公开(公告)号：US20130194670A1

公开(公告)日：2013-08-01

申请号：US13713990

申请日：2012-12-13

Applicant: Guardian Industries Corp.

Inventor： Liang LIANG ,  Chris LOVELL ,  Richard BLACKER ,  Mark A. LEWIS

IPC: B05D5/06 ,  G02B1/11

CPC classification number: B05D5/063 ,  B82Y30/00 ,  C03C1/008 ,  C03C17/007 ,  C03C17/3417 ,  C03C2217/213 ,  C03C2217/73 ,  C03C2217/732 ,  C03C2217/91 ,  C03C2218/113 ,  C03C2218/116 ,  C23C18/1212 ,  C23C18/1225 ,  C23C18/1245 ,  C23C18/1254 ,  C23C18/127 ,  C23C18/1283 ,  G02B1/11 ,  G02B2207/107 ,  G02B2207/109

Abstract: Certain examples relate to a method of making an antireflective (AR) coating supported by a glass substrate. The anti-reflection coating may include porous metal oxide(s) and/or silica, and may be produced using a sol-gel process. The pores may be formed and/or tuned in each layer respectively in such a manner that the coating ultimately may comprise a porous matrix, graded with respect to porosity. The gradient in porosity may be achieved by forming first and second layers using one or more of (a) nanoparticles of different shapes and/or sizes, (b) porous nanoparticles having varying pore sizes, and/or (c) compounds/materials of various types, sizes, and shapes that may ultimately be removed from the coating post-deposition (e.g., carbon structures, micelles, etc., removed through combustion, calcination, ozonolysis, solvent-extraction, etc.), leaving spaces where the removed materials were previously located.

Abstract translation: 某些实例涉及制​​备由玻璃基底支撑的抗反射（AR）涂层的方法。 防反射涂层可以包括多孔金属氧化物和/或二氧化硅，并且可以使用溶胶 - 凝胶法制备。 可以以这样的方式分别在各层中形成和/或调整孔，使得涂层最终可以包括相对于多孔性分级的多孔基质。 孔隙度的梯度可以通过使用一种或多种（a）不同形状和/或尺寸的纳米颗粒形成第一层和第二层来实现，（b）具有不同孔径的多孔纳米颗粒和/或（c） 可能最终从涂层后沉积（例如，通过燃烧，煅烧，臭氧分解，溶剂萃取等除去的碳结构，胶束等）中除去的各种类型，尺寸和形状，留下被移除的空间 材料以前位于。

公开(公告)号：US20130194668A1

公开(公告)日：2013-08-01

申请号：US13713811

申请日：2012-12-13

Applicant: GUARDIAN INDUSTRIES CORP.

Inventor： Liang LIANG ,  Richard BLACKER ,  Mark A. LEWIS ,  Nikhil KALYANKAR ,  Minh Huu LE

IPC: C03C17/22 ,  G02B1/11

CPC classification number: C03C17/22 ,  B82Y20/00 ,  B82Y40/00 ,  C03C1/008 ,  C03C17/3417 ,  C03C2217/213 ,  C03C2217/425 ,  C03C2217/452 ,  C03C2217/465 ,  C03C2217/478 ,  C03C2217/73 ,  C03C2217/732 ,  C03C2217/91 ,  C03C2218/113 ,  C03C2218/116 ,  G02B1/115 ,  G02B2207/107 ,  Y10S977/773

Abstract: Certain examples relate to a method of making an antireflective (AR) coating supported by a glass substrate. The anti-reflection coating may include porous metal oxide(s) and/or silica, and may be produced using a sol-gel process. The pores may be formed and/or tuned in each layer respectively in such a manner that the coating ultimately may comprise a porous matrix, graded with respect to porosity. The gradient in porosity may be achieved by forming first and second layers using one or more of (a) nanoparticles of different shapes and/or sizes, (b) porous nanoparticles having varying pore sizes, and/or (c) compounds/materials of various types, sizes, and shapes that may ultimately be removed from the coating post-deposition (e.g., carbon structures, micelles, etc., removed through combustion, calcination, ozonolysis, solvent-extraction, etc.), leaving spaces where the removed materials were previously located.

