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    FLUORINATED COPOLYMER AND PROCESS FOR ITS PRODUCTION, AND WATER/OIL REPELLENT COMPOSITION
    1.
    发明申请
    FLUORINATED COPOLYMER AND PROCESS FOR ITS PRODUCTION, AND WATER/OIL REPELLENT COMPOSITION 审中-公开
    氟化共聚物及其制备方法和水/油组合物

    公开(公告)号：US20140343206A1

    公开(公告)日：2014-11-20

    申请号：US14448217

    申请日：2014-07-31

    申请人： ASAHI GLASS COMPANY, LIMITED

    发明人： Miyako SASAKI ,  Taiki Hoshino ,  Nobuyuki Otozawa

    IPC分类号： C08F220/24 ,  C08K5/07 ,  C08F220/18

    CPC分类号： C08F220/24 ,  B65G3/00 ,  C08F220/18 ,  C08F290/04 ,  C08F291/04 ,  C08K5/07 ,  D06M15/263 ,  D06M15/267 ,  D06M15/273 ,  D06M15/277 ,  D06M2200/11 ,  D06M2200/12 ,  C08F220/14

    摘要： To provide a fluorinated copolymer and a water/oil repellent composition, whereby adequate water/oil repellency and excellent dynamic water repellency are obtainable and environmental impact is low. A fluorinated copolymer comprising units (A1) derived from a macromonomer wherein the average polymerization degree of e.g. 2-perfluorohexylethyl acrylate is from 20 to 30, and units (B) derived from a monomer (b) which has no fluoroalkyl group and no cross-linkable functional group and of which the glass transition temperature, when formed into a homopolymer, is from 50 to 150° C., wherein the average polymerization degree of the macromonomer per one molecule of the fluorinated copolymer is at least 1, and a water/oil repellent composition containing such a fluorinated copolymer.

    摘要翻译： 为了提供含氟共聚物和斥水斥油剂组合物，由此可以获得足够的拒水拒油性和优异的动态拒水性，并且环境影响低。 包含衍生自大分子单体的单元（A1）的氟化共聚物，其中平均聚合度为 2-全氟己基乙基丙烯酸酯为20〜30，单体（B）衍生自不含氟代烷基且不具有交联性官能团的单体（b），玻璃化转变温度在形成均聚物时为 50〜150℃，其中，每1分子含氟共聚物中的大分子单体的平均聚合度为1以上，含有该氟化共聚物的斥水斥油剂组合物。

    SURFACE-MODIFIED ELASTIC BODY
    2.
    发明申请
    SURFACE-MODIFIED ELASTIC BODY 有权
    表面改性弹性体

    公开(公告)号：US20140155510A1

    公开(公告)日：2014-06-05

    申请号：US14077829

    申请日：2013-11-12

    申请人： SUMITOMO RUBBER INDUSTRIES, LTD.

    发明人： Yasuhisa MINAGAWA

    IPC分类号： C08F36/18

    CPC分类号： C08J7/18 ,  A61L29/042 ,  A61L29/06 ,  A61L29/08 ,  A61L29/085 ,  A61L29/14 ,  A61L2400/18 ,  A61M3/00 ,  A61M5/178 ,  A61M5/31513 ,  A61M25/00 ,  A61M25/0009 ,  A61M25/0045 ,  A61M2025/0046 ,  A61M2025/0056 ,  A61M2025/0062 ,  B05D3/067 ,  C08F2/48 ,  C08F36/18 ,  C08F220/56 ,  C08F291/02 ,  C08F291/04 ,  C08J3/28 ,  C08J7/12 ,  C08J2323/28 ,  C08J2433/26 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/1393 ,  C08L9/00

    摘要： Provided are surface-modified elastic bodies (e.g. gasket for syringes) each obtained by a surface modification method for modifying a rubber vulcanizate or a thermoplastic elastomer, the method being capable of providing surfaces with excellent properties such as excellent sliding properties, excellent durability against repeated sliding motion, and excellent performance in preventing adsorption and aggregation of proteins, and allowing the surfaces to maintain the sealing properties, without using expensive self-lubricating plastics. The invention relates to surface-modified elastic bodies (e.g. gasket for syringes) at least partially having a surface modified by a surface modification method including: step 1 of forming polymerization initiation points on a surface of an object to be modified that includes a rubber vulcanizate or thermoplastic elastomer, and step 2 of radically polymerizing a monomer containing a C—N bond in a molecule thereof, starting from the polymerization initiation points, to grow polymer chains on the surface of the object.

