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公开(公告)号：US4831205A
公开(公告)日：1989-05-16
申请号：US133825
申请日：1987-12-16
IPC分类号： C07C11/02
CPC分类号： C07C11/02
摘要： The separation and recovery of liquid hydrocarbons in a FCC gas plant is removed by integrating therewith an oligomerization reactor which produces liquid hydrocarbons from one of several olefinic streams within the gas plant.
摘要翻译： 通过与FCC天然气厂中的液体烃的分离和回收，通过与气体装置内的几种烯烃流之一产生液态烃的低聚反应器相结合而被除去。
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2.发明授权Multistage system for conversion of lower olefins with reactor quenching means 失效用反应器淬火方法转化低级烯烃的多级体系
公开(公告)号：US4942021A
公开(公告)日：1990-07-17
申请号：US137224
申请日：1987-12-23
摘要： A continuous multistage catalytic conversion system for upgrading lower olefins comprisingfirst adaibatic catalytic bed reactor means containing an acidic zeolite solid catalyst;means for feeding light olefinic gas directly to the first reactor without addition of separate diluent or recycle streams;means for operating the first reactor under olefin partial conversion conditions at elevated temperature to control adiabatic temperature increase;interstage quench means for injecting a liquid coolant directly into first stage effluent for reducing the temperature thereof and protecting downstream catalyst;second catalytic bed reactor means for receiving cooled first stage effluent with injected liquid coolant and further converting the olefins over a metallic zeolite catalyst having a metal ethene oligomerization component;means for cooling and recovering heavier liquid hydrocarbon product from the second reactor effluent; andmeans for recovering liquid coolant from the second effluent for recycle to the interstage quench means.
摘要翻译： 一种用于升级低级烯烃的连续多级催化转化系统，包括含有酸性沸石固体催化剂的第一辅助催化床反应器装置; 用于将轻质烯属气体直接供给到第一反应器而不加入单独的稀释剂或再循环流的装置; 用于在高温下在烯烃部分转化条件下操作第一反应器的装置，以控制绝热温度升高; 级间骤冷装置，用于将液体冷却剂直接注入第一级流出物中以降低其温度并保护下游催化剂; 第二催化床反应器装置，用于接收具有注入的液体冷却剂的冷却的第一级流出物，并进一步转化具有金属乙烯低聚组分的金属沸石催化剂的烯烃; 用于从第二反应器流出物冷却和回收较重液体烃产物的装置; 以及用于从第二流出物回收液体冷却剂以再循环到级间骤冷装置的装置。
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公开(公告)号：US4740645A
公开(公告)日：1988-04-26
申请号：US903915
申请日：1986-09-05
CPC分类号： C10G50/00 , C07C11/02 , C07C2/12 , C07C2529/46 , Y02P20/52
摘要： A continuous multi-stage catalytic process for converting ethene-rich lower olefinic feedstock to heavier liquid hydrocarbon product, comprising the steps ofcontacting ethene-rich feedstock at elevated temperature and moderate pressure in a primary stage reaction zone with a first catalyst comprising shape selective medium pore zeolite to convert at least a portion of the lower olefinic components to intermediate olefinic hydrocarbons;cooling primary stage reaction effluent by introducing a stream of cold water sufficient to reduce the primary stage effluent to second stage reaction temperature; andcontacting unreacted ethene and at least a portion of the intermediate olefinic hydrocarbons from the primary stage with nickel-containing shape selective medium pore zeolite oligomerization component at elevated temperature to provide a heavier hydrocarbon effluent stream comprising gasoline and/or distillate range hydrocarbons.
