公开(公告)号：US20080269365A1

公开(公告)日：2008-10-30

申请号：US11739750

申请日：2007-04-25

申请人： Gary Dale Andrew ,  John Elton Dewhurst ,  Mark Leo Listemann ,  Goran Zarkov ,  Yuedong Zhang

发明人： Gary Dale Andrew ,  John Elton Dewhurst ,  Mark Leo Listemann ,  Goran Zarkov ,  Yuedong Zhang

IPC分类号： C08G18/22 ,  C08G18/18

CPC分类号： C08G18/3825 ,  C08G18/10 ,  C08G18/1808 ,  C08G2101/0008 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08K5/3445 ,  C08G18/664 ,  C08L75/04

摘要： A composition for making a polyurethane foam includes a fugitive tertiary amine urethane catalyst and amidoamine and/or imidazoline property enhancing additives. The inclusion of one or more of these property enhancing additives serves to reduce or eliminate physical property and surface deterioration of polyurethane foams made at reduced density.

摘要翻译： 用于制备聚氨酯泡沫的组合物包括短暂的叔胺氨基甲酸酯催化剂和酰胺胺和/或咪唑啉性质增强添加剂。 包含一种或多种这些性能增强添加剂用于减少或消除以较低密度制成的聚氨酯泡沫的物理性能和表面变质。

公开(公告)号：US08618014B2

公开(公告)日：2013-12-31

申请号：US13547756

申请日：2012-07-12

申请人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

发明人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

IPC分类号： B01J27/24

CPC分类号： C08G18/7671 ,  C08G18/092 ,  C08G18/10 ,  C08G18/161 ,  C08G2101/0083 ,  C08G18/664

摘要： Catalyst compositions for use in forming polyurethane products include a gelling catalyst, a trimerization catalyst, and a cure accelerator. The gelling catalyst is a tertiary amine, mono(tertiary amino) urea, bis(tertiary amino) urea, or a combination of any of these. Any known trimerization catalyst may be used. The cure accelerator may be a diol having at least one primary hydroxyl group, and having from five to 17 chain backbone atoms chosen from carbon, oxygen, or both between the hydroxyl groups, provided that at least five of the backbone atoms are carbon. Alternatively or in addition, the cure accelerator may be a polyol having three or more hydroxyl groups, at least two of which are primary, and having molecular weights between 90 g/mole and 400 g/mole. Delayed initiation of the polyurethane-forming reaction and/or reduced demold time for producing the polyurethane part can be obtained by using these catalyst compositions.

摘要翻译： 用于形成聚氨酯产品的催化剂组合物包括胶凝催化剂，三聚催化剂和固化促进剂。 胶凝催化剂是叔胺，单（叔氨基）脲，双（叔氨基）脲或这些中的任何一种的组合。 可以使用任何已知的三聚催化剂。 固化促进剂可以是具有至少一个伯羟基的二醇，并且在羟基之间具有5至17个选自碳，氧或两者的链骨架原子，条件是至少五个骨架原子是碳。 或者或另外，固化促进剂可以是具有三个或更多个羟基的多元醇，其中至少两个是伯的，分子量在90g / mol至400g / mol之间。 通过使用这些催化剂组合物可以获得聚氨酯形成反应的延迟起始和/或用于制备聚氨酯部分的脱模时间的减少。

公开(公告)号：US6046249A

公开(公告)日：2000-04-04

申请号：US338105

申请日：1999-06-23

申请人： James Douglas Tobias ,  Julia Renae Bennett ,  Gary Dale Andrew ,  John Elton Dewhurst ,  Robert G. Petrella

发明人： James Douglas Tobias ,  Julia Renae Bennett ,  Gary Dale Andrew ,  John Elton Dewhurst ,  Robert G. Petrella

IPC分类号： C08G18/00 ,  C08G18/18 ,  C08G18/34 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G18/65 ,  C08G18/66

CPC分类号： C08G18/341 ,  C08G18/6552 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083

摘要： A method for preparing a polyurethane flexible or rigid foam by reacting an organic polyisocyanate with a polyol in the presence of urethane catalyst, water as a blowing agent, optionally a silicone surfactant, and a cell opener characterized in that the cell opener comprises the reaction product of a C1-C20 hydrocarbyl group-containing organic acid anhydride and a substituted phenol which may be alkoxylated or an alkoxylated primary alcohol, optionally reacted in the presence of a tertiary amine urethane catalyst.