    摘要翻译： 提供了通过用于改性橡胶硫化橡胶或热塑性弹性体的表面改性方法获得的表面改性弹性体（例如注射器的垫圈），该方法能够提供具有优异性能的表面，例如优异的滑动性能，优异的耐重复性 滑动运动，以及防止蛋白质的吸附和聚集的优异性能，并且允许表面保持密封性能，而不使用昂贵的自润滑塑料。 本发明涉及至少部分具有通过表面改性方法改性的表面的表面改性弹性体（例如注射器的垫圈），其包括：步骤1，在待改性物体的表面上形成聚合起始点，其包括橡胶硫化橡胶 或热塑性弹性体，以及步骤2，从聚合起始点开始，在其分子中自由基聚合含有C-N键的单体，以在物体的表面上生长聚合物链。

    Graft copolymer and process for producing the same
    4.
    发明授权
    Graft copolymer and process for producing the same 失效
    接枝共聚物及其制备方法

    公开(公告)号：US08604133B2

    公开(公告)日：2013-12-10

    申请号：US11884309

    申请日：2006-02-14

    申请人： Shigeharu Takagi ,  Mitsuru Higa

    发明人： Shigeharu Takagi ,  Mitsuru Higa

    IPC分类号： C08F259/02 ,  B01J39/20 ,  H01M8/10 ,  H01M6/18

    CPC分类号： C08F291/04 ,  C08F293/005 ,  C08F2438/01 ,  C08F2/38

    摘要： A graft copolymer having a side chain graft-polymerized by atom transfer living radical polymerization (ATRP) on a main chain polymerized by organotellurium-mediated living radical polymerization (TERP), wherein the molecular weight distribution is such that Mw/Mn is 1.5 or less. The graft copolymer is also such that a main chain moiety mainly consisting of the main chain and a side chain moiety mainly consisting of the side chain have microphase-separated structures. The graft copolymer has a narrow molecular weight distribution and forms microphase-separated structures through self organization of hydrophobic and hydrophilic moieties.

    摘要翻译： 在通过有机碲介导的活性自由基聚合（TERP）聚合的主链上具有通过原子转移活性自由基聚合（ATRP）接枝聚合的侧链的接枝共聚物，其中分子量分布使得Mw / Mn为1.5以下 。 接枝共聚物也使主要由主链构成的主链部分和主要由侧链构成的侧链部分具有微相分离结构。 接枝共聚物具有窄的分子量分布，并通过疏水和亲水部分的自组织形成微相分离的结构。

    FLUORINE-BASED SURFACTANT, AND COATING COMPOSITION AND RESIST COMPOSITION EACH USING THE SAME
    10.
    发明申请
    FLUORINE-BASED SURFACTANT, AND COATING COMPOSITION AND RESIST COMPOSITION EACH USING THE SAME 审中-公开
    基于荧光体的表面活性剂，以及使用它们的涂料组合物和抗蚀剂组合物

    公开(公告)号：US20130172476A1

    公开(公告)日：2013-07-04

    申请号：US13807477

    申请日：2011-06-28

    申请人： Shin Sasamoto ,  Hideya Suzuki

    发明人： Shin Sasamoto ,  Hideya Suzuki

    IPC分类号： C08F222/20

    CPC分类号： C08F222/20 ,  C08F283/065 ,  C08F290/04 ,  C08F290/062 ,  C08F291/04 ,  C09D7/47 ,  C09D11/101 ,  G03F7/0046 ,  G03F7/0048 ,  C08F2220/287 ,  C08F2222/108 ,  C08F2220/288 ,  C08F2222/185 ,  C08F2220/286 ,  C08F2220/1875

    摘要： Provided is a fluorine-based surfactant including a copolymer synthesized by copolymerizing, as essential monomers, a polymerizable monomer (A) having a poly(perfluoroalkylene ether) chain and polymerizable unsaturated groups at both ends of the chain and a polymerizable monomer (B) having an oxyalkylene group and a polymerizable unsaturated group. The fluorine-based surfactant cannot structurally generate PFOS or PFOA, which tend to accumulate in the environment and living bodies; even when the fluorine-based surfactant has lower fluorine content than surfactants having a fluoroalkyl group having 8 or more carbon atoms, the fluorine-based surfactant has a higher capability of decreasing surface tension than the surfactants. Accordingly, the fluorine-based surfactant can be suitably used as a leveling agent for a coating composition, a resist composition, or the like.

    摘要翻译： 本发明提供一种氟系表面活性剂，其包括通过共聚作为必需单体合成的共聚合物，该链段的两端具有聚（全氟亚烷基醚）链和可聚合不饱和基团的可聚合单体（A）和可聚合单体（B） 氧化烯基和聚合性不饱和基。 氟基表面活性剂不能在结构上产生易于积聚在环境和生物体中的PFOS或PFOA; 即使氟系表面活性剂的氟含量低于具有碳原子数为8以上的氟代烷基的表面活性剂，氟系表面活性剂比表面活性剂具有较高的表面张力降低能力。 因此，氟系表面活性剂可以适合用作涂料组合物，抗蚀剂组合物等的流平剂。