公开(公告)号：US07183330B2

公开(公告)日：2007-02-27

申请号：US10736042

申请日：2003-12-15

申请人： Wayne Robert Furlan ,  Mark Leo Listemann ,  Joan Sudbury-Holtschlag ,  Thomas John Markley ,  Gary Dale Andrew

发明人： Wayne Robert Furlan ,  Mark Leo Listemann ,  Joan Sudbury-Holtschlag ,  Thomas John Markley ,  Gary Dale Andrew

IPC分类号： C08J9/14 ,  C08G77/46

CPC分类号： C08J9/141 ,  C08G18/7664 ,  C08G2101/0025 ,  C08G2101/005 ,  C08J9/0061 ,  C08J9/149 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2205/10 ,  C08J2375/04 ,  C08J2483/00

摘要： A method for making a rigid polyurethane foam by reacting a polyisocyanate and a polyol in the presence of a urethane catalyst, a blowing agent and a silicone surfactant characterized by employing a blowing agent comprising a C4 or C5 hydrocarbon, or mixtures thereof, with an average molecular weight of ≦72 g/mole and a boiling point in the range of 27.8 to 50° C., and a silicone surfactant comprising a polyether-polysiloxane copolymer represented by the following formula: (CH3)3—Si—O—(Si(CH3)2—O)x—(Si(CH3)(R)O)y—Si(CH3)3 where R=(CH2)3—O—(—CH2—CH2—O)a—(CH2—CH(CH3)—O)b—R″, and where R″ is H, (CH2)zCH3, or C(O)CH3; x+y+2 is 60–130; x/y is 5–14; z is 0–4; the total surfactant molecular weight, based on the formula, is 7000–30,000 g/mole, the wt % siloxane in the surfactant is 32–70 wt %, the blend average molecular weight (BAMW) of the polyether portion is 450–1000 g/mole, and the mole % of ethylene oxide in the polyether portion is 70–100 mole %.

公开(公告)号：US08618014B2

公开(公告)日：2013-12-31

申请号：US13547756

申请日：2012-07-12

申请人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

发明人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

IPC分类号： B01J27/24

CPC分类号： C08G18/7671 ,  C08G18/092 ,  C08G18/10 ,  C08G18/161 ,  C08G2101/0083 ,  C08G18/664

摘要： Catalyst compositions for use in forming polyurethane products include a gelling catalyst, a trimerization catalyst, and a cure accelerator. The gelling catalyst is a tertiary amine, mono(tertiary amino) urea, bis(tertiary amino) urea, or a combination of any of these. Any known trimerization catalyst may be used. The cure accelerator may be a diol having at least one primary hydroxyl group, and having from five to 17 chain backbone atoms chosen from carbon, oxygen, or both between the hydroxyl groups, provided that at least five of the backbone atoms are carbon. Alternatively or in addition, the cure accelerator may be a polyol having three or more hydroxyl groups, at least two of which are primary, and having molecular weights between 90 g/mole and 400 g/mole. Delayed initiation of the polyurethane-forming reaction and/or reduced demold time for producing the polyurethane part can be obtained by using these catalyst compositions.

摘要翻译： 用于形成聚氨酯产品的催化剂组合物包括胶凝催化剂，三聚催化剂和固化促进剂。 胶凝催化剂是叔胺，单（叔氨基）脲，双（叔氨基）脲或这些中的任何一种的组合。 可以使用任何已知的三聚催化剂。 固化促进剂可以是具有至少一个伯羟基的二醇，并且在羟基之间具有5至17个选自碳，氧或两者的链骨架原子，条件是至少五个骨架原子是碳。 或者或另外，固化促进剂可以是具有三个或更多个羟基的多元醇，其中至少两个是伯的，分子量在90g / mol至400g / mol之间。 通过使用这些催化剂组合物可以获得聚氨酯形成反应的延迟起始和/或用于制备聚氨酯部分的脱模时间的减少。

