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1.发明授权Method for carrying out radical ethylene high-pressure polymerization while preventing undesired polymer deposits 有权进行自由基乙烯高压聚合同时防止不期望的聚合物沉积物的方法公开(公告)号：US06562915B2
公开(公告)日：2003-05-13
申请号：US10182563
申请日：2002-07-31
申请人： Frank-Olaf Mähling , Andreas Deckers , Dieter Littmann , Heinz Friedrich Sutoris , Kaspar Evertz
发明人： Frank-Olaf Mähling , Andreas Deckers , Dieter Littmann , Heinz Friedrich Sutoris , Kaspar Evertz
IPC分类号： C08F240
CPC分类号： C08F297/08 , C08F110/02 , C08F2/40 , C08F2/00 , C08F4/34 , C08F2/005 , C08F2500/26
摘要： In a process for the polymerization or copolymerization of ethylenically unsaturated monomers in the presence of polymerization initiators which decompose to form free radicals in a continuously operated polymerization apparatus comprising a fresh gas feed line, a precompressor, a postcompressor, a reactor, a pressure maintenance valve, a high-pressure circuit having a high-pressure product separator and a high-pressure circulation gas return line, a product valve and a low-pressure circuit having a low-pressure product separator and a low-pressure circulation gas return line, nitrogen monoxide or oxygen is introduced as inhibitor into the high-pressure circuit, into the low-pressure circuit and/or the precompressor.
摘要翻译： 在用于在连续操作的聚合装置中分解形成自由基的聚合引发剂存在下烯键式不饱和单体的聚合或共聚的方法中，所述聚合引发剂包括新鲜气体进料管线，预压缩机，后压缩机，反应器，压力维持阀 具有高压产品分离器和高压循环气体返回管路的高压回路，具有低压产品分离器和低压循环气体返回管路的产品阀和低压回路，氮气 将一氧化碳或氧气作为抑制剂引入高压回路中，进入低压回路和/或预压缩机。
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公开(公告)号：US5872252A
公开(公告)日：1999-02-16
申请号：US867041
申请日：1997-06-02
申请人： Heinz Friedrich Sutoris , Alexander Aumuller , Andreas Koch , Andreas Deckers , Eckard Schauss , Roger Klimesch , Arend Jouke Kingma , Wilhelm Weber
发明人： Heinz Friedrich Sutoris , Alexander Aumuller , Andreas Koch , Andreas Deckers , Eckard Schauss , Roger Klimesch , Arend Jouke Kingma , Wilhelm Weber
IPC分类号： C08F2/34 , C07B63/04 , C07C7/20 , C07C11/04 , C08F2/38 , C08F2/40 , C08F10/00 , C08F210/02 , C07D251/00
摘要： A process for compressing ethylenically unsaturated monomers at a pressure of 200-5000 bar in the absence of a polymerization initiator comprises carrying out compression in the presence of a sterically hindered amine derivative.
摘要翻译： 在不存在聚合引发剂的情况下，在200-5000巴的压力下压制烯属不饱和单体的方法包括在空间位阻胺衍生物的存在下进行压缩。
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公开(公告)号：US5914379A
公开(公告)日：1999-06-22
申请号：US174247
申请日：1998-10-16
申请人： Heinz Friedrich Sutoris , Alexander Aumuller , Andreas Koch , Andreas Deckers , Eckard Schauss , Roger Klimesch , Arend Jouke Kingma , Wilhelm Weber
发明人： Heinz Friedrich Sutoris , Alexander Aumuller , Andreas Koch , Andreas Deckers , Eckard Schauss , Roger Klimesch , Arend Jouke Kingma , Wilhelm Weber
IPC分类号： C08F2/34 , C07B63/04 , C07C7/20 , C07C11/04 , C08F2/38 , C08F2/40 , C08F10/00 , C08F210/02 , C08F10/02
摘要： A process for compressing ethylenically unsaturated monomers at a pressure of 200-5000 bar in the absence of a polymerization initiator comprises carrying out compression in the presence of a sterically hindered amine derivative.
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公开(公告)号：US06350827B1
公开(公告)日：2002-02-26
申请号：US09452451
申请日：1999-12-02
IPC分类号： C08F240
摘要： Disclosed is a process for pressurizing ethylenically unsaturated monomers to 200-5000 bar in the absence of a polymerization initiator, which comprises effecting said pressurizing in the presence of nitroxyl compounds of the formula I where R1 and R2 are singly C1-C4-alkyl or combine with the joining carbon atom to form a 5- or 6-membered saturated hydrocarbon ring, R3 is C1-C4-alkyl, and R4 is hydrogen or C1-C12-alkyl. Also disclosed are a process for preparing copolymers by such pressurization and subsequent polymerization and copolymers obtainable thereby.
