Contact metathesis polymerization

    公开(公告)号:US06962729B2

    公开(公告)日:2005-11-08

    申请号:US09209706

    申请日:1998-12-11

    摘要: A method for bonding a material to a first substrate surface that includes providing a catalyst at the first substrate surface and then contacting that surface with a material that undergoes a metathesis reaction to bond the material to the first substrate surface. There are two embodiments of this method—a coating process and an adhesive process. In the coating embodiment, the metathesizable material is contacted with the catalyst on the substrate surface so that it undergoes metathesis polymerization to form the coating. The adhesive process includes (a) providing a catalyst at the first substrate surface, (b) providing a metathesizable material between the first substrate surface and the second substrate surface, and (c) contacting the catalyst on the first substrate surface with the metathesizable material so that the metathesizable material undergoes a metathesis reaction and bonds the first substrate surface to the second substrate surface.

    Transmission belts comprising a cord with at least two fused yarns
    3.
    发明授权
    Transmission belts comprising a cord with at least two fused yarns 失效
    传动带包括具有至少两根熔融纱线的绳索

    公开(公告)号:US06921572B2

    公开(公告)日:2005-07-26

    申请号:US10203893

    申请日:2001-02-13

    申请人: Jan Van Campen

    发明人: Jan Van Campen

    摘要: A transmission belt is made of a cord, a rubber or thermoplastic matrix, and an adhesion material which is able to adhere the cord to the rubber or thermoplastic matrix. The cord is made of at least two yarns, such that a first yarn has a melting or decomposition point T1 and a second yarn has a melting point T2, wherein T1>T2. A ratio of a linear density of the first yarn to a linear density of the second yarn is between 1,000:1 and 1:1, wherein the second yarn is fused to the first yarn. A method of making such cords includes intertwining the first and the second yarn and then heating to a temperature between T1 and T2, with the heating step being integrated with or followed by a step wherein the cord is subjected to a dipping treatment with a rubber adhesion material.

    摘要翻译: 传动带由绳索,橡胶或热塑性基体和能够将绳索粘附到橡胶或热塑性基体上的粘合材料制成。 帘线由至少两根纱线制成,使得第一纱线具有熔点或分解点T 1,第二纱线具有熔点T 2 N,其中T 2 T 2 2。 第一纱线的线密度与第二纱线的线密度的比率在1,000:1和1:1之间,其中第二纱线与第一纱线熔合。 制造这种帘线的方法包括将第一纱线和第二纱线相互缠绕,然后加热到T 1和T 2 2之间的温度,加热步骤与或之后整合 通过使用橡胶粘合材料进行浸渍处理的步骤。

    Method of bonding an ethylene-&agr;-olefin rubber composition to a fiber cord and a fiber cord-rubber laminate made according to the method
    4.
    发明授权
    Method of bonding an ethylene-&agr;-olefin rubber composition to a fiber cord and a fiber cord-rubber laminate made according to the method 有权
    将乙烯-α-烯烃橡胶组合物粘合到纤维帘线和根据该方法制造的纤维帘线 - 橡胶层压材料的方法

    公开(公告)号:US06607828B1

    公开(公告)日:2003-08-19

    申请号:US09461601

    申请日:1999-12-15

    申请人: Hitoshi Hasaka

    发明人: Hitoshi Hasaka

    IPC分类号: B32B2502

    摘要: A method of bonding an ethylene.&agr;-olefin rubber composition to a fiber cord. The method includes the steps of: treating a fiber cord with a first treating solution that is at least one of an isocyanate compound and an epoxy compound; after treating the fiber cord with the first treating solution, treating the fiber cord with a second treating solution including resorcinol-formalin-rubber latex; after treating the fiber cord with the second treating solution, treating the fiber cord with a third treating solution including a halogenated polymer and a vulcanizing agent; and after treating the fiber cord with the third treating solution, vulcanization-bonding an unvulcanized ethylene.&agr;-olefin rubber composition to the fiber cord.

