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    Modified ziegler catalyst, process for preparing it and process for preparing poly-1-olefins in its presence
    1.
    发明申请
    Modified ziegler catalyst, process for preparing it and process for preparing poly-1-olefins in its presence 失效
    改性齐格勒催化剂，其制备方法和在其存在下制备聚-1-烯烃的方法

    公开(公告)号：US20050261123A1

    公开(公告)日：2005-11-24

    申请号：US10523775

    申请日：2003-07-31

    申请人： Frank Alt ,  Ludwig Bohm ,  Friedhelm Gundert

    发明人： Frank Alt ,  Ludwig Bohm ,  Friedhelm Gundert

    IPC分类号： C08F4/652 ,  B01J31/00 ,  C08F4/44 ,  C08F4/64 ,  C08F4/69 ,  C08F10/02 ,  C08F110/02

    CPC分类号： C08F10/02 ,  C08F110/02 ,  C08F4/6465 ,  C08F4/6567 ,  C08F2500/17 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/04

    摘要： The invention relates to a modified Ziegler catalyst for preparing a poly-1-olefin in suspension, in solution or in the gas phase, which catalyst comprises the reaction product of a magnesium alkoxide (component a) with a transition metal compound (component b) and an organometallic compound (component c) together with an additional component (d) comprising a compound of the chemical formula M—Rx where M is an element of main group IV of the Periodic Table, R is halogen or an organic radical such as alkyl having from 1 to 10 carbon atoms, oxyalkyl having from 1 to 10 carbon atoms, cycloalkyl having from 4 to 8 carbon atoms in the ring and, if desired, from 1 to 6 substituents R′ on the ring, aryl having from 6 to 10 carbon atoms in the aromatic and, if desired, from 1 to 6 substituents R′ on the aromatic, where R′ is a halogen or an alkyl radical having from 1 to 4 carbon atoms or an OH group or an NO2 group or an oxyalkyl radical having from 1 to 4 carbon atoms, and x is an integer from 1 to 4. The invention also relates to a process for preparing the Ziegler catalyst and to the homopolymerization or copolymerization of 1-olefins in its presence.

    摘要翻译： 本发明涉及一种用于在悬浮液，溶液或气相中制备聚-1-烯烃的改性齐格勒催化剂，该催化剂包括烷氧基镁（组分a）与过渡金属化合物（组分b）的反应产物， 和有机金属化合物（组分c）以及另外的组分（d），其中包含化合物的化合物，其化学式为“？in-line-formula description =”In-line Formulas“end =”lead“？> <？in-line-formula description =“In-line Formulas”end =“tail”？>其中M是元素周期表第IV族的元素，R是卤素或有机基团如烷基 具有1至10个碳原子，具有1至10个碳原子的烷氧基烷基，环中具有4至8个碳原子的环烷基，如果需要，在环上具有1至6个取代基R'，具有6至10个 芳族化合物中的碳原子，如果需要，芳族中有1至6个取代基R'，其中R'是卤素或具有 1至4个碳原子或OH基团或NO 2 CO 2基团或具有1至4个碳原子的氧烷基，x为1至4的整数。本发明还涉及 齐格勒催化剂的制备方法和1-烯烃在其存在下的均聚或共聚。

    Polyethylene composition for producing l-ring drums
    3.
    发明申请
    Polyethylene composition for producing l-ring drums 审中-公开
    聚乙烯组合物，用于生产l环鼓

    公开(公告)号：US20060052542A1

    公开(公告)日：2006-03-09

    申请号：US10538894

    申请日：2003-12-10

    申请人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    发明人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    IPC分类号： C08L23/04

    CPC分类号： C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2207/068 ,  C08L2666/02 ,  C08L2666/06

    摘要： The invention relates to a polyethylene composition with multimodal molecular mass distribution, which is particularly suitable for the blow molding of L-ring drums having a volume in the range of from 50 to 250 dm3 (I). The composition has a density in the range of from 0.950 to 0.956 g/cm3 at 23° C. and a MFR1gp/21.6 in the range from 1.5 to 3.5 dg/min. It comprises from 35 to 45% by weight of a low-molecular-mass ethylene homopolymer A, from 34 to 44% by weight of a high-molecular-mass copolymer B made from ethylene and from another 1-olefin having from 4 to 8 carbon atoms, and from 18 to 26 % by weight of an ultrahigh-molecular-mass ethylene copolymer C.

