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1.发明授权Electrochemical cell and its use for the separation and the electrochemical extraction of oxygen 失效电化学电池及其用于分离和电化学提取的氧气
公开(公告)号：US5582710A
公开(公告)日：1996-12-10
申请号：US244034
申请日：1994-05-16
CPC分类号： G01N27/4073 , B01D53/326 , C01B13/0233 , C01B2210/0046 , C01B2210/0051 , C01B2210/0062 , C01B2210/0071 , C01B2210/0075 , C01B2210/0082
摘要： The present invention relates to an electrochemical cell comprising a solid electrolyte conductive for O.sup.2- anions in contact with an anode and a cathode of identical or different composition, the electrolyte solid being comprised of a composition derived from Bi.sub.4 V.sub.2 O.sub.11 of which at least one of the cationic constituent elements is substituted by at least one substituting element chosen such that the gamma phase structural type of Bi.sub.4 V.sub.2 O.sub.11 is maintained, as well as the equilibrium of charges, at least one of the anode or the cathode including two parts, a first part being of a mixed electronic and ionic conductive material in contact with the solid electrolyte, the second part being an electronic conductive material superposed on the first part. The invention equally relates to the use of the electrochemical cell with a view towards the separation or the extraction of oxygen.
摘要翻译： PCT No.PCT / FR93 / 00872 Sec。 371日期1994年5月16日 102（e）日期1994年5月16日PCT提交1992年9月13日PCT公布。 出版物WO94 / 06545 日期：1994年3月31日本发明涉及一种电化学电池，其包含用于与阳极和阴极相接触或相同或不同组成的阴离子导电的固体电解质，电解质固体由衍生自Bi4V2O11的组合物组成， 阳离子组成元素中的至少一个被至少一个选择为使得维持Bi4V2O11的γ相结构类型以及电荷的平衡的取代元素所取代，阳极或阴极中的至少一个包括两个部分，一个 第一部分是与固体电解质接触的混合电子和离子导电材料，第二部分是重叠在第一部分上的电子导电材料。 本发明同样涉及电化学电池用于分离或提取氧气的用途。
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2.发明授权Electrochemical cell and its use in the separation or electrochemical extraction of oxygen 失效电化学电池及其在氧气分离或电化学提取中的应用
公开(公告)号：US5573655A
公开(公告)日：1996-11-12
申请号：US244030
申请日：1994-07-28
IPC分类号： B01D53/32 , C01B13/02 , C01G31/00 , C25B9/00 , C25B9/08 , C25B11/06 , G01N27/407 , H01M8/12 , C25B1/02
CPC分类号： C01B13/0233 , B01D53/326 , G01N27/4073 , H01M8/1266 , C01B2210/0046 , C01B2210/0051 , C01B2210/0062 , C01B2210/0071 , C01B2210/0075 , C01B2210/0082 , Y02E60/525 , Y02P70/56
摘要： The present invention relates to an electrochemical cell comprising a solid electrolyte which conducts O.sup.2- anions in contact with an anode and a cathode of identical or different composition, the solid electrolyte being comprised of a composition derived from Bi.sub.4 V.sub.2 O.sub.11 of which at least one of the constituent cationic elements is substituted by at least one substituting element such that the gamma phase structural type of Bi.sub.4 V.sub.2 O.sub.11 is maintained as well as the equilibrium of charges, at least one of the anode or of the cathode is a material containing at least one element of substitution of said composition derived from Bi.sub.4 V.sub.2 O.sub.11, that element being in a metallic or cationic state. The invention equally relates to the use of the electrochemical cell with a view towards the separation or extraction of oxygen.
