开(公告)号：US07563427B2

公开(公告)日：2009-07-21

申请号：US10478512

申请日：2002-01-29

申请人： Fei Wei ,  Yao Wang ,  Guohua Luo ,  Hao Yu ,  Zhifei Li ,  Weizhong Qian ,  Zhanwen Wang ,  Yong Jin

发明人： Fei Wei ,  Yao Wang ,  Guohua Luo ,  Hao Yu ,  Zhifei Li ,  Weizhong Qian ,  Zhanwen Wang ,  Yong Jin

IPC分类号： D01F9/12

CPC分类号： B82Y30/00 ,  B01J8/0055 ,  B01J8/1836 ,  B01J21/04 ,  B01J21/08 ,  B01J21/185 ,  B01J23/70 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/8892 ,  B01J2208/00132 ,  B82Y40/00 ,  C01B3/26 ,  C01B32/162 ,  C01B32/164 ,  Y10S977/843

摘要： The present invention relates to a method for continuous production of carbon nanotubes in a nano-agglomerate fluidized bed, which comprises the following steps: loading transition metal compounds on a support, obtaining supported nanosized metal catalysts by reducing or dissociating, catalytically decomposing a carbon-source gas, and growing carbon nanotubes on the catalyst support by chemical vapor deposition of carbon atoms. The carbon nanotubes are 4˜100 nm in diameter and 0.5˜1000 μm in length. The carbon nanotube agglomerates, ranged between 1˜1000 μm, are smoothly fluidized under 0.005 to 2 m/s superficial gas velocity and 20˜800 kg/m3 bed density in the fluidized-bed reactor. The apparatus is simple and easy to operate, has a high reaction rate, and it can be used to produce carbon nanotubes with high degree of crystallization, high purity, and high yield.

摘要翻译： 本发明涉及一种在纳米聚集体流化床中连续生产碳纳米管的方法，包括以下步骤：将载体上的过渡金属化合物加载到载体上，通过还原或解离催化分解碳 - 源气体和通过碳原子的化学气相沉积在催化剂载体上生长碳纳米管。 碳纳米管的直径为4〜100nm，长度为0.5〜1000μm。 流化床反应器中碳纳米管凝聚体的范围在1〜1000μm之间，在0.005〜2m / s表观气体速度和20〜800kg / m3床密度下平稳流动。 该装置简单易操作，反应速度快，可用于生产高结晶度，高纯度，高产率的碳纳米管。

公开(公告)号：US20090286675A1

公开(公告)日：2009-11-19

申请号：US12400713

申请日：2009-03-09

申请人： Fei Wei ,  Yao Wang ,  Guohua Luo ,  Hao Yu ,  Zhifei Li ,  Weizhong Qian ,  Zhanwen Wang ,  Yong Jin

发明人： Fei Wei ,  Yao Wang ,  Guohua Luo ,  Hao Yu ,  Zhifei Li ,  Weizhong Qian ,  Zhanwen Wang ,  Yong Jin

IPC分类号： B01J21/18 ,  B82B1/00

CPC分类号： B01J8/0055 ,  B01J8/1836 ,  B01J21/04 ,  B01J21/08 ,  B01J21/185 ,  B01J23/70 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/8892 ,  B01J2208/00132 ,  B01J2219/00033 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B32/164 ,  C01B2202/06 ,  C01B2202/34 ,  C01B2202/36

摘要： The present invention relates to a method for continuous production of carbon nanotubes in a nano-agglomerate fluidized bed, which comprises the following steps: loading transition metal compounds on a support, obtaining supported nanosized metal catalysts by reducing or dissociating, catalytically decomposing a carbon-source gas, and growing carbon nanotubes on the catalyst support by chemical vapor deposition of carbon atoms. The carbon nanotubes are 4˜100 nm in diameter and 0.5˜1000 μm in length. The carbon nanotube agglomerates, ranged between 1˜1000 μm, are smoothly fluidized under 0.005 to 2 m/s superficial gas velocity and 20-800 kg/m3 bed density in the fluidized-bed reactor. The apparatus is simple and easy to operate, has a high reaction rate, and it can be used to produce carbon nanotubes with high degree of crystallization, high purity, and high yield.