    摘要翻译: 将乙烯-α-烯烃橡胶组合物粘合到纤维帘线上的方法。 该方法包括以下步骤:用至少一种异氰酸酯化合物和环氧化合物的第一处理溶液处理纤维帘线; 在用第一处理溶液处理纤维帘线之后,用包括间苯二酚 - 福尔马林 - 橡胶胶乳的第二处理溶液处理纤维帘线; 在用第二处理溶液处理纤维帘线之后,用包含卤化聚合物和硫化剂的第三处理溶液处理纤维帘线; 并且在用第三处理溶液处理纤维帘线之后,将未硫化的乙烯-α-烯烃橡胶组合物硫化成纤维帘线。

    Textile/rubber composites
    5.
    发明授权
    Textile/rubber composites 失效
    纺织/橡胶复合材料

    公开(公告)号:US06497954B1

    公开(公告)日:2002-12-24

    申请号:US09561267

    申请日:2000-04-28

    IPC分类号: D02G300

    摘要: This invention relates to a method of promoting the adhesion of textiles to rubber compounds through a vinyl compound plasma pre-treatment procedure and a subsequent application of resorcinol-formaldehyde latex (RFL) to the textile surface. The inventive method encompasses a process through which free radicals of compounds comprising strong carbon-carbon bonds form a film over textile films and then covalently bonded to the resin component of the RFL. Such a method thus produces an extremely strong and versatile adhesive that facilitates adhesion between rubber compounds and heretofore unusable or difficult-to-use textiles. The resultant textile/rubber composites are utilized as reinforcements within such materials as automobile tires, fan belts, conveyor belts, and the like. Such materials and composites are also contemplated within this invention.

    摘要翻译: 本发明涉及通过乙烯基化合物等离子体预处理方法和随后将间苯二酚 - 甲醛胶乳(RFL)应用于织物表面来促进纺织品对橡胶化合物的粘附的方法。 本发明的方法包括一种方法,通过该方法,包含强碳 - 碳键的化合物的自由基在织物膜上形成膜,然后共价键合到RFL的树脂组分。 因此,这样一种方法产生了一种非常坚固和通用的粘合剂,其有助于橡胶化合物之间的粘合和迄今为止不可用或难以使用的纺织品之间的粘合。 所得的纺织品/橡胶复合材料用作汽车轮胎,风扇皮带,传送带等材料中的增强材料。 这些材料和复合材料也在本发明中。

    Adhesive composition and method for adhering textiles to EPDM rubber
    6.
    发明申请
    Adhesive composition and method for adhering textiles to EPDM rubber 有权
    用于将纺织品粘附到EPDM橡胶上的粘合剂组合物和方法

    公开(公告)号:US20020144779A1

    公开(公告)日:2002-10-10

    申请号:US10093281

    申请日:2002-03-07

    发明人: Daniel A. Pelton

    IPC分类号: C09J001/00

    摘要: An improved adhesive composition and method for adhering textile reinforcing elements to rubber, particularly ethylene-propylene-diene rubber in the manufacture of rubber articles such as power transmission belts, wherein the adhesive composition comprises a latex of a hydrogenated styrene-butadiene rubber, a carboxylated hydrogenated styrene-butadiene rubber, a hyddogenated nitrile-butadiene rubber, a carboxylated hydrogenated nitrile-butadiene rubber, a chlorosulfonated polyethylene or blends thereof; an aqueous solution of a half-ester of maleinized liquid poybutadiene; and, optionally, up to about 15% by weight carbon black in an aqueous solution.