摘要翻译： 公开了一种在不存在聚合引发剂的情况下将烯属不饱和单体加压至200-5000巴的方法，其包括在式I的硝酰基化合物存在下进行所述加压，其中R 1和R 2是单C1-C4烷基或与 连接碳原子以形成5-或6-元饱和烃环，R 3为C 1 -C 4 - 烷基，R 4为氢或C 1 -C 12 - 烷基。还公开了通过这种加压和随后的聚合和共聚物制备共聚物的方法 从而获得。
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公开(公告)号：US06949611B2
公开(公告)日：2005-09-27
申请号：US10845396
申请日：2004-05-14
申请人： Lars Wittkowski , Andreas Deckers , Wilhelm Weber , Thomas Dröge , Andrei Gonioukh , Frank-Olaf Mähling
发明人： Lars Wittkowski , Andreas Deckers , Wilhelm Weber , Thomas Dröge , Andrei Gonioukh , Frank-Olaf Mähling
CPC分类号： A61Q1/06 , A61K8/8111 , A61Q1/02 , A61Q1/10 , C08F10/02 , C08F110/02 , C08K5/07 , C08K5/14 , Y10S585/946 , C08F4/36 , C08F2/00
摘要： A process for preparing ethylene polymers by the high-pressure method comprises dissolving one or more free-radical initiators in one or more ketones of the formula I where R1 and R2 are identical or different and are selected from among C1-C6-alkyl and C3-C12-cycloalkyl and R1 and R2 may also be covalently linked to one another to form a 4- to 13-membered ring, prior to the polymerization, compressing the solution, metering it into the polymerization reactor at one or more points and subsequently carrying out the polymerization at from 150 to 380° C. and from 500 to 4500 bar.
摘要翻译： 通过高压法制备乙烯聚合物的方法包括将一种或多种自由基引发剂溶解在式I中的一种或多种酮中，其中R 1和R 2， 相同或不同，并且选自C 1 -C 6 - C 6 - 烷基和C 3 -C 12 - 环烷基和R 1和R 2可以在聚合之前彼此共价连接以形成4-至13-元环，压缩溶液， 在一个或多个点将其计量到聚合反应器中，随后在150至380℃和500至4500巴下进行聚合。
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6.发明授权Nonodorous ethylene homopolymers and copolymers having good mechanical properties 失效具有良好机械性能的非多孔乙烯均聚物和共聚物公开(公告)号：US07709584B2
公开(公告)日：2010-05-04
申请号：US10450774
申请日：2001-12-12
申请人： Frank-Olaf Mähling , Andreas Deckers , Gernot Köhler , Axel Schmitz , Lars Wittkowski , Michael Hoppach
发明人： Frank-Olaf Mähling , Andreas Deckers , Gernot Köhler , Axel Schmitz , Lars Wittkowski , Michael Hoppach
IPC分类号： C08F2/38 , C08F110/02
CPC分类号： C08F210/02 , C08F110/02 , Y10T428/1352 , Y10T428/139 , C08F2/001 , C08F4/28 , C08F2/38 , C08F2500/12
摘要： A process for preparing ethylene homopolymers and copolymers in a tubular reactor having two or more polymerization zones at temperatures of between 150° C. and 350° C. and pressures in the range from 500 to 5000 bar, using oxygen as initiator, which comprises using, as molar mass regulator, one or more aliphatic ketones of the formula I, where the variable R1 is a C1-C6-alkyl or C3-C12-cycloalkyl, ethylene homopolymers and copolymers obtainable therefrom and their user for producing injection-molded products in the cosmetics, medical and food sectors are described.
摘要翻译： 一种在管状反应器中制备乙烯均聚物和共聚物的方法，该管式反应器具有在150℃至350℃之间的温度下具有两个或多个聚合区域，并且使用氧气作为引发剂，其压力范围为500至5000巴，其包括使用 作为摩尔质量调节剂，一种或多种式I的脂族酮，其中可变的R 1是C 1 -C 6 - 烷基或C 3 -C 12 - 环烷基，可从其获得的乙烯均聚物和共聚物及其用于生产注射成型产品的用户 描述了化妆品，医疗和食品行业。
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公开(公告)号：US06815571B1
公开(公告)日：2004-11-09
申请号：US10466117
申请日：2003-07-23
申请人： Lars Wittkowski , Andreas Deckers , Wilhelm Weber , Thomas Dröge , Andrei Gonioukh , Frank-Olaf Mähling
发明人： Lars Wittkowski , Andreas Deckers , Wilhelm Weber , Thomas Dröge , Andrei Gonioukh , Frank-Olaf Mähling
IPC分类号： C07C202
CPC分类号： A61Q1/06 , A61K8/8111 , A61Q1/02 , A61Q1/10 , C08F10/02 , C08F110/02 , C08K5/07 , C08K5/14 , Y10S585/946 , C08F4/36 , C08F2/00
摘要： A process for preparing ethylene polymers by the high-pressure method comprises dissolving one or more free-radical initiators in one or more ketones of the formula I where R1 and R2 are identical or different and are selected from among C1-C6-alkyl and C3-C12-cycloalkyl and R1 and R2 may also be covalently linked to one another to form a 4- to 13-membered ring, prior to the polymerization, compressing the solution, metering it into the polymerization reactor at one or more points and subsequently carrying out the polymerization at from 150 to 380° C. and from 500 to 4500 bar.