    摘要翻译： 本发明涉及具有多峰分子量分布的聚乙烯组合物，其特别适用于体积在50-250dm 3（I）范围内的L型环鼓的吹塑。 组合物在23℃下的密度范围为0.950-0.956g / cm 3，MFR1 / 1cp / 21.6℃范围为1.5-3.5dg /分钟 它包含35至45重量％的低分子量乙烯均聚物A，34至44重量％的由乙烯制成的高分子量共聚物B和具有4至8个的另外的1-烯烃 碳原子和18至26重量％的超高分子量乙烯共聚物C.

    Method for producing a poly-1olefin in the presence of a ziegler catalyst
    4.
    发明申请
    Method for producing a poly-1olefin in the presence of a ziegler catalyst 有权
    在齐格勒催化剂存在下制备聚-1-烯烃的方法

    公开(公告)号：US20050239978A1

    公开(公告)日：2005-10-27

    申请号：US10514095

    申请日：2003-05-22

    申请人： Ludwig Bohm ,  Joachim Berthold

    发明人： Ludwig Bohm ,  Joachim Berthold

    IPC分类号： C08F10/00 ,  C08F4/44 ,  C08F4/60 ,  C08F4/658 ,  C08F10/02 ,  C08F110/02

    CPC分类号： C08F110/02 ,  C08F10/02 ,  C08F4/6555 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

    摘要： The invention relates to a method for producing a poly-1-olefin by polymerization of a 1-olefin of the formula R4C═CH2, in which R4 is hydrogen or an alkyl radical having from 1 to 10 carbon atoms, in suspension, in solution or in the gas phase, at a temperature of from 20 to 200° C. and a pressure of from 0.5 to 50 bar, in the presence of a catalyst which consists of the product of the reaction of a magnesium alkoxide with a transition-metal compound (component a) and an organometallic compound (component b), whose component (a) has been produced by reacting a transitionmetal compound of titanium, zirconium, vanadium or chromium with a gelatinous dispersion of the magnesium alkoxide in an inert hydrocarbon. In accordance with the invention, the gelatinous dispersion is obtained by stirring, using a stirring element, or shearing, using a high-performance shearing tool, a suspension of a magnesium alkoxide powder having a mean particle size, expressed as the d50 value, in the range from 50 to 1000 um, in an aliphatic hydrocarbon in which the magnesium alkoxide particles are insoluble. The suspension has, before conversion into the dispersion, been subjected to heat treatment at a temperature in the range from 40 to 150° C. over a period of from 10 to 100 hours.

    摘要翻译： 本发明涉及通过聚合式R 4 C-CH 2 2-的1-烯烃制备聚-1-烯烃的方法，其中R 0 > 4是氢或具有1至10个碳原子的烷基，悬浮液，溶液或气相中，温度为20-200℃，压力为0.5至50 在由醇盐与过渡金属化合物（组分a）的反应产物和有机金属化合物（组分b）组成的催化剂的存在下，其组分（a）通过使 钛，锆，钒或铬的过渡金属化合物与烷氧基镁在惰性烃中的凝胶状分散体。 根据本发明，通过使用搅拌元件搅拌或使用高性能剪切工具剪切平均粒度的烷氧基镁粉末的悬浮液（表示为d＆lt; 在50〜1000μm的范围内，在烷氧基镁颗粒不溶的脂族烃中。 悬浮液在转化成分散体之前，在10〜100小时的时间内，在40〜150℃的温度下进行热处理。

    Method for the quantitative analysis of Al-C- and Al-H- bonds in hydrocarbons
    5.
    发明授权
    Method for the quantitative analysis of Al-C- and Al-H- bonds in hydrocarbons 失效
    烃中Al-C和Al-H键的定量分析方法