Abstract translation: 某些实例涉及制​​备由玻璃基底支撑的抗反射（AR）涂层的方法。 抗反射涂层可以包括多孔金属氧化物和/或二氧化硅，并且可以使用溶胶 - 凝胶法制备。 可以以这样的方式分别在各层中形成和/或调整孔，使得涂层最终可以包括相对于多孔性分级的多孔基质。 孔隙度的梯度可以通过使用一种或多种（a）不同形状和/或尺寸的纳米颗粒形成第一层和第二层来实现，（b）具有不同孔径的多孔纳米颗粒和/或（c） 可能最终从涂层后沉积中除去的各种类型，尺寸和形状（例如，通过燃烧，煅烧，臭氧分解，溶剂萃取等除去的碳结构，胶束等），留下被除去的空间 材料以前位于。

公开(公告)号：US20140272126A1

公开(公告)日：2014-09-18

申请号：US13826288

申请日：2013-03-14

Applicant: GUARDIAN INDUSTRIES CORP.

Inventor： Liang LIANG ,  Richard Blacker ,  Nikhil D. Kalyankar ,  Scott JewHurst

IPC: G02B1/11

CPC classification number: G02B1/111 ,  C03C17/245 ,  C03C2217/732 ,  C03C2218/113

Abstract: Anti-reflection (AR) coating for a glass substrate is prepared by blending at least two different sols to form a coating sol which is used to coat a substrate such as a transparent glass substrate. In certain example embodiments, a method includes forming a first sol formulation including a colloidal solution having a tri-alkoxysilane based binder; forming a second sol formulation including a colloidal solution having a tetra-alkoxysilane based binder; blending the first and second sol formulations to form a coating sol formulation; coating at least a portion of said coating sol formulation onto the glass substrate to form a coating; and heating (e.g., for curing and/or annealing) the glass substrate and the coating thereon. Anti-reflection glasses show improved mechanical strength and higher transmittances (e.g., Tqe % gain).

Abstract translation: 通过混合至少两种不同的溶胶来制备用于玻璃基板的抗反射（AR）涂层，以形成用于涂覆诸如透明玻璃基板的基板的涂层溶胶。 在某些示例性实施方案中，一种方法包括形成包含具有三烷氧基硅烷基粘合剂的胶体溶液的第一溶胶制剂; 形成包含具有四烷氧基硅烷基粘合剂的胶体溶液的第二溶胶制剂; 混合第一和第二溶胶制剂以形成涂料溶胶制剂; 将所述涂料溶胶制剂的至少一部分涂覆到所述玻璃基板上以形成涂层; 以及加热（例如，用于固化和/或退火）玻璃基板和其上的涂层。 抗反射眼镜显示出改进的机械强度和更高的透光率（例如，Tqe％增益）。

公开(公告)号：US20140272125A1

公开(公告)日：2014-09-18

申请号：US13826011

申请日：2013-03-14

Applicant: GUARDIAN INDUSTRIES CORP

Inventor： Liang LIANG ,  Richard Blacker ,  Nikhil D. Kalyankar ,  Scott Jewhurst

IPC: C09D5/00

CPC classification number: C09D5/006 ,  C03C17/002 ,  C03C17/007 ,  C03C17/30 ,  C03C2217/213 ,  C03C2217/425 ,  C03C2217/478 ,  C03C2217/732 ,  C03C2217/78 ,  C03C2218/113

Abstract: A method of making a coated article including an anti-reflection coating on a glass substrate, the method comprising: mixing at least a tri-alkoxysilane based binder and a tetra-alkoxysilane based binder with at least silica based nanoparticles and a solvent in forming a coating sol formulation; aging the coating sol formulation at least about two weeks so as to provide an aged coating sol formulation; coating at least a portion of said aged coating sol formulation onto the glass substrate to form a coating; and heating said glass substrate and said coating. Anti-reflection (AR) glasses show improved mechanical strength and higher transmittances (e.g., Tqe % gain).

