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    Additives For Detergents And Cleaning Agents
    1.
    发明申请
    Additives For Detergents And Cleaning Agents 审中-公开
    洗涤剂和清洁剂添加剂

    公开(公告)号：US20110098418A1

    公开(公告)日：2011-04-28

    申请号：US12992389

    申请日：2009-05-02

    申请人： Roman Morschhaeuser ,  Frank-Peter Lang ,  Steve Laborda ,  Georg Borchers ,  Michael Seebach ,  Sven Gebhard

    发明人： Roman Morschhaeuser ,  Frank-Peter Lang ,  Steve Laborda ,  Georg Borchers ,  Michael Seebach ,  Sven Gebhard

    IPC分类号： C08G63/672

    CPC分类号： C11D3/3715 ,  C08G63/672 ,  C11D3/0036

    摘要： The invention relates to additives in the form of non-ionic polyesters comprising terephthalic acid, ethylene glycol, polyethylene glycol, optionally propylene glycol, C—C-alkyl-polyalkene glycol ether, and a multifunctional cross-linked monomer. Said polyesters preferably have a flow factor ff of greater than 8, and preferably have a melting point of over 40° C. and molecular weights Mp of 4,000 to 15,000 g/mol. Said polyesters are suitable as soil release components in detergents and cleaning agents.

    摘要翻译： 本发明涉及包含对苯二甲酸，乙二醇，聚乙二醇，任选的丙二醇，C-C-烷基 - 聚烯烃二醇醚和多官能交联单体的非离子聚酯形式的添加剂。 所述聚酯优选具有大于8的流动因子ff，并且优选具有超过40℃的熔点和4,000至15,000g / mol的分子量Mp。 所述聚酯适用于洗涤剂和清洁剂中的去污组分。

    Polyester concentrates having high stability in solution and having a greying-inhibiting effect
    3.
    发明授权
    Polyester concentrates having high stability in solution and having a greying-inhibiting effect 有权
    聚酯浓缩物在溶液中具有高稳定性并具有防灰白效果

    公开(公告)号：US08871703B2

    公开(公告)日：2014-10-28

    申请号：US13512260

    申请日：2010-11-24

    申请人： Roman Morschhaeuser ,  Barbara Duecker ,  Frank-Peter Lang ,  Georg Borchers ,  Peter Naumann

    发明人： Roman Morschhaeuser ,  Barbara Duecker ,  Frank-Peter Lang ,  Georg Borchers ,  Peter Naumann

    IPC分类号： B08B3/04 ,  C08G63/672 ,  C08G63/688 ,  C11D3/00 ,  C11D3/37

    CPC分类号： C11D3/0036 ,  C08G63/672 ,  C08G63/6886 ,  C11D3/3715

    摘要： The invention relates to an aqueous polyester concentrate having a proportion by weight of polyesters of 12 to 60%, wherein the polyesters are obtainable by means of polymerization of the components selected from a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and n is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), where m is an integer of from 1 to 10 and X is hydrogen or an alkali metal ion, and g) optionally one or more cross-linking polyfunctional compounds, provided that at least one of the components b) or f) is present, and provided further that the molar ratio of the components c) 1,2-propylene glycol to d) ethylene glycol is greater than or equal to 1.60.

    摘要翻译： 本发明涉及一种聚酯重量百分比为12至60％的聚酯水性聚酯浓缩物，其中聚酯可通过选自以下成分的聚合获得：a）一种或多种不含无磺基的芳族二羧酸和/或 其盐和/或其酸酐和/或其酯，b）任选的一种或多种含磺基的二羧酸，其盐和/或其酸酐和/或其酯，c）1,2-丙二醇，d） 乙二醇，e）一种或多种式（1）化合物R 1 O（CHR 2 CHR 3 O）n H（1），其中R 1是具有1至22个C原子的直链或支链饱和或不饱和的烷基，R2和R3独立地 是氢或具有1至4个碳原子的烷基，n是1至50的整数，f）任选的一种或多种式（2）的化合物，H（OCH 2 CH 2）m -SO 3 X （2）中，m为1〜10的整数，X为氢或碱金属离子，g）选择 条件是存在至少一种组分b）或f）的一种或多种交联多官能化合物，并进一步提供组分c）1,2-丙二醇与d）乙二醇的摩尔比为 大于或等于1.60。