摘要翻译： PCT No.PCT / FR93 / 00871 Sec。 371日期：1994年7月28日 102（e）日期1994年7月28日PCT提交1993年9月13日PCT公布。 公开号WO94 / 06544 日期：1994年3月31日本发明涉及一种电化学电池，其包含固体电解质，其导电与阳极和阴极具有相同或不同组成的接触，所述固体电解质由衍生自Bi4V2O11的组合物组成， 至少一种构成的阳离子元素被至少一个取代元素取代，使得维持Bi 4 V 2 O 11的γ相结构类型以及电荷的平衡，阳极或阴极中的至少一个是至少含有 衍生自Bi4V2O11的所述组合物的一种取代元素是该元素处于金属或阳离子状态。 本发明同样涉及电化学电池用于分离或提取氧气的用途。
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3.发明授权Polyazacycloalkanes, tri-, tetra- or penta-azamacrocyclic complexes, processs for the production of these substituted or unsubstituted polyazacycloalkanes grafted to a support and uses of polyazacycloalkanes and the aforementioned complexes 失效多氮杂环烷烃，三，四或五氮杂十环配合物，用于制备接枝到载体上的这些取代或未取代的多氮杂环烷烃的方法和多氮杂环烷烃和上述络合物的用途
公开(公告)号：US5891574A
公开(公告)日：1999-04-06
申请号：US646330
申请日：1997-04-25
CPC分类号： G21F9/12 , B01D53/1493 , B01J45/00 , C08F12/32 , B01D2253/106 , B01D2259/4583 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： The invention relates to polyazacycloalkanes having 3, 4 or 5 nitrogen atoms, tri-, tetra- or penta-azamacrocyclic transition metal complexes and processes for the production of said polyazacycloalkanes.The object of the invention is to form polyazacycloalkanes able to trap metal cations and in particular U, Pu, Am, Ce, Eu, Al, Gd, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Sn, Au, Mg or Pb or complexes able to trap in particular oxygen in a gaseous mixture.The invention more particularly applies to the treatment of liquid effluents from nuclear power stations.
摘要翻译： 本发明涉及具有3,4或5个氮原子的多氮杂环烷烃，三 - ，四 - 或五 - 氮杂十八烷基过渡金属络合物和用于生产所述多氮杂环烷烃的方法。 本发明的目的是形成能够捕获金属阳离子，特别是U，Pu，Am，Ce，Eu，Al，Gd，Cr，Mn，Fe，Co，Ni，Cu，Zn，Ag，Cd，Sn的多氮杂环烷烃 ，Au，Mg或Pb或能够在气体混合物中捕获特别是氧的络合物。 本发明更特别适用于从核电站处理液体流出物。
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公开(公告)号：US4978802A
公开(公告)日：1990-12-18
申请号：US286788
申请日：1988-12-20
申请人： Philippe Campo , Panayotis Cocolios , Paul Dognin , Henry Ledon
发明人： Philippe Campo , Panayotis Cocolios , Paul Dognin , Henry Ledon
CPC分类号： C07C47/565 , C07C45/36
摘要： Aromatic aldehydes are produced by oxidation with oxygen of a para-cresol derivative in a solvent, in the presence of a base and a catalytic amount of a cobalt compound. The catalyst is a chelated complex of cobalt with a rigid structure that is slightly oxidizable selected from the group consisting of bis-(4-methylpyridine isoindolinato)cobalt(II) acetate, phthalocyaninatocobalt(II), and sulfophthalocyaninanatocobalt(II). The process is particularly suited to the production of p-hydroxy benzaldehydes.
摘要翻译： 通过在溶剂中，在碱和催化量的钴化合物的存在下，用对甲酚衍生物的氧气进行氧化来制备芳族醛。 催化剂是具有刚性结构的钴的螯合络合物，其可以选自双 - （4-甲基吡啶异吲哚啉）乙酸钴（II），酞菁钴（II）和磺基酞菁纳多钴（II）。 该方法特别适用于生产对羟基苯甲醛。
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5.发明授权Process for treatment of gaseous effluents containing sulfur dioxide with oxygen 失效用氧气处理含二氧化硫的气体流出物的方法
公开(公告)号：US4943422A
公开(公告)日：1990-07-24
申请号：US275135
申请日：1988-09-12
申请人： Henry Ledon , Jean Louise , Panayotis Cocolios
发明人： Henry Ledon , Jean Louise , Panayotis Cocolios
IPC分类号： B01D53/50 , B01D53/77 , C01B17/775
CPC分类号： C01B17/775 , B01D53/501 , B01D53/507
摘要： A method and apparatus are provided for treating gaseous effluents containing sulfur dioxide. Sulfur dioxide is oxidized by oxygen in a concentrated sulfuric acid medium in the presence of a catalyst comprising electrooxidized salts of Mn+2. The gaseous effluents are converted to directly usable sulfuric acid.