摘要翻译： 一种用于将含富烯烃的较低级烯烃原料转化为较重液体烃产物的连续多级催化方法，包括以下步骤：在初级阶段反应区中将升温和中等压力的富含烯烃的原料与包含形状选择介质 孔沸石将至少一部分低级烯烃组分转化成中间体烯烃; 通过引入足以将初级阶段流出物降至第二阶段反应温度的冷水流来冷却初级反应流出物; 并在升高的温度下使未反应的乙烯和至少一部分来自初级阶段的中间体烯烃与含镍形状选择性中孔沸石低聚组分接触，以提供包含汽油和/或馏出物范围烃的较重烃流出物流。
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公开(公告)号：US4746761A
公开(公告)日：1988-05-24
申请号：US65775
申请日：1987-07-02
CPC分类号： C07C41/06 , C07C1/20 , C07C9/16 , C10G29/205 , C10G3/49 , C10L1/023 , C07C2529/40 , C10G2300/4081 , C10G2400/02 , C10G2400/20 , C10G2400/22 , Y02P20/52 , Y02P30/20 , Y02P30/42
摘要： A multistage process for producing isoalkyl ethers from lower aliphatic oxygenate feedstock, such as methanol. Feedstock is catalytically converted in a primary catalyst stage at elevated temperature in contact with zeolite catalyst to predominantly C.sub.2 -C.sub.7 lower olefins comprising isobutylene and isoamylene, by-product water and a minor amount of C.sub.8.sup.+ hydrocarbons, followed by fractionation of the C.sub.2 -C.sub.7 olefins to recover a C.sub.2 -C.sub.3 -rich recycle stream for further catalytic conversion in the primary stage. C.sub.4 -C.sub.7 olefins are passed to a second catalytic etherification stage for reaction of isoalkenes with methanol to produce methyl tertiary-butyl ether, methyl isoamylether and higher isoalkyl ethers. The second stage effluent may be fractionated to recover an ether product, C.sub.5.sup.+ hydrocarbon liquid product, and unreacted butenes. Advantageously, the unreacted butenes are further reacted with isoparaffin in a third catalytic stage under acid catalysis alkylation conditions, and fractionated to recover C.sub.6.sup.+ alkylate liquid, liquid hydrocarbon product. The ethers may be blended with at least one C.sub.6.sup.+ hydrocarbon to produce high octane gasoline.
摘要翻译： 用于从低级脂族含氧化合物原料如甲醇生产异烷基醚的多阶段方法。 原料在初级催化剂阶段在升高的温度下与沸石催化剂催化转化成主要是包含异丁烯和异戊烯，副产物水和少量C 8+烃的C 2 -C 7低级烯烃，然后分馏C2-C7烯烃 以回收在初级阶段进一步催化转化的富含C2-3的再循环物流。 将C4-C7烯烃通入第二催化醚化阶段，以使异烯烃与甲醇反应，生成甲基叔丁基醚，甲基异戊醚和高级异烷基醚。 第二级流出物可以分馏以回收醚产物，C5 +烃液体产物和未反应的丁烯。 有利地，在酸催化烷基化条件下，在第三催化阶段中，未反应的丁烯进一步与异链烷烃反应，并分馏以回收C6 +烷基化液体液体烃产物。 醚可以与至少一种C6 +烃混合以产生高辛烷值汽油。
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5.发明授权Process for converting methanol to alkyl ethers, gasoline, distillate and alkylate liquid hydrocarbons 失效将甲醇转化为烷基醚，汽油，馏出物和烷基化液体烃的方法
公开(公告)号：US4684757A
公开(公告)日：1987-08-04
申请号：US886996
申请日：1986-07-18
摘要： A multistage process for producing ethers from lower aliphatic oxygenate feedstock, such as methanol. Feedstock is catalytically converted in a primary catalyst stage at elevated temperature in contact with zeolite catalyst to predominantly C.sub.2 -C.sub.5 lower olefins comprising isobutylene and isoamylene, by-product water and a minor amount of C.sub.6.sup.+ hydrocarbons, followed by fractionation of the C.sub.2 -C.sub.5 olefins to recover a C.sub.2 -C.sub.3 -rich recycle stream for further catalytic conversion in the primary stage. C.sub.4 -C.sub.5 olefins are passed to a second catalytic etherification stage for reaction of isoalkenes with methanol to produce methyl tertiary-butyl ether and methyl isoamylether. The second stage effluent may be fractionated to recover an ether product, C.sub.5.sup.+ hydrocarbon liquid product, and unreacted butenes. Advantageously, the unreacted butenes are further reacted wtih isoparaffin in a third catalytic stage under acid catalysis alkylation conditions, and fractionated to recover C.sub.6.sup.+ alkylate liquid, liquid hydrocarbon product. The ethers may be blended with at least one C.sub.6.sup.+ hydrocarbon to produce high octane gasoline.