Abstract translation: 一种制造包括在玻璃基板上的抗反射涂层的涂覆制品的方法，所述方法包括：至少将三烷氧基硅烷基粘合剂和四烷氧基硅烷基粘合剂与至少二氧化硅基纳米颗粒和溶剂混合形成 涂料溶胶配方; 使涂料溶胶制剂老化至少约两周，以提供老化的涂料溶胶制剂; 将所述老化涂层溶胶制剂的至少一部分涂布到玻璃基板上以形成涂层; 并加热所述玻璃基底和所述涂层。 抗反射（AR）眼镜显示出改善的机械强度和更高的透射率（例如，Tqe％增益）。

公开(公告)号：US20160340234A1

公开(公告)日：2016-11-24

申请号：US15166297

申请日：2016-05-27

Applicant: Guardian Industries Corp.

Inventor： Liang LIANG

IPC: C03C17/30 ,  C09D5/08 ,  C09D5/00 ,  C03C17/00 ,  G02B1/11

CPC classification number: C03C17/30 ,  C03C17/007 ,  C03C17/009 ,  C03C2217/732 ,  C03C2218/113 ,  C09D5/006 ,  C09D5/08 ,  G02B1/11 ,  G02B1/111

Abstract: Certain example embodiments relate to methods of making anti-corrosion anti-reflection (ACAR) films, and/or associated coated articles. The methods may involve forming the reaction product of a hydrolysis and/or a condensation reaction of at least one hybrid alkoxide selected from the group consisting of Si(OR)4—Al(s-OBu)3, Si(OR)4—B(OBu)3 and Si(OR)4 and Zr(OBu)4, where R is a CH2CH3 group, s-OBu is sec-butoxide and OBu is n-butoxide. The solution optionally may be blended and/or mixed with silicon nanoparticles and/or siloxanes. A Tqe % gain of about 3.2% and/or refractive index of 1.5 or less is/are possible in certain example embodiments.

Abstract translation: 某些示例性实施例涉及制备抗腐蚀抗反射（ACAR）膜和/或相关涂层制品的方法。 所述方法可以包括形成选自Si（OR）4-Al（s-OBu）3，Si（OR）4-B）的至少一种杂化醇盐的水解和/或缩合反应的反应产物 （OBu）3和Si（OR）4和Zr（OBu）4，其中R是CH 2 CH 3基团，s-OBu是仲丁醇盐，OBu是正丁醇盐。 溶液任选地可以与硅纳米颗粒和/或硅氧烷共混和/或混合。 在某些示例性实施例中，可以有约3.2％的Tqe％增益和/或折射率为1.5或更小的折射率。

公开(公告)号：US20140356633A1

公开(公告)日：2014-12-04

申请号：US13904421

申请日：2013-05-29

Applicant: Guardian Industries Corp.

Inventor： Liang LIANG

IPC: C03C17/30

CPC classification number: C03C17/30 ,  C03C17/007 ,  C03C17/009 ,  C03C2217/732 ,  C03C2218/113 ,  C09D5/006 ,  C09D5/08 ,  G02B1/11 ,  G02B1/111

Abstract: Certain example embodiments relate to methods of making anti-corrosion anti-reflection (ACAR) films, and/or associated coated articles. The methods may involve forming the reaction product of a hydrolysis and/or a condensation reaction of at least one hybrid alkoxide selected from the group consisting of Si(OR)4—Al(s-OBu)3, Si(OR)4—B(OBu)3 and Si(OR)4 and Zr(OBu)4, where R is a CH2CH3 group, s-OBu is sec-butoxide and OBu is n-butoxide. The solution optionally may be blended and/or mixed with silicon nanoparticles and/or siloxanes. A Tqe % gain of about 3.2% and/or refractive index of 1.5 or less is/are possible in certain example embodiments.

Abstract translation: 某些示例性实施例涉及制备抗腐蚀抗反射（ACAR）膜和/或相关涂层制品的方法。 所述方法可以包括形成选自Si（OR）4-Al（s-OBu）3，Si（OR）4-B）的至少一种杂化醇盐的水解和/或缩合反应的反应产物 （OBu）3和Si（OR）4和Zr（OBu）4，其中R是CH 2 CH 3基团，s-OBu是仲丁醇盐，OBu是正丁醇盐。 溶液任选地可以与硅纳米颗粒和/或硅氧烷共混和/或混合。 在某些示例性实施例中，可以有约3.2％的Tqe％增益和/或折射率为1.5或更小的折射率。

公开(公告)号：US20160096769A1

公开(公告)日：2016-04-07

申请号：US14873290

申请日：2015-10-02

Applicant: Guardian Industries Corp.