公开(公告)号：US20120277093A1

公开(公告)日：2012-11-01

申请号：US13547756

申请日：2012-07-12

申请人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

发明人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

IPC分类号： C08F4/00 ,  C08F4/08

CPC分类号： C08G18/7671 ,  C08G18/092 ,  C08G18/10 ,  C08G18/161 ,  C08G2101/0083 ,  C08G18/664

摘要： Catalyst compositions for use in forming polyurethane products include a gelling catalyst, a trimerization catalyst, and a cure accelerator. The gelling catalyst is a tertiary amine, mono(tertiary amino) urea, bis(tertiary amino) urea, or a combination of any of these. Any known trimerization catalyst may be used. The cure accelerator may be a diol having at least one primary hydroxyl group, and having from five to 17 chain backbone atoms chosen from carbon, oxygen, or both between the hydroxyl groups, provided that at least five of the backbone atoms are carbon. Alternatively or in addition, the cure accelerator may be a polyol having three or more hydroxyl groups, at least two of which are primary, and having molecular weights between 90 g/mole and 400 g/mole. Delayed initiation of the polyurethane-forming reaction and/or reduced demold time for producing the polyurethane part can be obtained by using these catalyst compositions.

摘要翻译： 用于形成聚氨酯产品的催化剂组合物包括胶凝催化剂，三聚催化剂和固化促进剂。 胶凝催化剂是叔胺，单（叔氨基）脲，双（叔氨基）脲或这些中的任何一种的组合。 可以使用任何已知的三聚催化剂。 固化促进剂可以是具有至少一个伯羟基的二醇，并且在羟基之间具有5至17个选自碳，氧或两者的链骨架原子，条件是至少五个骨架原子是碳。 或者或另外，固化促进剂可以是具有三个或更多个羟基的多元醇，其中至少两个是伯的，分子量在90g / mol至400g / mol之间。 通过使用这些催化剂组合物可以获得聚氨酯形成反应的延迟起始和/或用于制备聚氨酯部分的脱模时间的减少。

公开(公告)号：US08258198B2

公开(公告)日：2012-09-04

申请号：US11131179

申请日：2005-05-18

申请人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

发明人： Gary Dale Andrew ,  Mark Leo Listemann ,  Patrick Gordon Stehley ,  James Douglas Tobias ,  John William Miller

IPC分类号： B01J31/02

CPC分类号： C08G18/7671 ,  C08G18/092 ,  C08G18/10 ,  C08G18/161 ,  C08G2101/0083 ,  C08G18/664

摘要： Catalyst compositions for use in forming polyurethane products include a gelling catalyst, a trimerization catalyst, and a cure accelerator. The gelling catalyst is a tertiary amine, mono(tertiary amino) urea, bis(tertiary amino) urea, or a combination of any of these. Any known trimerization catalyst may be used. The cure accelerator may be a diol having at least one primary hydroxyl group, and having from five to 17 chain backbone atoms chosen from carbon, oxygen, or both between the hydroxyl groups, provided that at least five of the backbone atoms are carbon. Alternatively or in addition, the cure accelerator may be a polyol having three or more hydroxyl groups, at least two of which are primary, and having molecular weights between 90 g/mole and 400 g/mole. Delayed initiation of the polyurethane-forming reaction and/or reduced demold time for producing the polyurethane part can be obtained by using these catalyst compositions.

摘要翻译： 用于形成聚氨酯产品的催化剂组合物包括胶凝催化剂，三聚催化剂和固化促进剂。 胶凝催化剂是叔胺，单（叔氨基）脲，双（叔氨基）脲或这些中的任何一种的组合。 可以使用任何已知的三聚催化剂。 固化促进剂可以是具有至少一个伯羟基的二醇，并且在羟基之间具有5至17个选自碳，氧或两者的链骨架原子，条件是至少五个骨架原子是碳。 或者或另外，固化促进剂可以是具有三个或更多个羟基的多元醇，其中至少两个是伯的，分子量在90g / mol至400g / mol之间。 通过使用这些催化剂组合物可以获得聚氨酯形成反应的延迟起始和/或用于制备聚氨酯部分的脱模时间的减少。

公开(公告)号：US20080269365A1

公开(公告)日：2008-10-30

申请号：US11739750

申请日：2007-04-25

申请人： Gary Dale Andrew ,  John Elton Dewhurst ,  Mark Leo Listemann ,  Goran Zarkov ,  Yuedong Zhang

发明人： Gary Dale Andrew ,  John Elton Dewhurst ,  Mark Leo Listemann ,  Goran Zarkov ,  Yuedong Zhang

IPC分类号： C08G18/22 ,  C08G18/18

CPC分类号： C08G18/3825 ,  C08G18/10 ,  C08G18/1808 ,  C08G2101/0008 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08K5/3445 ,  C08G18/664 ,  C08L75/04

摘要： A composition for making a polyurethane foam includes a fugitive tertiary amine urethane catalyst and amidoamine and/or imidazoline property enhancing additives. The inclusion of one or more of these property enhancing additives serves to reduce or eliminate physical property and surface deterioration of polyurethane foams made at reduced density.

