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    Conjugated diene butyl
    1.
    发明授权
    Conjugated diene butyl 失效
    共轭二烯丁基

    公开(公告)号：US3965213A

    公开(公告)日：1976-06-22

    申请号：US465479

    申请日：1974-04-30

    申请人： Francis P. Baldwin ,  Alberto Malatesta

    发明人： Francis P. Baldwin ,  Alberto Malatesta

    IPC分类号： C08F8/00 ,  C08L21/00 ,  C08L23/22 ,  C08L9/00 ,  C08F279/02 ,  C08K5/10 ,  C08L47/00

    CPC分类号： C08L23/22 ,  C08F8/00 ,  C08L21/00

    摘要： Dehydrohalogenation of halogenated butyl to produce a butyl rubber having conjugated double bonds in the linear backbone. The composition is disclosed as having the predominant structure: ##EQU1## where n + 1 represent the number of isoolefin units incorporated in the butyl rubber polymer backbone, and m represents the number of conjugated diolefin units present, substantially as isolated units. The composition is prepared by contacting a solution of halogenated butyl rubber with: (1) a soluble metal carboxylate, where the metal is selected from the metals of Groups Ib, IIb, IVa and VIII of the Periodic Table; (2) a soluble carboxylic acid; and (3) an oxide or hydroxide of a metal selected from the metals of Groups Ia or IIa of the Periodic Table.

    摘要翻译： 卤代丁基的脱卤化氢生成在线性骨架中具有共轭双键的丁基橡胶。 该组合物被公开为具有主要结构：CH 3 CH 3 CH 3 || CH 2 -C CH = C-CH = CHCH 2 -C 3 CH 3 nmCH 31其中n + 1代表掺入丁基橡胶聚合物主链中的异烯烃单元的数量，m表示 共轭二烯烃单元的数量基本上为隔离单元。 通过使卤化丁基橡胶的溶液与（1）可溶性金属羧酸盐接触来制备组合物，其中金属选自元素周期表的Ib，IIb，IVa和VIII族的金属; （2）可溶性羧酸; 和（3）选自元素周期表的Ia或IIa族金属的金属的氧化物或氢氧化物。

    Latex from conjugated diene butyl rubber
    3.
    发明授权
    Latex from conjugated diene butyl rubber 失效
    共轭二烯丁基胶乳胶

    公开(公告)号：US3983062A

    公开(公告)日：1976-09-28

    申请号：US496199

    申请日：1974-08-09

    申请人： Francis P. Baldwin ,  Alberto Malatesta ,  Charles P. O'Farrell

    发明人： Francis P. Baldwin ,  Alberto Malatesta ,  Charles P. O'Farrell

    IPC分类号： C08F8/12 ,  C08L47/00

    CPC分类号： C08F8/12

    摘要： A process for preparing latices in ionomeric form from copolymers of an isoolefin containing from 4 to 7 carbon atoms and a conjugated multiolefin containing from 4 to 14 carbon atoms, where a major portion of said conjugated multiolefin has conjugated diene unsaturation, is disclosed. The process principally comprises forming an adduct of conjugated diene butyl rubber with a dienophile capable of implanting carboxylic acid functionality on the polymer such as maleic anhydride, emulsifying the adduct thus formed, and neutralizing the resulting emulsion with a suitable base. Highly improved ionomeric latices are also disclosed, having an average particle size of less than about 1 micron, average solids contents easily adjusted from between about 5 to 70 weight percent solids, and having a pH, depending on the emulsifier used, of from 3 to 12. Films cast from these latices have an improved tensile at break of greater than about 2500 psi.

    摘要翻译： 公开了一种从含有4至7个碳原子的异烯烃和含有4至14个碳原子的共轭多烯烃的共聚物制备离聚物形式的胶乳的方法，其中所述共轭多烯烃的主要部分具有共轭二烯不饱和度。 该方法主要包括共轭二烯丁基橡胶与能够在聚合物如马来酸酐上注入羧酸官能团的亲二烯体形成加合物，乳化由此形成的加合物，并用合适的碱中和所得的乳液。 还公开了高度改进的离聚物胶乳，其平均粒度小于约1微米，平均固体含量容易从约5-70重量％固体之间调节，并且具有取决于所用乳化剂的pH为3〜 从这些胶乳铸造的薄膜具有大于约2500psi的改进的断裂拉伸强度。

    Process for the manufacture of halogenated polymers
    5.
    发明授权
    Process for the manufacture of halogenated polymers 失效
    制备卤化聚合物的方法