摘要翻译： 用于从低级脂肪族含氧化合物原料如甲醇生产醚的多阶段方法。 原料在初级催化剂阶段在升高的温度下与沸石催化剂催化转化成主要是包含异丁烯和异戊烯，副产物水和少量C 6 +烃的C 2 -C 5低级烯烃，然后分馏C2-C5烯烃 以回收在初级阶段进一步催化转化的富含C2-3的再循环物流。 将C4-C5烯烃通入第二催化醚化阶段，以使异烯烃与甲醇反应生成甲基叔丁基醚和甲基异戊醚。 第二级流出物可以分馏以回收醚产物，C5 +烃液体产物和未反应的丁烯。 有利地，未反应的丁烯在酸性催化烷基化条件下在第三催化阶段进一步与异链烷烃反应，并分馏以回收C6 +烷基化物液体液体烃产物。 醚可以与至少一种C6 +烃混合以产生高辛烷值汽油。
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6.发明授权
公开(公告)号：US4849186A
公开(公告)日：1989-07-18
申请号：US935374
申请日：1986-11-26
CPC分类号： C07C2/12 , C10G29/16 , C07C2529/40 , F02B3/06 , Y10S203/06
摘要： An oligomerization system is provided for upgrading lower olefins to distillate hydrocarbons, especially useful as high quality jet or diesel fuels. Thye olefinic feedstock is reacted over a shape selective acid zeolite, such as ZSM-5, to oligomerize feedstock olefins and further convert recycled hydrocarbons. Reactor effluent is fractionated to recover a light-middle distillate range product stream and to obtain gasoline and heavy hydrocarbon streams for recycle.
摘要翻译： 提供了一种低聚体系，用于将低级烯烃升级成馏分烃，特别适用于高质量的喷气或柴油燃料。 烯烃原料在形状选择性酸性沸石（如ZSM-5）上反应，使原料烯烃低聚并进一步转化回收的烃。 将反应器流出物分馏以回收轻 - 中馏分范围的产物流并获得用于再循环的汽油和重烃流。
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公开(公告)号：US4634798A
公开(公告)日：1987-01-06
申请号：US779369
申请日：1985-09-23
申请人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
发明人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
CPC分类号： C07C2/62 , C07C1/20 , C10G3/49 , C10L1/06 , C07C2527/1206 , C07C2529/06 , C07C2529/40 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/20 , Y02P30/42
摘要： Alkylate is produced by catalytically converting oxygenate feedstock, such as methanol, to lower olefins comprising C.sub.2 -C.sub.4 olefins. Ethene is separated by interstage sorption of C.sub.3 + components and an isoparaffin is alkylated with C.sub.3 -C.sub.4 olefins.The improved technique comprises fractionating an olefinic feedstream containing ethene and C.sub.3 + olefinic components by contacting the olefinic feedstream in a sorption zone with a liquid hydrocarbon sorbent to selectively sorb C.sub.3 + components; reacting C.sub.3 + olefins with excess isoparaffin in a catalytic alkylation reactor to produce C.sub.7 + alkylate hydrocarbons; fractionating the alkylation reactor effluent to provide a liquid hydrocarbon fraction rich in C.sub.4 + isoparaffin for recycle to the sorption zone as lean sorbent; and recovering C.sub.7 + alkylate product from the process.
摘要翻译： 烷基化物通过将含氧化合物原料如甲醇催化转化成包含C 2 -C 4烯烃的低级烯烃来制备。 乙烯通过C3 +组分的级间吸附分离，异链烷烃用C 3 -C 4烯烃烷基化。 改进的技术包括通过使吸附区中的烯烃进料流与液体烃吸附剂接触以选择性吸附C3 +组分来分馏含有乙烯和C3 +烯烃组分的烯烃进料流; 在催化烷基化反应器中使C3 +烯烃与过量的异链烷烃反应生成C7 +烷基化烃; 分馏烷基化反应器流出物以提供富含C 4 +异链烷烃的液体烃馏分，作为贫吸附剂再循环至吸附区; 并从该过程中回收C7 +烷基化产物。
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公开(公告)号：US4633028A
公开(公告)日：1986-12-30
申请号：US779367
申请日：1985-09-23
申请人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
发明人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
CPC分类号： C10L1/06 , C07C9/16 , C10G3/49 , C07C2527/1206 , C07C2529/06 , C07C2529/40 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2400/02 , C10G2400/20
摘要： Alkylate is produced by catalytically converting oxygenate feedstock, such as methanol, to lower olefins comprising C.sub.2 -C.sub.4 olefins. Ethene is separated by interstage sorption of C.sub.3 + components and an isoparaffin is alkylated with C.sub.3 -C.sub.4 olefins derived from sorbate.The improved technique comprises fractionating an olefinic feedstream containing ethene and C.sub.3 + olefinic components by contacting the olefinic feedstream in a sorption zone with a liquid hydrocarbon sorbent to selectively sorb C.sub.3 + components; reacting C.sub.3 + olefins with excess isoparaffin in a catalytic alkylation reactor to produce C.sub.7 + alkylate hydrocarbons; fractionating the alkylation reactor effluent to provide a liquid hydrocarbon fraction rich in C.sub.7 +, alkylate for recycle to the sorption zone as lean sorbent; and recovering C.sub.7 + alkylate product and C.sub.5 + gasoline from the process.