摘要翻译： 通过高压法制备乙烯聚合物的方法包括将一种或多种自由基引发剂溶解在一种或多种式I的酮中，其中R 1和R 2相同或不同，并且选自C1- C6-烷基和C3-C12-环烷基，并且R 1和R 2也可以彼此共价连接以形成4-至13-元环，在聚合之前，将溶液压缩，将其计量 聚合反应器在一个或多个点处，随后在150至380℃和500至4500巴下进行聚合反应。
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公开(公告)号：US06649788B2
公开(公告)日：2003-11-18
申请号：US09809252
申请日：2001-03-16
IPC分类号： C07C6952
CPC分类号： C08F110/02 , C08F4/38 , C08F4/36 , C08F2500/23
摘要： In a process for preparing polyethylene waxes at from 200 to 350° C. and pressures in the range from 500 to 4 000 bar using molar mass regulators, a peroxide mixture comprising from 5 to 95% by weight of at least one cyclic peroxide of the formula I, where the radicals R are identical or different and are selected from among alkyl groups and aryl groups, is used as free radical initiator and a molar H2/ethylene ratio of from 1:2 000 to 1:40 000 is employed.
摘要翻译： 在使用摩尔质量调节剂在200-350℃制备聚乙烯蜡和500-4000巴范围内的压力的方法中，过氧化物混合物包含5-95重量％的至少一种环状过氧化物 其中基团R相同或不同并且选自烷基和芳基的式I被用作自由基引发剂，并且使用1：2000至1:40000的摩尔H 2 /乙烯比。
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公开(公告)号：US06596822B1
公开(公告)日：2003-07-22
申请号：US10089749
申请日：2002-04-02
申请人： Michael Witt , Andreas Deckers , Farid Rizk , Kaspar Evertz
发明人： Michael Witt , Andreas Deckers , Farid Rizk , Kaspar Evertz
IPC分类号： C08F234
CPC分类号： C08F6/005 , B01J8/007 , B01J8/10 , B01J8/1872 , C08F210/16 , Y10S526/901 , C08L23/00 , C08F2/34 , C08F2/01 , C08F210/14 , C08F2500/18 , C08F2500/24
摘要： The invention relates to a method and an apparatus for the polymerization of gaseous olefins, in particular of ethylene and at least one &agr;-olefin, in the gas phase in a stirred or fluidized, catalyst-containing polymerization zone (2) and at least one decompression zone (6, 10) downstream of the polymerization zone (2). The mixture of solid (co)polymer and unreacted monomers leaving the polymerization zone (2) flows through a settling zone, in particular in the form of a settling leg (14), before the decompression zone.
摘要翻译： 本发明涉及用于在搅拌或流化的含催化剂的聚合区（2）中的气相中气态烯烃，特别是乙烯和至少一种α-烯烃的聚合的方法和装置，以及至少一种 在聚合区（2）下游的减压区（6,10）。 离开聚合区（2）的固体（共）聚合物和未反应单体的混合物在减压区之前流过沉降区，特别是沉降腿（14）的形式。
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10.发明授权Method for producing Phillips catalysts for polymerizing olefins with better productivity rates in the particle-form process 失效用于在颗粒形成方法中以更好的生产率生产用于聚合烯烃的菲利普斯催化剂的方法公开(公告)号：US06699947B1
公开(公告)日：2004-03-02
申请号：US10070805
申请日：2002-03-11
申请人： Kaspar Evertz , Guido Funk , Paulus de Lange , Peter Kölle , Andreas Deckers
发明人： Kaspar Evertz , Guido Funk , Paulus de Lange , Peter Kölle , Andreas Deckers
IPC分类号： C08F424
CPC分类号： C08F10/02 , B01J23/26 , C08F110/02 , C08F4/24 , C08F2/14 , C08F4/025 , C08F2500/12 , C08F2500/18
摘要： In a process for producing Phillips catalysts in which an oxidic support material is treated in suspension with a chromium salt solution and subsequently, after removing the solvent, calcined in an oxygen-containing atmosphere at above 300° C., the oxidic support material and/or the catalyst after calcination are/is, according to the present invention, comminuted until a mean particle size of
摘要翻译： 在制备菲利普斯催化剂的方法中，其中氧化载体材料用铬盐溶液悬浮处理，随后在除去溶剂之后，在含氧气氛中在300℃以上煅烧，氧化载体材料和/ 或根据本发明的煅烧后的催化剂粉碎直至达到<100μm的平均粒度，并且尺寸<50μm的颗粒的比例为至少30％，优选在该范围内 从40％到80％。 还提供了在通过本发明的方法生产的催化剂存在下，在30至150℃的压力范围内，在环管反应器中制备乙烯的均聚物或共聚物的方法。
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