摘要翻译： PCT No.PCT / FR88 / 00104 Sec。 371日期：1988年9月12日 102（e）日期1988年9月12日PCT提交1988年2月24日PCT公布。 出版物WO88 / 06483 日期为1988年9月7日。提供了一种用于处理含有二氧化硫的气体流出物的方法和装置。 在含有Mn + 2的电氧化盐的催化剂存在下，在浓硫酸介质中，二氧化硫被氧氧化。 将气态废水转化成可直接使用的硫酸。
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6.发明申请公开(公告)号：US20100035496A1
公开(公告)日：2010-02-11
申请号：US12522996
申请日：2007-10-26
申请人： Panayotis Cocolios , Frederic Noel
发明人： Panayotis Cocolios , Frederic Noel
CPC分类号： B29C59/12 , B29C59/14 , C08J7/123 , D06M10/02 , D06M10/08 , D06M2200/50 , Y10T442/2861
摘要： The invention relates to a method for processing the surface of polymer substrates, during which the substrate is subjected to a dielectric-barrier electric discharge of the filament type in a gaseous processing mixture containing at least a carrier gas and an active gas and under a pressure substantially equal to the atmospheric pressure, characterized in that the active gas is selected from the group including a mono-unsaturated or poly-unsaturated linear or branched hydrocarbon preferably containing 2 to 10 carbon atoms, more preferably 2 to 5 carbon atoms and even more preferably 2 or 3 carbon atoms, the residual oxygen content of the processing mixture being lower than 250 ppm, preferably lower than 100 ppm, and more preferably lower than 50 ppm.
摘要翻译： 本发明涉及一种用于加工聚合物基材表面的方法，在该方法中，基材经受至少含有载气和活性气体并在压力下的气态处理混合物中的长丝型电介质阻挡放电 基本上等于大气压，其特征在于活性气体选自包含优选含有2至10个碳原子，更优选2至5个碳原子的单不饱和或多不饱和直链或支链烃基，甚至更优选的是 2或3个碳原子，处理混合物的残余氧含量低于250ppm，优选低于100ppm，更优选低于50ppm。
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7.发明授权POLYAZACYCLOALKANES, TRI-, TETRA- OR PENTA-AZAMACROCYCLIC COMPLEXES, PROCESSES FOR THE PRODUCTION OF THESE SUBSTITUTED OR UNSUBSTITUTED POLYAZACYCLOALKANES GRAFTED TO A SUPPORT AND USES OF POLYAZACYCLOALKANES AND THE AFOREMENTIONED COMPLEXES 失效聚氮杂环戊烷，三异氰酸酯，四环戊基或三甲基环烷基复合物，生产这些取代或未取代的聚氨基甲酸酯的方法，用于支持和使用聚氨基甲酸酯和已制备的复合物公开(公告)号：US06410143B1
公开(公告)日：2002-06-25
申请号：US09667506
申请日：2000-09-22
IPC分类号： B32B516
CPC分类号： G21F9/12 , B01D53/1493 , B01D2253/106 , B01D2259/4583 , B01J45/00 , C08F12/32 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： The invention relates to polyazacycloalkanes having 3, 4 or 5 nitrogen atoms, tri-, tetra- or penta-azamacrocyclic transition metal complexes and processes for the production of said polyazacycloalkanes. The object of the invention is to form polyazacycloalkanes able to trap metal cations and in particular U, Pu, Am, Ce, Eu, Al, Gd, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Sn, Au, Mg or Pb or complexes able to trap in particular oxygen in a gaseous mixture. The invention more particularly applies to the treatment of liquid effluents from nuclear power stations.
摘要翻译： 本发明涉及具有3,4或5个氮原子的多氮杂环烷烃，三，四或五氮杂十八烷基过渡金属络合物以及用于制备所述多氮杂环烷烃的方法。本发明的目的是形成能够捕获金属阳离子的多氮杂环烷烃， 特别是U，Pu，Am，Ce，Eu，Al，Gd，Cr，Mn，Fe，Co，Ni，Cu，Zn，Ag，Cd，Sn，Au，Mg或Pb或能够特别吸留氧的络合物 气体混合物。本发明更特别适用于处理来自核电站的液体流出物。
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公开(公告)号：US5425857A
公开(公告)日：1995-06-20
申请号：US305835
申请日：1994-09-14
CPC分类号： C25B1/00
摘要： The invention relates to a process for the electrolytic generation of arsine from an electrochemical cell provided with a cathode supplied with H.sup.+ and AsO.sub.2.sup.- ions where two concurrent reactions take place producing arsine and gaseous hydrogen respectively, and an anode where a reaction producing H.sup.+ ions takes place, the ratio of the H.sup.+ /As concentrations at the cathode being controlled and kept constant.