摘要翻译： 本发明涉及一种在纳米聚集体流化床中连续生产碳纳米管的方法，包括以下步骤：将载体上的过渡金属化合物加载到载体上，通过还原或解离催化分解碳 - 源气体和通过碳原子的化学气相沉积在催化剂载体上生长碳纳米管。 碳纳米管的直径为4〜100nm，长度为0.5〜1000μm。 流化床反应器中的碳纳米管凝聚体，范围在1〜1000μm之间，在0.005〜2m / s表观气体流速和20〜800kg / m3床密度下平稳流化。 该装置简单易操作，反应速度快，可用于生产高结晶度，高纯度，高产率的碳纳米管。

公开(公告)号：US08470941B2

公开(公告)日：2013-06-25

申请号：US13127591

申请日：2008-12-02

申请人： Jianjun Yi ,  Baozuo Yin ,  Chunming Cui ,  Zhifei Li ,  Liang Cui ,  Huashu Li ,  Weihuan Huang ,  Jianying Zhang ,  Li Wang

发明人： Jianjun Yi ,  Baozuo Yin ,  Chunming Cui ,  Zhifei Li ,  Liang Cui ,  Huashu Li ,  Weihuan Huang ,  Jianying Zhang ,  Li Wang

IPC分类号： C08F4/44

CPC分类号： C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F4/6545 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/15 ,  C08F210/16 ,  C08F2500/12

摘要： A catalyst for homopolymerizing and copolymerizing propylene and its preparation and use. The catalyst component includes titanium compound containing at least one Ti-halogen bond and at least two kinds of electron donor compounds A and B supported on MgCl2.nROH adduct, wherein the electron donor compound A is a compound of formula (I), the electron donor compound B is ester or ether compound; the molar ratio between compound A and compound B is 0.1-5; the molar ratio between the total amounts of the two kinds of electron donors and MgCl2.nROH is 0.01-1, based on the amount of MgCl2.nROH; and the molar ration between the titanium compound containing Ti-halogen bond and MgCl2.nROH is 1-200. The catalyst has high activity, high stereospecificity and good copolymerization performance. In addition, the morphology of the polymer obtained therefrom is good.

摘要翻译： 丙烯均聚和共聚的催化剂及其制备和用途。 催化剂组分包括含有至少一个Ti-卤素键的钛化合物和负载在MgCl 2·nROH加合物上的至少两种电子给体化合物A和B，其中电子给体化合物A是式（I）化合物， 给体化合物B是酯或醚化合物; 化合物A与化合物B的摩尔比为0.1-5; 基于MgCl 2·nROH的量，两种电子给体和MgCl 2·nROH的总量之间的摩尔比为0.01-1。 含Ti-卤键的钛化合物与MgCl 2·nROH之间的摩尔比为1-200。 该催化剂具有高活性，高立体定向性和良好的共聚性能。 此外，由其获得的聚合物的形态是良好的。

公开(公告)号：US08541332B2

公开(公告)日：2013-09-24

申请号：US13813479

申请日：2011-06-03

申请人： Zhifei Li ,  Kuilong Tan ,  Hao Wang ,  Jianjun Yi ,  Qinghong Xu ,  Weisong Cui ,  Wei Bai ,  Xinyuan Liu ,  Pu Xu ,  Wanqing Ju

发明人： Zhifei Li ,  Kuilong Tan ,  Hao Wang ,  Jianjun Yi ,  Qinghong Xu ,  Weisong Cui ,  Wei Bai ,  Xinyuan Liu ,  Pu Xu ,  Wanqing Ju

IPC分类号： C08F4/02 ,  C08F4/44 ,  C08F2/00 ,  C08F4/00 ,  B01J27/02 ,  B01J21/00

CPC分类号： C08F110/00 ,  C08F110/06 ,  C08F4/6465 ,  C08F2500/12 ,  C08F2500/15

摘要： Disclosed is a catalyst for the polymerization of olefins comprising thienyl-substituted silanes, which comprises a solid titanium catalyst component containing titanium, magnesium and a halogen as the main components, an alkylaluminum compound, and a component of organosiloxane compound comprising two thienyl as substituents represented by general formula (I). The molar ratio of each catalyst component is 1:50-150:5-50 based on titanium:aluminum:silicon. When the catalyst is used in the polymerization of propylene, the polymerisate obtained has a very high degree of isotacticity, and the yield is high.