    Polyester Concentrates Having High Stability In Solution And Having A Greying-Inhibiting Effect
    4.
    发明申请
    Polyester Concentrates Having High Stability In Solution And Having A Greying-Inhibiting Effect 有权
    聚酯聚合物在溶液中具有高稳定性并具有防灰白色效果

    公开(公告)号：US20130200290A1

    公开(公告)日：2013-08-08

    申请号：US13512260

    申请日：2010-11-24

    申请人： Roman Morschhaeuser ,  Barbara Duecker ,  Frank-Peter Lang ,  Georg Borchers ,  Peter Naumann

    发明人： Roman Morschhaeuser ,  Barbara Duecker ,  Frank-Peter Lang ,  Georg Borchers ,  Peter Naumann

    IPC分类号： C11D3/00 ,  C11D3/37

    CPC分类号： C11D3/0036 ,  C08G63/672 ,  C08G63/6886 ,  C11D3/3715

    摘要： The invention relates to an aqueous polyester concentrate having a proportion by weight of polyesters of 12 to 60%, wherein the polyesters are obtainable by means of polymerisation of the components selected from a) one or more sulfo group-free aromatic dicarboxylic acids and/or salts thereof and/or anhydrides thereof and/or esters thereof, b) optionally one or more sulfo group-containing dicarboxylic acids, salts thereof and/or anhydrides thereof and/or esters thereof, c) 1,2-propylene glycol, d) ethylene glycol, e) one or more compounds of the formula (1) R1O(CHR2CHR3O)nH (1), where R1 is a linear or branched, saturated or unsaturated alkyl group having from 1 to 22 C atoms, R2 and R3, independently of one another, are hydrogen or an alkyl group having from 1 to 4 carbon atoms, and n is an integer of from 1 to 50, f) optionally one or more compounds of the formula (2) H—(OCH2CH2)m—SO3X (2), where m is an integer of from 1 to 10 and X is hydrogen or an alkali metal ion, and g) optionally one or more cross-linking polyfunctional compounds, provided that at least one of the components b) or f) is present, and provided further that the molar ratio of the components c) 1,2-propylene glycol to d) ethylene glycol is greater than or equal to 1.60.

    摘要翻译： 本发明涉及一种聚酯重量百分比为12至60％的聚酯水性聚酯浓缩物，其中聚酯可通过选自以下成分的聚合获得：a）一种或多种不含磺基的芳族二羧酸和/或 其盐和/或其酸酐和/或其酯，b）任选的一种或多种含磺基的二羧酸，其盐和/或其酸酐和/或其酯，c）1,2-丙二醇，d） 乙二醇，e）一种或多种式（1）化合物R 1 O（CHR 2 CHR 3 O）n H（1），其中R 1是具有1至22个C原子的直链或支链饱和或不饱和的烷基，R2和R3独立地 是氢或具有1至4个碳原子的烷基，n是1至50的整数，f）任选的一种或多种式（2）的化合物，H（OCH 2 CH 2）m -SO 3 X （2）其中m为1〜10的整数，X为氢或碱金属离子，g）可选项 提供一种或多种交联多官能化合物，条件是存在组分b）或f）中的至少一种，并且进一步提供组分c）1,2-丙二醇与d）乙二醇的摩尔比为 大于或等于1.60。

    Comb polymers and the use thereof in washing and cleaning agents
    5.
    发明授权
    Comb polymers and the use thereof in washing and cleaning agents 有权
    梳形聚合物及其在洗涤和清洁剂中的用途