    公开(公告)号：US4130396A

    公开(公告)日：1978-12-19

    申请号：US800911

    申请日：1977-05-26

    申请人： Ludwig Bohm

    发明人： Ludwig Bohm

    IPC分类号： G01N21/78 ,  G01N31/00 ,  G01N31/16 ,  G01N21/06

    CPC分类号： G01N31/16 ,  G01N21/78 ,  G01N31/00

    摘要： For quantitative analysis of aluminum compounds containing Al--C-- and Al--H-- bonds in hydrocarbons the organo-aluminum compounds are decomposed with a lower alcohol and the excess alcohol is subjected to back titration with the solution of a colored compound of an alkali metal with a polynuclear aromatic hydrocarbon.

    摘要翻译： 对于在烃中含有Al-C和Al-H键的铝化合物的定量分析，有机铝化合物用低级醇分解，过量的醇用碱金属的有色化合物的溶液进行反滴定 与多核芳烃。

    Process for producing low molecular-weight poly-1-olefins
    6.
    发明授权
    Process for producing low molecular-weight poly-1-olefins 失效
    低分子量聚-1-烯烃的制备方法

    公开(公告)号：US5917100A

    公开(公告)日：1999-06-29

    申请号：US864211

    申请日：1997-05-28

    申请人： Ludwig Bohm ,  Hans-Friedrich Herrmann ,  Joachim Berthold ,  Gerd Hohner ,  Rainer Lecht ,  Hans Joachim Vetter

    发明人： Ludwig Bohm ,  Hans-Friedrich Herrmann ,  Joachim Berthold ,  Gerd Hohner ,  Rainer Lecht ,  Hans Joachim Vetter

    IPC分类号： C08F4/654 ,  C08F4/60 ,  C08F4/626 ,  C08F4/634 ,  C08F4/635 ,  C08F10/00 ,  C08F110/00 ,  C10L1/16 ,  C07C2/24

    CPC分类号： C08F10/00 ,  Y10S526/905

    摘要： A catalyst formed by the reaction of a magnesium alkoxide dispersion having a particle size of from 100 to 3000 nm with a compound of a metal selected from the group comprising titanium, zirconium, vanadium and chromium and then with a chlorine-containing organoaluminum compound possesses a very good hydrogen responsiveness and a high activity even in the presence of molecular-weight regulators such as hydrogen. The catalyst is therefore outstandingly suitable for the production of low molecular-weight polyolefins. The catalyst makes possible the production of waxes having a reduced residual ash content. The large particle diameter and the low fines content of the polymer powder produced by suspension polymerization with this catalyst enables easy removal of the suspension medium and drying. The catalyst is furthermore advantageously used in solution polymerization and, because of the large particle diameter, in gas phase polymerization for producing low molecular-weight poly-1-olefins.

    摘要翻译： 由粒径为100〜3000nm的烷氧基镁分散体与选自钛，锆，钒，铬的金属化合物反应形成的催化剂，然后与含氯有机铝化合物反应形成的催化剂具有 甚至在分子量调节剂如氢气的存在下也具有非常好的氢响应性和高活性。 因此，催化剂非常适合于生产低分子量聚烯烃。 该催化剂使得生产具有减少的残余灰分含量的蜡成为可能。 通过与该催化剂的悬浮聚合制备的聚合物粉末的大粒径和低细粉含量可以容易地除去悬浮介质并干燥。 此外，催化剂有利地用于溶液聚合，并且由于粒径大，用于制备低分子量聚-1-烯烃的气相聚合。

    Process for the quantitative analysis of organoaluminum compounds in their solutions
    8.
    发明授权
    Process for the quantitative analysis of organoaluminum compounds in their solutions 失效
    在其溶液中定量分析有机铝化合物的方法

    公开(公告)号：US4152117A

    公开(公告)日：1979-05-01

    申请号：US881912

    申请日：1978-02-28

    申请人： Ludwig Bohm

    发明人： Ludwig Bohm

    IPC分类号： G01N33/00 ,  G01N25/48 ,  G01N31/00 ,  G01N33/20 ,  G01N25/20

    CPC分类号： G01N25/4873

    摘要： The concentration of organoaluminum compounds in their solutions can be determined quantitatively, even in a range of less than 10 mmols/dm.sup.3, when adding to the solution to be analyzed instantaneously an excess of reactant and when measuring the produced reaction heat.