摘要翻译： 公开了包含噻吩基取代的硅烷的烯烃聚合催化剂，其包含含有钛，镁和卤素作为主要成分的固体钛催化剂组分，烷基铝化合物和包含两个噻吩基作为取代基的有机硅氧烷化合物的组分 由通式（I）表示。 每个催化剂组分的摩尔比基于钛：铝：硅为1:50-150:5-50。 当催化剂用于丙烯的聚合时，获得的聚合物具有非常高的全同立构规整度，产率高。

公开(公告)号：US20130072647A1

公开(公告)日：2013-03-21

申请号：US13702209

申请日：2011-06-03

申请人： Jianjun Yi ,  Chunming Cui ,  Huashu Li ,  Zhifei Li ,  Baozuo Yin ,  Liang Cui ,  Jianying Zhang ,  Liang Wang

发明人： Jianjun Yi ,  Chunming Cui ,  Huashu Li ,  Zhifei Li ,  Baozuo Yin ,  Liang Cui ,  Jianying Zhang ,  Liang Wang

IPC分类号： C08F4/16 ,  C08F10/06

CPC分类号： C08F4/16 ,  C08F10/06 ,  C08F110/06 ,  C08F4/6565 ,  C08F4/6465 ,  C08F2500/15

摘要： An olefin polymerization catalyst and preparation method and use thereof are provided. The components of the catalyst comprise an active magnesium halide, a titanium compound containing at least one Ti-halide bond loaded on the active magnesium halide, and an internal electron donor selected from one or more silicon esters compounds having formula (I). The method for preparing the catalyst components is that: adding spherical magnesium chloride alcoholate particles and the electron donor into the solution of titanium compound in sequence, and processing with the titanium compound for one or more times to obtain the catalyst. The catalyst system used for the olefin polymerization comprises the catalyst components, a cocatalyst and an external electron donor. The catalyst has high activity for the propylene polymerization, and the activity is 4399 gPP/gTi·h(50° C., 1 h, slurry polymerization at atmospheric pressure), and the isotacticity of the polymer is 98%.

摘要翻译： 提供烯烃聚合催化剂及其制备方法和用途。 催化剂的组分包括活性卤化镁，含有负载在活性卤化镁上的至少一种Ti-卤化物键的钛化合物和选自一种或多种具有式（I）的硅酯化合物的内部电子给体。 制备催化剂组分的方法是：将球形氯化镁醇盐颗粒和电子给体依次加入钛化合物溶液中，并用钛化合物处理一次或多次以获得催化剂。 用于烯烃聚合的催化剂体系包括催化剂组分，助催化剂和外部电子给体。 该催化剂对丙烯聚合具有高活性，活性为4399gPP / gTi·h（50℃，1小时，常压下淤浆聚合），聚合物的全同立构规整度为98％。

公开(公告)号：US08716417B2

公开(公告)日：2014-05-06

申请号：US13702209

申请日：2011-06-03

申请人： Jianjun Yi ,  Chunming Cui ,  Huashu Li ,  Zhifei Li ,  Baozuo Yin ,  Liang Cui ,  Jianying Zhang ,  Liang Wang

发明人： Jianjun Yi ,  Chunming Cui ,  Huashu Li ,  Zhifei Li ,  Baozuo Yin ,  Liang Cui ,  Jianying Zhang ,  Liang Wang

IPC分类号： C08F4/44 ,  B01J35/08 ,  B01J31/00

CPC分类号： C08F4/16 ,  C08F10/06 ,  C08F110/06 ,  C08F4/6565 ,  C08F4/6465 ,  C08F2500/15

摘要： An olefin polymerization catalyst and preparation method and use thereof are provided. The components of the catalyst comprise an active magnesium halide, a titanium compound containing at least one Ti-halide bond loaded on the active magnesium halide, and an internal electron donor selected from one or more silicon esters compounds having formula (I). The method for preparing the catalyst components is that: adding spherical magnesium chloride alcoholate particles and the electron donor into the solution of titanium compound in sequence, and processing with the titanium compound for one or more times to obtain the catalyst. The catalyst system used for the olefin polymerization comprises the catalyst components, a cocatalyst and an external electron donor. The catalyst has high activity for the propylene polymerization, and the activity is 4399 gPP/gTi·h(50° C., 1 h, slurry polymerization at atmospheric pressure), and the isotacticity of the polymer is 98%.