摘要翻译： 本发明涉及一种从电化学电池电解生成胂的方法，该电化学电池具有提供有H +和AsO 2 - 离子的阴极，其中分别产生两个同时发生的反应产生胂和气态氢，以及产生H +离子的反应的阳极 在阴极处的H + / As浓度的比例被控制并保持恒定。
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9.发明授权公开(公告)号：US06878857B1
公开(公告)日：2005-04-12
申请号：US09744920
申请日：1999-08-02
IPC分类号： A61F13/511 , A61F5/44 , A61F13/15 , A61F13/49 , A61F13/53 , A61L15/42 , D06M10/02 , D06M10/06 , D06M10/08 , D06M11/00 , D06M11/77 , D06M11/78 , D06M11/79 , D06M13/507 , D06M23/00 , A61F13/20
CPC分类号： A61F13/53 , D06M10/025 , D06M10/06 , D06M10/08 , D06M11/77 , D06M11/78 , D06M11/79 , D06M13/507 , D06M23/005
摘要： A fibrous structure is described for use in hygienic articles such as diapers, sanitary napkins, incontinence guards, wipes and the like, having one or more polar, silicon containing compounds bound to at least one portion of the surface of the fibrous structure by interaction between the surface and the silicon containing compounds. The fibrous structure exhibits a predetermined degree of hydrophilicity and adhesion properties which are substantially unaffected by wetting of the fibrous structure. Absorbent, hygienic and textile articles comprising such a fibrous structure are also described.
摘要翻译： 描述了纤维结构用于诸如尿布，卫生巾，失禁防护件，擦拭物等卫生制品中的卫生制品，其具有一个或多个极性的含硅化合物，通过在纤维结构表面的至少一部分之间的相互作用结合 表面和含硅化合物。 纤维结构表现出预定程度的亲水性和粘合性能，其基本上不受纤维结构的润湿的影响。 还描述了包含这种纤维结构的吸收剂，卫生和纺织制品。
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10.发明授权Polyazacycloalkanes, tri, tetra- or penta-azamacrocyclic complexes, processes for the production of these substituted or unsubstituted polyazacycloalkanes grafted to a support and uses of polyazacycloalkanes and the aforementioned complexes 失效多氮杂环烷烃，三，四或五氮杂十环配合物，用于制备接枝到载体上的这些取代或未取代的多氮杂环烷烃的方法和多氮杂环烷烃和上述络合物的用途公开(公告)号：US06265483B1
公开(公告)日：2001-07-24
申请号：US09190144
申请日：1998-11-12
IPC分类号： C07D25502
CPC分类号： G21F9/12 , B01D53/1493 , B01D2253/106 , B01D2259/4583 , B01J45/00 , C08F12/32 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： The invention relates to polyazacycloalkanes having 3, 4 or 5 nitrogen atoms, tri-, tetra- or penta-azamacrocyclic transition metal complexes and processes for the production of said polyazacycloalkanes. The object of the invention is to form polyazacycloalkanes able to trap metal cations and in particular U, Pu, Am, Ce, Eu, Al, Gd, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Sn, Au, Mg or Pb or complexes able to trap in particular oxygen in a gaseous mixture. The invention more particularly applies to the treatment of liquid effluents from nuclear power stations.
摘要翻译： 本发明涉及具有3,4或5个氮原子的多氮杂环烷烃，三，四或五氮杂十八烷基过渡金属络合物以及用于制备所述多氮杂环烷烃的方法。本发明的目的是形成能够捕获金属阳离子的多氮杂环烷烃， 特别是U，Pu，Am，Ce，Eu，Al，Gd，Cr，Mn，Fe，Co，Ni，Cu，Zn，Ag，Cd，Sn，Au，Mg或Pb或能够特别吸留氧的络合物 气体混合物。本发明更特别适用于处理来自核电站的液体流出物。
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