    摘要翻译： 当添加到瞬时分析过量的反应物和测量所产生的反应热量的溶液中时，即使在小于10mmol / dm 3的范围内，可以定量地测定其溶液中的有机铝化合物的浓度。

    Polyethylene blow molding composition for producing jerry cans
    9.
    发明申请
    Polyethylene blow molding composition for producing jerry cans 审中-公开
    聚乙烯吹塑组合物，用于生产杰瑞罐

    公开(公告)号：US20060074194A1

    公开(公告)日：2006-04-06

    申请号：US10538896

    申请日：2003-12-06

    申请人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    发明人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    IPC分类号： C08L23/04

    CPC分类号： C08L23/06 ,  C08F297/08 ,  C08F297/086 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2314/02 ,  C08L2666/06 ,  C08L2666/04 ,  C08L2666/02

    摘要： The invention relates to a polyethylene composition with multimodal molecular mass distribution, which is particularly suitable for the blow moulding of canisters having a volume in the range of from 2 to 20 dm3 (I). The composition has a density in the range from 0.950 to 0.958 g/cm3 at 23° C. and an MFR190/5 in the range of from 0.30 to 0.50 dg/min. It comprises from 40 to 50% by weight of a low-molecular-mass ethylene homopolymer A, from 25 to 35% by weight of a high-molecular-mass copolymer B made from ethylene and from another olefin having from 4 to 8 carbon atoms, and from 24 to 28% by weight of an ultrahigh-molecular-mass ethylene copolymer C.

    摘要翻译： 本发明涉及具有多峰分子量分布的聚乙烯组合物，其特别适用于体积在2至20dm 3（I）范围内的罐的吹塑。 组合物在23℃下的密度为0.950至0.958g / cm 3，MFR为190至0.50dg的MFR为190/5 / /分钟 它包含40至50重量％的低分子量乙烯均聚物A，25至35重量％的由乙烯制成的高分子量共聚物B和具有4至8个碳原子的另一种烯烃 ，和24〜28重量％的超高分子量乙烯共聚物C.

    Polyethylene blow molding composition for producing large containers
    10.
    发明申请
    Polyethylene blow molding composition for producing large containers 审中-公开
    用于生产大容器的聚乙烯吹塑组合物

    公开(公告)号：US20060074193A1

    公开(公告)日：2006-04-06

    申请号：US10538895

    申请日：2003-12-10

    申请人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    发明人： Joachim Berthold ,  Ludwig Bohm ,  Peter Krumpel ,  Rainer Mantel

    IPC分类号： C08L23/04

    CPC分类号： C08L23/06 ,  C08F297/08 ,  C08F297/086 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2666/06 ,  C08L2666/04 ,  C08L2666/02

    摘要： The invention relates to a polyethylene composition with multimodal molecular mass distribution, which is particularly suitable for the blow molding of large containers with a volume in the range of from 10 to 150 dm3 (I). The composition has a density in the range of from 0.949 to 0.955 g/cm3 at 23° C. and an MFI190/5 in the range of from 0.1 to 0.3 dg/min. It comprises from 38 to 45% by weight of a low-molecular-mass ethylene homopolymer A, from 30 to 40% by weight of a high-molecular-mass copolymer B made from ethylene and from another 1-olefin having from 4 to 8 carbon atoms, and from 18 to 26% by weight of an ultrahigh-molecular-mass ethylene copolymer C.

    摘要翻译： 本发明涉及具有多峰分子量分布的聚乙烯组合物，其特别适用于体积在10至150 dm 3（I）范围内的大容器的吹塑。 组合物在23℃下的密度为0.949〜0.955g / cm 3，MFI为190〜0.5 / 0.1，范围为0.1〜0.3 dg / min。 它包含38至45重量％的低分子量乙烯均聚物A，30至40重量％的由乙烯制成的高分子量共聚物B和具有4至8个的另外的1-烯烃 碳原子和18至26重量％的超高分子量乙烯共聚物C.