摘要翻译： 提供烯烃聚合催化剂及其制备方法和用途。 催化剂的组分包括活性卤化镁，含有负载在活性卤化镁上的至少一种Ti-卤化物键的钛化合物和选自一种或多种具有式（I）的硅酯化合物的内部电子给体。 制备催化剂组分的方法是：将球形氯化镁醇盐颗粒和电子给体依次加入钛化合物溶液中，并用钛化合物处理一次或多次以获得催化剂。 用于烯烃聚合的催化剂体系包括催化剂组分，助催化剂和外部电子给体。 该催化剂对丙烯聚合具有高活性，活性为4399gPP / gTi·h（50℃，1小时，常压下淤浆聚合），聚合物的全同立构规整度为98％。

公开(公告)号：US20130131292A1

公开(公告)日：2013-05-23

申请号：US13813479

申请日：2011-06-03

申请人： Zhifei Li ,  Kuilong Tan ,  Hao Wang ,  Jianjun Yi ,  Qinghong Xu ,  Weisong Cui ,  Wei Bai ,  Xinyuan Liu ,  Pu Xu ,  Wanqing Ju

发明人： Zhifei Li ,  Kuilong Tan ,  Hao Wang ,  Jianjun Yi ,  Qinghong Xu ,  Weisong Cui ,  Wei Bai ,  Xinyuan Liu ,  Pu Xu ,  Wanqing Ju

IPC分类号： C08F110/00

CPC分类号： C08F110/00 ,  C08F110/06 ,  C08F4/6465 ,  C08F2500/12 ,  C08F2500/15

摘要： Disclosed is a catalyst for the polymerization of olefins comprising thienyl-substituted silanes, which comprises a solid titanium catalyst component containing titanium, magnesium and a halogen as the main components, an alkylaluminum compound, and a component of organosiloxane compound comprising two thienyl as substituents represented by general formula (I). The molar ratio of each catalyst component is 1:50-150:5-50 based on titanium:aluminum:silicon. When the catalyst is used in the polymerization of propylene, the polymerisate obtained has very high degree of isotacticity, and the yield is high.

摘要翻译： 公开了包含噻吩基取代的硅烷的烯烃聚合催化剂，其包含含有钛，镁和卤素作为主要成分的固体钛催化剂组分，烷基铝化合物和包含两个噻吩基作为取代基的有机硅氧烷化合物的组分 由通式（I）表示。 每个催化剂组分的摩尔比基于钛：铝：硅为1:50-150:5-50。 当催化剂用于丙烯聚合时，所得聚合物具有非常高的全同立构规整度，产率高。

公开(公告)号：US20110207900A1

公开(公告)日：2011-08-25

申请号：US13127591

申请日：2008-12-02

申请人： Jianjun Yi ,  Baozuo Yin ,  Chunming Cui ,  Zhifei Li ,  Liang Cui ,  Huashu Li ,  Weihuan Huang ,  Jianying Zhang ,  Li Wang

发明人： Jianjun Yi ,  Baozuo Yin ,  Chunming Cui ,  Zhifei Li ,  Liang Cui ,  Huashu Li ,  Weihuan Huang ,  Jianying Zhang ,  Li Wang

IPC分类号： C08F4/76 ,  B01J31/02 ,  B01J37/08 ,  B01J37/06

CPC分类号： C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F4/6545 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/15 ,  C08F210/16 ,  C08F2500/12

摘要： A catalyst for homopolymerizing and copolymerizing propylene and its preparation and use. The catalyst component includes titanium compound containing at least one Ti-halogen bond and at least two kinds of electron donor compounds A and B supported on MgCl2.nROH adduct, wherein the electron donor compound A is a compound of formula (I), the electron donor compound B is ester or ether compound; the molar ratio between compound A and compound B is 0.1-5; the molar ratio between the total amounts of the two kinds of electron donors and MgCl2.nROH is 0.01-1, based on the amount of MgCl2.nROH; and the molar ration between the titanium compound containing Ti-halogen bond and MgCl2.nROH is 1-200. The catalyst has high activity, high stereospecificity and good copolymerization performance. In addition, the morphology of the polymer obtained therefrom is good.

摘要翻译： 丙烯均聚和共聚的催化剂及其制备和用途。 催化剂组分包括含有至少一个Ti-卤素键的钛化合物和负载在MgCl 2·nROH加合物上的至少两种电子给体化合物A和B，其中电子给体化合物A是式（I）化合物， 给体化合物B是酯或醚化合物; 化合物A与化合物B之间的摩尔比为0.1-5; 基于MgCl 2·nROH的量，两种电子给体和MgCl 2·nROH的总量之间的摩尔比为0.01-1。 含Ti-卤键的钛化合物与MgCl 2·nROH之间的摩尔比为1-200。 该催化剂具有高活性，高立体定向性和良好的共聚性能。 此外，由其获得的聚合物的形态是良好的。