    公开(公告)号：US09090741B2

    公开(公告)日：2015-07-28

    申请号：US13318632

    申请日：2010-04-30

    申请人： Roman Morschhaeuser ,  Georg Borchers ,  Hans-Juergen Scholz

    发明人： Roman Morschhaeuser ,  Georg Borchers ,  Hans-Juergen Scholz

    IPC分类号： C11D3/37 ,  C08G63/668 ,  C08G63/20 ,  C11D3/00

    CPC分类号： C08G63/668 ,  C08G63/20 ,  C08G2261/128 ,  C11D3/0036 ,  C11D3/37 ,  C11D3/3715 ,  C11D3/3788

    摘要： The invention relates to a comb polymer made of a polymer main chain and polyester side chains linked to said polymer main chain via ester groups, characterized in that (i) the polymer main chain is a polycarbolic acid or a copolymer polycarbolic acid (A), (ii) the polyester side chains comprises the components (B1) C8-dicarbolic acids, optionally sulfonated, (B2) dioles and/or polyolethers having 2 OH groups, and (C) non-ionic terminal groups of the formula -0-(AO)xR, where A means ethylene, propylene, or butylene, x is a number from 1 to 100, and R is a hydrocarbon radical having 1 to 30 C atoms; (iii) the total percent by mass of the polyester side chains B1+B2+C is 80 to 99.9%, relative to the total mass of the comb polymer; (iv) the polyester side chains are obtained from an esterification reaction of the components B1, B2, and C at a mass ratio B1+B2/C of 2:1 to 100:1.

    摘要翻译： 本发明涉及一种由聚合物主链和通过酯基与所述聚合物主链连接的聚酯侧链制成的梳状聚合物，其特征在于（i）聚合物主链为聚碳酸酯或共聚物聚碳酸（A）， （ii）聚酯侧链包含组分（B1）C8-二元酸，任选磺化的（B2）二醇和/或具有2个OH基团的聚烯烃，和（C）式-O-（ AO）xR，其中A表示乙烯，丙烯或丁烯，x为1至100的数，R为具有1至30个C原子的烃基; （iii）相对于梳形聚合物的总质量，聚酯侧链B1 + B2 + C的总质量百分数为80〜99.9％ （iv）聚酯侧链以组分B1，B2和C的质量比B1 + B2 / C为2:1至100:1的酯化反应获得。

    Comb Polymers And The Use Thereof In Washing And Cleaning Agents
    6.
    发明申请
    Comb Polymers And The Use Thereof In Washing And Cleaning Agents 有权
    梳子聚合物及其在洗涤和清洁剂中的应用

    公开(公告)号：US20120065119A1

    公开(公告)日：2012-03-15

    申请号：US13318632

    申请日：2010-04-30

    申请人： Roman Morschhaeuser ,  Georg Borchers ,  Hans-Juergen Scholz

    发明人： Roman Morschhaeuser ,  Georg Borchers ,  Hans-Juergen Scholz

    IPC分类号： C11D3/37 ,  C08G63/183

    CPC分类号： C08G63/668 ,  C08G63/20 ,  C08G2261/128 ,  C11D3/0036 ,  C11D3/37 ,  C11D3/3715 ,  C11D3/3788

    摘要： The invention relates to a comb polymer made of a polymer main chain and polyester side chains linked to said polymer main chain via ester groups, characterized in that (i) the polymer main chain is a polycarbolic acid or a copolymer polycarbolic acid (A), (ii) the polyester side chains comprises the components (B1) C8-dicarbolic acids, optionally sulfonated, (B2) dioles and/or polyolethers having 2 OH groups, and (C) non-ionic terminal groups of the formula -0-(AO)xR, where A means ethylene, propylene, or butylene, x is a number from 1 to 100, and R is a hydrocarbon radical having 1 to 30 C atoms; (iii) the total percent by mass of the polyester side chains B1+B2+C is 80 to 99.9%, relative to the total mass of the comb polymer; (iv) the polyester side chains are obtained from an esterification reaction of the components B1, B2, and C at a mass ratio B1+B2/C of 2:1 to 100:1.