    公开(公告)号：US4650832A

    公开(公告)日：1987-03-17

    申请号：US788425

    申请日：1985-10-17

    申请人： Ronald C. Kowalski ,  William M. Davis ,  Neil F. Newman ,  Zisis A. Foroulis ,  Francis P. Baldwin

    发明人： Ronald C. Kowalski ,  William M. Davis ,  Neil F. Newman ,  Zisis A. Foroulis ,  Francis P. Baldwin

    IPC分类号： C08F8/20 ,  C08F8/22

    CPC分类号： C08F8/20

    摘要： In a process for the continuous halogenation of polymers by contacting polymer and halogenating agent in a continuous flow device in which means are provided for disengaging reaction by-products and unreacted halogenating agent from the reaction mixture, by deforming and disrupting the halogenated polymer surface and injecting an inert and/or reactive gas into the halogenated polymers immediately after reaction thereby neutralizing the product. In a preferred embodiment the process is carried out in an extruder-reactor and an optional, supplementary inert and/or reactive gas scrubbing zone is included. The process is amenable to saturated and unsaturated polymers.

    摘要翻译： 在聚合物和卤化剂在连续流动装置中连续卤化聚合物的方法中，其中提供了用于使反应副产物和未反应的卤化剂从反应混合物中分离的方法，通过变形和破坏卤化聚合物表面并注入 惰性和/或反应性气体在反应后立即进入卤代聚合物，从而中和产物。 在优选的实施方案中，该方法在挤出机 - 反应器中进行，并且包括任选的补充的惰性和/或反应性气体洗涤区。 该方法适用于饱和和不饱和聚合物。

    Process for preparing conjugated diene butyl
    7.
    发明授权
    Process for preparing conjugated diene butyl 失效
    共轭二烯丁基的制备方法

    公开(公告)号：US4068051A

    公开(公告)日：1978-01-10

    申请号：US631483

    申请日：1975-11-13

    申请人： Francis P. Baldwin ,  James A. Rae

    发明人： Francis P. Baldwin ,  James A. Rae

    IPC分类号： C08F8/00 ,  C08F8/26

    CPC分类号： C08F8/26

    摘要： Improved processes for the dehydrohalogenation of halogenated butyl rubber in order to prepare a butyl rubber having randomly distributed sites of conjugated unsaturation are disclosed. Such processes, which include the contacting of a solution of halogenated butyl rubber with a soluble metal carboxylate, a soluble carboxylic acid, and an oxide or hydroxide of a metal selected from Groups Ia and IIa of the Periodic Table, are carried out in a reaction zone which is maintained substantially free of free water vapor. Preferably, excess amounts of hydrophilic reagents are added to the reaction zone or in the alternative the reaction zone is purged with a drying gas.

    摘要翻译： 公开了用于制备具有共轭不饱和度的随机分布位点的丁基橡胶的卤化丁基橡胶的脱卤化氢的改进方法。 这些方法包括将卤代丁基橡胶与可溶性金属羧酸盐的溶液，可溶性羧酸和选自元素周期表第Ia和IIa族的金属的氧化物或氢氧化物的接触反应在反应中进行 保持基本上不含游离水蒸气的区域。 优选地，将过量的亲水试剂加入到反应区中，或者在反应区中用干燥气体吹扫反应区。

    Covulcanization of conjugated diene-containing butyl with halobutyl and butyl rubber
    8.
    发明授权
    Covulcanization of conjugated diene-containing butyl with halobutyl and butyl rubber 失效
    含有共轭二烯的丁基与卤代丁基和丁基橡胶的共硫化

    公开(公告)号：US4039506A

    公开(公告)日：1977-08-02

    申请号：US562828

    申请日：1975-03-28

    申请人： Albert M. Gessler ,  Francis P. Baldwin

    发明人： Albert M. Gessler ,  Francis P. Baldwin

    IPC分类号： C08L23/22 ,  C08L23/28 ,  C08K3/04

    CPC分类号： C08L23/22 ,  C08L23/283

    摘要： Blends of 5 to 95 wt. % conjugated diene-containing butyl rubber with 95 to 25 wt. % halobutyl or butyl rubber are capable of higher carbon black loading and have faster cure times, unusually high tensile strength and improved green strength. The blends may be cured with dienophilic compounds or sulfur-based cure packages.

    摘要翻译： 共混物为5至95wt。 ％共轭二烯的丁基橡胶，95〜25wt。 ％卤代丁基或丁基橡胶能够具有更高的炭黑负载量并且具有更快的固化时间，异常高的拉伸强度和改善的生坯强度。 共混物可以用二亲性化合物或硫基固化包装固化。