Inventor： Liang LIANG

IPC: C03C17/30 ,  C09D183/04

CPC classification number: C03C17/30 ,  C03C17/3663 ,  C03C2217/29 ,  C03C2217/76 ,  C03C2217/77 ,  C03C2218/113 ,  C03C2218/116 ,  C09D183/02 ,  C09D183/04 ,  C09D183/06 ,  C09D183/08 ,  G02B1/11 ,  Y10T428/24355

Abstract: Certain example embodiments relate to a coated article including a coating formed from a sol that has hydrophobic surface properties. The sol may include a mixture of at least two alkylsiloxane chemicals, with the sol potentially being aged for a certain comparatively short amount of time before being wet-applied to a major substrate surface. The application process may also undergo a certain comparatively short curing process to help provide hydrophobic surface properties. The hydrophobic surface properties help provide anti-soiling functions that are advantageous in a variety of applications including, for example, solar mirror applications.

Abstract translation: 某些示例性实施方案涉及包含由具有疏水表面性质的溶胶形成的涂层的涂覆制品。 溶胶可以包括至少两种烷基硅氧烷化学品的混合物，其中溶胶潜在地被老化一定相对较短的时间，然后湿施加到主要的基材表面。 施加过程也可能经历一定的较短的固化过程以帮助提供疏水表面性质。 疏水表面性质有助于提供在各种应用中有利的防污功能，包括例如太阳镜应用。

公开(公告)号：US20140186613A1

公开(公告)日：2014-07-03

申请号：US13727767

申请日：2012-12-27

Applicant: GUARDIAN INDUSTRIES CORP.

Inventor： Liang LIANG ,  Richard BLACKER

IPC: C09D5/00 ,  C03C17/32

CPC classification number: C09D5/006 ,  C03C17/007 ,  C03C2217/45 ,  C03C2217/477 ,  C03C2217/71 ,  C03C2217/732 ,  C03C2218/113 ,  C09D1/00 ,  Y10T428/256

Abstract: Methods of making titania coatings having self-cleaning properties, and associated articles are provided. In certain example instances, a substrate supports a layer comprising titanium dioxide. The substrate may support multiple layers. After curing, the resulting coating may reduce the occurrence of fouling.

Abstract translation: 提供了具有自清洁性能的二氧化钛涂层的制造方法以及相关的制品。 在某些示例中，衬底支撑包含二氧化钛的层。 衬底可以支撑多层。 固化后，所得到的涂层可能减少结垢的发生。

公开(公告)号：US20140154466A1

公开(公告)日：2014-06-05

申请号：US13692160

申请日：2012-12-03

Applicant: GUARDIAN INDUSTRIES CORP.

Inventor： Liang LIANG

IPC: C09D183/08 ,  C09D183/06 ,  C09D183/02

CPC classification number: C03C17/30 ,  C03C17/3663 ,  C03C2217/29 ,  C03C2217/76 ,  C03C2217/77 ,  C03C2218/113 ,  C03C2218/116 ,  C09D183/02 ,  C09D183/04 ,  C09D183/06 ,  C09D183/08 ,  G02B1/11 ,  Y10T428/24355

Abstract: Certain example embodiments relate to a coated article including a coating formed from a sol that has hydrophobic surface properties. The sol may include a mixture of at least two alkylsiloxane chemicals, with the sol potentially being aged for a certain comparatively short amount of time before being wet-applied to a major substrate surface. The application process may also undergo a certain comparatively short curing process to help provide hydrophobic surface properties. The hydrophobic surface properties help provide anti-soiling functions that are advantageous in a variety of applications including, for example, solar mirror applications.

Abstract translation: 某些示例性实施方案涉及包含由具有疏水表面性质的溶胶形成的涂层的涂覆制品。 溶胶可以包括至少两种烷基硅氧烷化学品的混合物，其中溶胶潜在地被老化一定相对较短的时间，然后湿施加到主要的基材表面。 施加过程也可能经历一定的较短的固化过程以帮助提供疏水表面性质。 疏水表面性质有助于提供在各种应用中有利的防污功能，包括例如太阳镜应用。