摘要翻译： 一种通过有机多异氰酸酯与聚氨酯催化剂，水作为发泡剂，任选的硅氧烷表面活性剂的存在下反应制备聚氨酯软质或刚性泡沫的方法，以及开孔剂，其特征在于开孔剂包括反应产物 含有C1-C20烃基的有机酸酐和可以被烷氧基化的取代苯酚或烷氧基化伯醇，任选在叔胺氨基甲酸酯催化剂存在下反应。

公开(公告)号：US20120277093A1

公开(公告)日：2012-11-01

申请号：US13547756

申请日：2012-07-12

申请人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

发明人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

IPC分类号： C08F4/00 ,  C08F4/08

CPC分类号： C08G18/7671 ,  C08G18/092 ,  C08G18/10 ,  C08G18/161 ,  C08G2101/0083 ,  C08G18/664

摘要： Catalyst compositions for use in forming polyurethane products include a gelling catalyst, a trimerization catalyst, and a cure accelerator. The gelling catalyst is a tertiary amine, mono(tertiary amino) urea, bis(tertiary amino) urea, or a combination of any of these. Any known trimerization catalyst may be used. The cure accelerator may be a diol having at least one primary hydroxyl group, and having from five to 17 chain backbone atoms chosen from carbon, oxygen, or both between the hydroxyl groups, provided that at least five of the backbone atoms are carbon. Alternatively or in addition, the cure accelerator may be a polyol having three or more hydroxyl groups, at least two of which are primary, and having molecular weights between 90 g/mole and 400 g/mole. Delayed initiation of the polyurethane-forming reaction and/or reduced demold time for producing the polyurethane part can be obtained by using these catalyst compositions.

摘要翻译： 用于形成聚氨酯产品的催化剂组合物包括胶凝催化剂，三聚催化剂和固化促进剂。 胶凝催化剂是叔胺，单（叔氨基）脲，双（叔氨基）脲或这些中的任何一种的组合。 可以使用任何已知的三聚催化剂。 固化促进剂可以是具有至少一个伯羟基的二醇，并且在羟基之间具有5至17个选自碳，氧或两者的链骨架原子，条件是至少五个骨架原子是碳。 或者或另外，固化促进剂可以是具有三个或更多个羟基的多元醇，其中至少两个是伯的，分子量在90g / mol至400g / mol之间。 通过使用这些催化剂组合物可以获得聚氨酯形成反应的延迟起始和/或用于制备聚氨酯部分的脱模时间的减少。

公开(公告)号：US08258198B2

公开(公告)日：2012-09-04

申请号：US11131179

申请日：2005-05-18

申请人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

发明人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

IPC分类号： B01J31/02

CPC分类号： C08G18/7671 ,  C08G18/092 ,  C08G18/10 ,  C08G18/161 ,  C08G2101/0083 ,  C08G18/664

摘要： Catalyst compositions for use in forming polyurethane products include a gelling catalyst, a trimerization catalyst, and a cure accelerator. The gelling catalyst is a tertiary amine, mono(tertiary amino) urea, bis(tertiary amino) urea, or a combination of any of these. Any known trimerization catalyst may be used. The cure accelerator may be a diol having at least one primary hydroxyl group, and having from five to 17 chain backbone atoms chosen from carbon, oxygen, or both between the hydroxyl groups, provided that at least five of the backbone atoms are carbon. Alternatively or in addition, the cure accelerator may be a polyol having three or more hydroxyl groups, at least two of which are primary, and having molecular weights between 90 g/mole and 400 g/mole. Delayed initiation of the polyurethane-forming reaction and/or reduced demold time for producing the polyurethane part can be obtained by using these catalyst compositions.

摘要翻译： 用于形成聚氨酯产品的催化剂组合物包括胶凝催化剂，三聚催化剂和固化促进剂。 胶凝催化剂是叔胺，单（叔氨基）脲，双（叔氨基）脲或这些中的任何一种的组合。 可以使用任何已知的三聚催化剂。 固化促进剂可以是具有至少一个伯羟基的二醇，并且在羟基之间具有5至17个选自碳，氧或两者的链骨架原子，条件是至少五个骨架原子是碳。 或者或另外，固化促进剂可以是具有三个或更多个羟基的多元醇，其中至少两个是伯的，分子量在90g / mol至400g / mol之间。 通过使用这些催化剂组合物可以获得聚氨酯形成反应的延迟起始和/或用于制备聚氨酯部分的脱模时间的减少。

