摘要:
The present invention relates to an electrochemical cell comprising a solid electrolyte conductive for O.sup.2- anions in contact with an anode and a cathode of identical or different composition, the electrolyte solid being comprised of a composition derived from Bi.sub.4 V.sub.2 O.sub.11 of which at least one of the cationic constituent elements is substituted by at least one substituting element chosen such that the gamma phase structural type of Bi.sub.4 V.sub.2 O.sub.11 is maintained, as well as the equilibrium of charges, at least one of the anode or the cathode including two parts, a first part being of a mixed electronic and ionic conductive material in contact with the solid electrolyte, the second part being an electronic conductive material superposed on the first part. The invention equally relates to the use of the electrochemical cell with a view towards the separation or the extraction of oxygen.
摘要:
The present invention relates to an electrochemical cell comprising a solid electrolyte which conducts O.sup.2- anions in contact with an anode and a cathode of identical or different composition, the solid electrolyte being comprised of a composition derived from Bi.sub.4 V.sub.2 O.sub.11 of which at least one of the constituent cationic elements is substituted by at least one substituting element such that the gamma phase structural type of Bi.sub.4 V.sub.2 O.sub.11 is maintained as well as the equilibrium of charges, at least one of the anode or of the cathode is a material containing at least one element of substitution of said composition derived from Bi.sub.4 V.sub.2 O.sub.11, that element being in a metallic or cationic state. The invention equally relates to the use of the electrochemical cell with a view towards the separation or extraction of oxygen.
摘要:
Process for separating oxygen from a gas mixture containing it employs a solid-electrolyte electrochemical cell, where the cell includes a homogeneous structure of one or more BIMEVOX derivatives, with dynamic electrodes created "in situ" that are reversible and self-adaptive, and at least two current collectors.
摘要:
A process for preparing a solid composite electrolyte comprising at least one compound of the BIMEVOX family is provided. The process comprises at least one step of preparing a mixture of one or more compounds of the BIMEVOX family with one or more chemically inert compounds, at least one step of compacting the mixture obtained, and at least one sintering step during which the temperature reached, over a nonzero time interval, has a value greater than the optimum sintering temperature for the compound of the BIMEVOX family.
摘要:
Provided is a device for treating a food product in order to reduce or eliminate the detrimental effects of the presence of oxygen which is in contact with the external surface of the product. The device includes a vat provided with a hood, containing a food product whose free surface is in contact with the atmospheric air, a solid electrolyte membrane, each face of the membrane being connected to an electrode, each electrode being connected to a current generator, a heater for making the electrolyte operate at the desired working temperature, a pump for discharging oxygen extracted, by the solid electrolyte, from the atmospheric air present above the food product, in a pipe, a pump for circulating the atmosphere to be treated, an oxygen analyzer for measuring the oxygen level in the gas atmosphere above the food product, a control unit for modifying the operation of the solid electrolyte as a function of the oxygen level and the gas atmosphere to be treated and the recirculation rate of the atmosphere and, optionally, a cooling unit.
摘要:
A novel compound which can be used in the field of separation and purification of gases is disclosed. The compound can be incorporated into a silica gel incorporating polyazacycloalkane structural units for separating a predetermined gas from a mixture of gases. The mixture of gases is brought into contact with a metallated hybrid gel under conditions which make possible the absorption of the gas to be separated, followed by a phase of desorption of the attached gas, and the recovery of the gas.
摘要:
A control device for operation of a system for treating a surface of a solid running substrate by dielectric-barrier electrical discharge in a controlled gaseous atmosphere, comprising (A) a system which includes (i) a treatment device through which a substrate to be treated runs at a speed, (ii) the system is connected to the treatment device for supplying the treatment device with a flow of gas, (iii) the system is connected to the treatment device for supplying the treatment device with electrical power in order to produce the electrical discharge and (iv) the system sucking out the gas, (B) a data processing unit capable of receiving, as input, a datum regarding the speed at which the substrate is running through the treatment device, the data processing unit further comprising an output side connected to the system for controlling the electrical power supply system, in order to regulate the flow of gas delivered by the or each of the gas supply system and/or the electrical power delivered by the electrical power supply system to the device as a function of the speed at which the substrate is running through the treatment device, so as to obtain a surface treatment of the substrate with an equivalent quality whatever the speed at which the substrate is running through the treatment.
摘要:
The invention concerns a method for preparing polyazacycloalkanes immobilised on a silica gel from a polyazacycloalkane of formula (A) in which: R1 and R2 represent a hydrogen atom, an alkyl radical, or a [hetero(aryl)]alkyl radical; W1, W2 and W3 represent a radical of formula (B): —[(CT1T2)n—[N(R3)]p—(CT3T4)m]l— such as defined in the description; R3 represents a hydrogen atom, an alkyl radical or a [hetero(aryl)]alkyl radical, provided that the polyazacycloalkane ring of the compound of formula (A) comprises not more than 30 cyclic carbon atoms, and not more than 6 cyclic nitrogen atoms. The invention is characterised in that: (a) the compound of formula (A) is reacted with a compound of formula (C): Z—R4—Si(X1)(X2)(X3), such as defined in the description to form a compound of formula (D); (b) said compound of formula (D) is condensed on the silanol sites of a silica gel to form the immobilised polyazacycloalkane of formula (E); and (c) some ethanol sites having not reacted are, if required, protected by Z′, a group protecting the hydroxyl function. The invention is useful for separating oxygen from air.
摘要:
A control device for operation of a system for treating a surface of a solid running substrate by dielectric-barrier electrical discharge in a controlled gaseous atmosphere, comprising (A) a system which includes (i) a treatment device through which a substrate to be treated runs at a speed, (ii) the system is connected to the treatment device for supplying the treatment device with gas, (iii) the system is connected to the device for supplying the treatment device with electrical power in order to produce the electrical discharge and (iv) the system for sucking out the gas (B) a data processing unit designed to receive, as input, a datum regarding the speed at which the substrate is running through the treatment device, the data processing unit being connected, on the output side, to the gas supply system, to the electrical power supply system and to the gas suction system, in order: (a) upon starting the treatment device and when the running speed of the substrate is greater than a predetermined speed, to carry out the following actions: initiate operation of the suction system, initiate operation of the gas supply system, initiate operation of the electrical power supply system, and (b) upon stopping the device and/or when the running speed of the substrate drops to a level below a predetermined speed to carry out the following actions: interrupt operation of the electrical power supply system, interrupt operation of the gas supply system, and interrupt operation of the suction system.