摘要翻译： 烷基化物通过将含氧化合物原料如甲醇催化转化成包含C 2 -C 4烯烃的低级烯烃来制备。 乙烯通过C3 +组分的级间吸附分离，异链烷烃用来自山梨酸酯的C3-C4烯烃烷基化。 改进的技术包括通过使吸附区中的烯烃进料流与液体烃吸附剂接触以选择性吸附C3 +组分来分馏含有乙烯和C3 +烯烃组分的烯烃进料流; 在催化烷基化反应器中使C3 +烯烃与过量的异链烷烃反应生成C7 +烷基化烃; 分馏烷基化反应器流出物以提供富含C 7+的烷烃馏分，作为贫吸附剂再循环到吸附区; 并从该过程中回收C7 +烷基化物产物和C5 +汽油。
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9.发明授权Integrated production of gasoline from light olefins in a fluid cracking process plant 失效在流体裂解过程工厂从轻质烯烃综合生产汽油
公开(公告)号：US4831203A
公开(公告)日：1989-05-16
申请号：US133771
申请日：1987-12-16
申请人： Hartley Owen , Samuel A. Tabak
发明人： Hartley Owen , Samuel A. Tabak
IPC分类号： C10G57/02
CPC分类号： C10G57/02
摘要： Separation and recovery of liquid hydrocarbons in a FCC gas plant is improved by integrating therewith a catalytic bed oligomerization reactor which produces predominantly olefinic liquid hydrocarbons from at least one olefinic stream within the gas plant.
摘要翻译： 通过与催化床低聚反应器整合来改善FCC气体装置中的液体烃的分离和回收，催化床低聚反应器主要产生来自气体装置内的至少一个烯烃的烯烃液体烃。
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公开(公告)号：US4504693A
公开(公告)日：1985-03-12
申请号：US616379
申请日：1984-06-01
申请人： Samuel A. Tabak , Bernard S. Wright , Hartley Owen
发明人： Samuel A. Tabak , Bernard S. Wright , Hartley Owen
CPC分类号： C07C2/00 , C10G50/00 , C07C2529/40
摘要： A catalytic process for converting an olefinic feedstock comprising lower olefin to heavier hydrocarbon product comprising the steps of:contacting the feedstock and a recycled hydrocarbon with shape-selective zeolite oligomerization catalyst in catalytic reaction zone at elevated temperature and pressure to provide a heavier hydrocarbon effluent stream comprising heavy, intermediate and light hydrocarbons;flashing the effluent stream between the reaction zone and a phase separation zone by reducing pressure of the effluent stream, thereby producing a heavy liquid stream rich in heavy hydrocarbons and a flashed effluent vapor stream containing lighter hydrocarbons;separating and recovering a recycle stream rich in intermediate range hydrocarbons from the separation zone and pressurizing the recycle stream for recycle to the reactor inlet;further fractionating the heavy liquid stream and flashed effluent vapor from the phase separation zone in first distillation tower to remove light hydrocarbons therefrom; andrecovering substantially all of the heavy hydrocarbons produced in the reaction zone in a fractionated liquid product stream.
摘要翻译： 用于将包含低级烯烃的烯烃原料转化成较重烃产物的催化方法，包括以下步骤：在催化反应区中在升高的温度和压力下使原料和再循环烃与形状选择性沸石低聚催化剂接触，以提供较重的烃流出物流 包括重质，中间和轻质烃类; 通过减少流出物流的压力使反应区和相分离区之间的流出物流闪烁，从而产生富含重质烃的重质液体物流和含有较轻质烃的闪蒸流出物蒸气流; 从分离区分离和回收富含中间范围烃的循环物流，并加压再循环流再循环到反应器入口; 进一步分馏重质液体物流，并从第一蒸馏塔中的相分离区闪蒸流出的蒸汽以从其中除去轻烃; 并且在分馏的液体产物流中基本上回收在反应区中产生的所有重质烃。
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