公开(公告)号：US09290604B2

公开(公告)日：2016-03-22

申请号：US13206545

申请日：2011-08-10

申请人： Gary Dale Andrew ,  Jean Louise Vincent ,  Timothy J. Miller ,  Goran Zarkov

发明人： Gary Dale Andrew ,  Jean Louise Vincent ,  Timothy J. Miller ,  Goran Zarkov

IPC分类号： C08J9/00 ,  C08G18/06 ,  C08G18/28 ,  C08G18/10 ,  C08G18/12 ,  C08G101/00

CPC分类号： C08G18/283 ,  C08G18/10 ,  C08G18/12 ,  C08G18/2835 ,  C08G2101/00 ,  C08G2101/005

摘要： Alkylethoxylate alcohols or mixtures of alkyl alcohol ethoxylate with an average HLB value between 10 and 15 as compatibilizers for water blown polyurethane foam formulations that are substantially free of nonylphenol ethoxylates are disclosed. The HLB is defined as the mass percent of average structure of the compatibilizer that is hydrophilic, divided by 5. The compatibilizer is mixed into the B-side of the polyurethane formulation. The B-side of the spray foam formulations comprise polyol, water, amine catalyst, and the compatibilizer of the invention such that the water is present at about 2% to about 30% by weight of the B-side formulation, and the compatibilizer is present at about 1% to about 30% by weight of the B-side formulation. The B-side of the formulation may further comprise metal catalysts, flame retardants, silicone surfactants, cell openers, antioxidants, as well as other additives.

摘要翻译： 公开了烷基乙氧基化物醇或烷基醇乙氧基化物的混合物，其平均HLB值为10至15，作为基本上不含壬基酚乙氧基化物的水性聚氨酯泡沫制剂的增容剂。 HLB定义为亲水性增加剂的平均结构质量百分比除以5.将增容剂混入聚氨酯配方的B侧。 喷雾泡沫制剂的B侧包含多元醇，水，胺催化剂和本发明的相容剂，使得水以B侧制剂的约2重量％至约30重量％存在，增容剂为 以B-side制剂的约1％至约30％重量存在。 制剂的B侧还可以包含金属催化剂，阻燃剂，硅氧烷表面活性剂，开孔剂，抗氧化剂以及其它添加剂。

公开(公告)号：US07183330B2

公开(公告)日：2007-02-27

申请号：US10736042

申请日：2003-12-15

申请人： Wayne Robert Furlan ,  Mark Leo Listemann ,  Joan Sudbury-Holtschlag ,  Thomas John Markley ,  Gary Dale Andrew

发明人： Wayne Robert Furlan ,  Mark Leo Listemann ,  Joan Sudbury-Holtschlag ,  Thomas John Markley ,  Gary Dale Andrew

IPC分类号： C08J9/14 ,  C08G77/46

CPC分类号： C08J9/141 ,  C08G18/7664 ,  C08G2101/0025 ,  C08G2101/005 ,  C08J9/0061 ,  C08J9/149 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2205/10 ,  C08J2375/04 ,  C08J2483/00

摘要： A method for making a rigid polyurethane foam by reacting a polyisocyanate and a polyol in the presence of a urethane catalyst, a blowing agent and a silicone surfactant characterized by employing a blowing agent comprising a C4 or C5 hydrocarbon, or mixtures thereof, with an average molecular weight of ≦72 g/mole and a boiling point in the range of 27.8 to 50° C., and a silicone surfactant comprising a polyether-polysiloxane copolymer represented by the following formula: (CH3)3—Si—O—(Si(CH3)2—O)x—(Si(CH3)(R)O)y—Si(CH3)3 where R=(CH2)3—O—(—CH2—CH2—O)a—(CH2—CH(CH3)—O)b—R″, and where R″ is H, (CH2)zCH3, or C(O)CH3; x+y+2 is 60–130; x/y is 5–14; z is 0–4; the total surfactant molecular weight, based on the formula, is 7000–30,000 g/mole, the wt % siloxane in the surfactant is 32–70 wt %, the blend average molecular weight (BAMW) of the polyether portion is 450–1000 g/mole, and the mole % of ethylene oxide in the polyether portion is 70–100 mole %.