    摘要翻译: 一种改进的粘合剂组合物和用于在橡胶制品如动力传动带的制造中将纺织增强元件粘附到橡胶,特别是乙烯 - 丙烯 - 二烯橡胶上的粘合剂组合物和方法,其中粘合剂组合物包括氢化苯乙烯 - 丁二烯橡胶的胶乳, 氢化丁苯橡胶,氢化丁腈橡胶,羧化氢化丁腈橡胶,氯磺化聚乙烯或其混合物; 马来酸化液体聚丁二烯的半酯的水溶液; 和任选地至多约15重量%的炭黑在水溶液中。

    CONTACT METATHESIS POLYMERIZATION
    7.
    发明申请
    CONTACT METATHESIS POLYMERIZATION 失效
    联系METATHESIS聚合

    公开(公告)号:US20020053379A1

    公开(公告)日:2002-05-09

    申请号:US09209706

    申请日:1998-12-11

    IPC分类号: B60C001/00

    摘要: A method for bonding a material to a first substrate surface that includes providing a catalyst at the first substrate surface and then contacting that surface with a material that undergoes a metathesis reaction to bond the material to the first substrate surface. There are two embodiments of this methodnulla coating process and an adhesive process. In the coating embodiment, the metathesizable material is contacted with the catalyst on the substrate surface so that it undergoes metathesis polymerization to form the coating. The adhesive process includes (a) providing a catalyst at the first substrate surface, (b) providing a metathesizable material between the first substrate surface and the second substrate surface, and (c) contacting the catalyst on the first substrate surface with the metathesizable material so that the metathesizable material undergoes a metathesis reaction and bonds the first substrate surface to the second substrate surface.

    摘要翻译: 一种用于将材料粘合到第一衬底表面的方法,包括在第一衬底表面处提供催化剂,然后使该表面与经历复分解反应的材料接触以将材料粘合到第一衬底表面。 该方法有两个实施方案 - 涂覆方法和粘合方法。 在涂布实施例中,可复分解材料与衬底表面上的催化剂接触,使得其进行易位聚合以形成涂层。 粘合方法包括(a)在第一基材表面提供催化剂,(b)在第一基材表面和第二基材表面之间提供可复分解材料,和(c)使第一基材表面上的催化剂与可复分解材料 使得可复分解材料经历复分解反应并将第一基材表面结合到第二基材表面。

    Rubber-reinforcing glass fiber product
    9.
    发明授权
    Rubber-reinforcing glass fiber product 失效
    橡胶增强玻璃纤维制品

    公开(公告)号:US5885718A

    公开(公告)日:1999-03-23

    申请号:US594938

    申请日:1996-01-31

    摘要: A treating agent comprises a nitrile group-containing highly saturated polymer rubber latex (A) having an iodine value of 120 or less, a rubber latex (B) other than the highly saturated polymer rubber latex, and a water-soluble resorcinol/formaldehyde condensate in amounts of 15 to 80%, 5 to 70% and 2 to 15%, all by weight in terms of solids, respectively. A rubber-reinforcing fiber product is coated with the treating agent. A rubber article such as a toothed belt, a tire and the like is made using this rubber-reinforcing fiber product. The glass fiber product coated with the treating agent may be further coated with a halogen-containing polymer-based adhesive as a secondary treating agent. Thus, the treating agent exhibits a large bonding force between the reinforcing fiber product and a matrix. Even if the rubber article is repeatedly subjected to a flexing stress, the strength thereof cannot be reduced. A peel-off cannot occurs between the reinforcing fiber product and the rubber matrix. Moreover, the rubber article has sufficient heat and water resistances.

    摘要翻译: 处理剂包括碘值为120以下的含腈基的高饱和聚合物橡胶胶乳(A),高饱和聚合物橡胶胶乳以外的橡胶胶乳(B)和水溶性间苯二酚/甲醛缩合物 分别为15〜80%,5〜70%,2〜15%。 用处理剂涂覆橡胶增强纤维制品。 使用这种橡胶增强纤维制品制造诸如齿形带,轮胎等的橡胶制品。 涂覆有处理剂的玻璃纤维产品可以进一步涂覆有含卤聚合物的粘合剂作为二次处理剂。 因此,处理剂在增强纤维产品和基质之间表现出很大的粘结力。 即使橡胶制品反复受到弯曲应力,其强度也不能降低。 增强纤维制品和橡胶基质之间不能发生剥离。 此外,橡胶制品具有足够的耐热和耐水性。