    摘要翻译： 本发明涉及一种由聚合物主链和通过酯基与所述聚合物主链连接的聚酯侧链制成的梳状聚合物，其特征在于（i）聚合物主链为聚碳酸酯或共聚物聚碳酸（A）， （ii）聚酯侧链包含组分（B1）C8-二元酸，任选磺化的（B2）二醇和/或具有2个OH基团的聚烯烃，和（C）式-O-（ AO）xR，其中A表示乙烯，丙烯或丁烯，x为1至100的数，R为具有1至30个C原子的烃基; （iii）相对于梳形聚合物的总质量，聚酯侧链B1 + B2 + C的总质量百分数为80〜99.9％ （iv）聚酯侧链以组分B1，B2和C的质量比B1 + B2 / C为2:1至100:1的酯化反应获得。

    Method for modifying polymers comprising hydroxyl groups
    9.
    发明授权
    Method for modifying polymers comprising hydroxyl groups 有权
    用于改性包含羟基的聚合物的方法

    公开(公告)号：US09243116B2

    公开(公告)日：2016-01-26

    申请号：US13976787

    申请日：2011-12-08

    申请人： Matthias Krull ,  Roman Morschhaeuser ,  Hans Juergen Scholz

    发明人： Matthias Krull ,  Roman Morschhaeuser ,  Hans Juergen Scholz

    IPC分类号： C08F2/42 ,  C08L29/02 ,  C08J3/28 ,  C08F8/14 ,  C08F8/34

    CPC分类号： C08J3/28 ,  C08F8/14 ,  C08F8/34 ,  C08F2810/20 ,  C08F16/06 ,  C08F8/00

    摘要： The invention relates to a method for reacting polymers (A) comprising hydroxyl groups and which have repetitive structural units of general formula (I), wherein D represents a direct bond between the polymer backbone and a hydroxyl group, a C1- to C6-alkene group, a C5- to C12-arylene group, an oxyalkylene group of formula —O—R2—, an ester group of formula —C(O)—O—R2— or an amide group of formula —C(O)—N(R8)R2—, R2 represents a C2- to C10-alkene group, R8 represents hydrogen or an optionally substituted C2- to C10-alkyl group and n represents a number between 3 and 5000, with carboxylic acids B1) of formula (II) or carboxylic acid esters B2) of formula (III) R1—COOH (II) R1—COOR7 (III), wherein R1 represents a hydrocarbon group having 2 to 50 C atoms, and R7 represents a C1C4-alkyl group, in which the polymers (A); comprising the hydroxyl groups are exposed to microwaves in the presence of carboxylic acids of formula (II) or carboxylic acid esters of formula (III) and in the presence of water. The reaction mixture is heated to temperatures over 100° C. by microwave rays.

    摘要翻译： 本发明涉及一种使包含羟基并且具有通式（I）的重复结构单元的聚合物（A）的反应方法，其中D表示聚合物主链和羟基之间的直接键，C1-至C6-烯烃 基团，C5至C12亚芳基，式-O-R2-的氧化烯基，式-C（O）-O-R2-的酯基或式-C（O）-N的酰胺基 （R 8）R 2 - ，R 2表示C 2至C 10烯基，R 8表示氢或任选取代的C 2至C 10 - 烷基，n表示3至5000的数，式（II）的羧酸B1） ）或式（III）的羧酸酯B2）R1-COOH（II）R1-COOR7（III），其中R1表示具有2-50个碳原子的烃基，R7表示C1C4-烷基，其中 聚合物（A）; 在式（II）的羧酸或式（III）的羧酸酯存在下，在水的存在下，将羟基暴露于微波。 通过微波将反应混合物加热至超过100℃。