公开(公告)号：US20080293841A1

公开(公告)日：2008-11-27

申请号：US11753633

申请日：2007-05-25

申请人： Gary Dale Andrew ,  Juan Jesus Burdeniuc ,  Goran Zarkov

发明人： Gary Dale Andrew ,  Juan Jesus Burdeniuc ,  Goran Zarkov

IPC分类号： C08G18/72 ,  C08G18/82

CPC分类号： C08G18/18 ,  C08G18/161 ,  C08G18/1808 ,  C08G18/546

摘要： An isocyanate reactive composition for making a polyurethane foam includes a tertiary amine urethane catalyst comprising a di(C1-C4)alkyl fatty alkyl amine and a polyester polyol. The use of one or more of fatty alkyl tertiary amine serves to reduce hydrolysis of the polyester polyol in the isocyanate reactive composition.

摘要翻译： 用于制备聚氨酯泡沫的异氰酸酯反应性组合物包括含有二（C 1 -C 4）烷基脂肪烷基胺和聚酯多元醇的叔胺氨基甲酸酯催化剂。 使用一种或多种脂肪烷基叔胺用于减少异氰酸酯反应性组合物中聚酯多元醇的水解。

公开(公告)号：US08637584B2

公开(公告)日：2014-01-28

申请号：US11753633

申请日：2007-05-25

申请人： Gary Dale Andrew ,  Juan Jesus Burdeniuc ,  Goran Zarkov

发明人： Gary Dale Andrew ,  Juan Jesus Burdeniuc ,  Goran Zarkov

IPC分类号： C08G18/18

CPC分类号： C08G18/18 ,  C08G18/161 ,  C08G18/1808 ,  C08G18/546

摘要： An isocyanate reactive composition for making a polyurethane foam includes a tertiary amine urethane catalyst comprising a di(C1-C4)alkyl fatty alkyl amine and a polyester polyol. The use of one or more of fatty alkyl tertiary amine serves to reduce hydrolysis of the polyester polyol in the isocyanate reactive composition.

摘要翻译： 用于制备聚氨酯泡沫的异氰酸酯反应性组合物包括含有二（C 1 -C 4）烷基脂肪烷基胺和聚酯多元醇的叔胺氨基甲酸酯催化剂。 使用一种或多种脂肪烷基叔胺用于减少异氰酸酯反应性组合物中聚酯多元醇的水解。

公开(公告)号：US20120202903A1

公开(公告)日：2012-08-09

申请号：US13206545

申请日：2011-08-10

申请人： Gary Dale Andrew ,  Jean Louise Vincent ,  Timothy J. Miller ,  Goran Zarkov

发明人： Gary Dale Andrew ,  Jean Louise Vincent ,  Timothy J. Miller ,  Goran Zarkov

IPC分类号： C08J9/00 ,  C08G18/06

CPC分类号： C08G18/283 ,  C08G18/10 ,  C08G18/12 ,  C08G18/2835 ,  C08G2101/00 ,  C08G2101/005

摘要： Alkylethoxylate alcohols or mixtures of alkyl alcohol ethoxylate with an average HLB value between 10 and 15 as compatibilizers for water blown polyurethane foam formulations that are substantially free of nonylphenol ethoxylates are disclosed. The HLB is defined as the mass percent of average structure of the compatibilizer that is hydrophilic, divided by 5. The compatiblilizer is mixed into the B-side of the polyurethane formulation. The B-side of the spray foam formulations comprise polyol, water, amine catalyst, and the compatibilizer of the invention such that the water is present at about 2% to about 30% by weight of the B-side formulation, and the compatibilizer is present at about 1% to about 30% by weight of the B-side formulation. The B-side of the formulation may further comprise metal catalysts, flame retardants, silicone surfactants, cell openers, antioxidants, as well as other additives.

摘要翻译： 公开了烷基乙氧基化物醇或烷基醇乙氧基化物的混合物，其平均HLB值为10至15，作为基本上不含壬基酚乙氧基化物的水性聚氨酯泡沫制剂的增容剂。 HLB定义为亲水性增加剂平均结构的质量百分比除以5.将增容剂混合到聚氨酯配方的B侧。 喷雾泡沫制剂的B侧包含多元醇，水，胺催化剂和本发明的相容剂，使得水以B侧制剂的约2重量％至约30重量％存在，增容剂为 以B-side制剂的约1％至约30％重量存在。 制剂的B侧还可以包含金属催化剂，阻燃剂，硅氧烷表面活性剂，开孔剂，抗氧化剂以及其它添加剂。