摘要翻译： 用于制备聚氨酯泡沫的组合物包括短暂的叔胺氨基甲酸酯催化剂和酰胺胺和/或咪唑啉性质增强添加剂。 包含一种或多种这些性能增强添加剂用于减少或消除以较低密度制成的聚氨酯泡沫的物理性能和表面变质。

公开(公告)号：US10023683B2

公开(公告)日：2018-07-17

申请号：US11451176

申请日：2006-06-12

申请人： Jared Denis Bender ,  Mark Leo Listemann ,  James Douglas Tobias

发明人： Jared Denis Bender ,  Mark Leo Listemann ,  James Douglas Tobias

IPC分类号： C08G18/40 ,  C08G18/48 ,  C08G18/18 ,  C08G18/20 ,  C08G18/76 ,  C08G101/00

摘要： The present invention provides a reactive catalyst composition for making a water blown flexible polyurethane foam. The catalyst composition comprises one or more tertiary amine catalysts in combination with (1) 2-methyl-1,3-propanediol or (2) a blend of 2-methyl-1,3-propanediol and a C7+ alkanol. The use of such catalyst composition improves the physical properties of the polyurethane foam.

公开(公告)号：US06759447B1

公开(公告)日：2004-07-06

申请号：US10338184

申请日：2003-01-06

申请人： Juan Jesus Burdeniuc ,  Mark Leo Listemann

发明人： Juan Jesus Burdeniuc ,  Mark Leo Listemann

IPC分类号： C08G1828

CPC分类号： C08G18/6564 ,  C08G18/1841 ,  C08G18/4072 ,  C08G2101/0008 ,  C08G2101/0083

摘要： The present invention relates to a method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, a gelling catalyst, and a tertiary amino alkyl amide catalyst composition. The catalyst composition is represented by the formula I: wherein R1, R2, R3, R4, R5, R6, A, and n are as defined herein.

摘要翻译： 本发明涉及一种制备聚氨酯泡沫体的方法，该方法包括在水作为发泡剂，细胞稳定剂，胶凝催化剂和叔氨基烷基酰胺催化剂组合物的存在下使有机多异氰酸酯和多元醇反应。 催化剂组合物由式I表示：其中R 1，R 2，R 3，R 4，R 5，R 6，A和n如本文所定义。

公开(公告)号：US6153659A

公开(公告)日：2000-11-28

申请号：US456261

申请日：1999-12-07

申请人： Richard Van Court Carr ,  Ning Chen ,  Mark Leo Listemann ,  Richard Paul Underwood

发明人： Richard Van Court Carr ,  Ning Chen ,  Mark Leo Listemann ,  Richard Paul Underwood

IPC分类号： C07C237/06 ,  C08G18/16 ,  C08G18/18 ,  C08G18/40 ,  C08G101/00 ,  C08J9/08 ,  C08G18/20 ,  C08G18/24 ,  C08G18/32

CPC分类号： C08G18/1841 ,  C07C237/06 ,  C08G18/4072 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： 3-{N-[2-(N',N'-dimethylamino ethoxy)ethyl]-N-methylamino}propionamide is a new compound which is useful as a catalyst in the production of polyurethane foams.

摘要翻译： 3- {N- [2-（N'，N'-二甲基氨基乙氧基）乙基] -N-甲基氨基}丙酰胺是一种新的化合物，可用作生产聚氨酯泡沫体中的催化剂。

公开(公告)号：US5710191A

公开(公告)日：1998-01-20

申请号：US647159

申请日：1996-05-21

申请人： Mark Leo Listemann ,  Kristen Elaine Minnich ,  Brian Eugene Farrell ,  Lisa Ann Mercando ,  Michael John Kimock ,  James Dudley Nichols

发明人： Mark Leo Listemann ,  Kristen Elaine Minnich ,  Brian Eugene Farrell ,  Lisa Ann Mercando ,  Michael John Kimock ,  James Dudley Nichols

IPC分类号： C07D453/02 ,  C08G18/18 ,  C08G18/20 ,  C07C269/02 ,  C07D251/34 ,  C08J9/04

CPC分类号： C08G18/1825 ,  C07D453/02 ,  C08G18/2054 ,  C08G2101/0008 ,  C08G2105/02 ,  Y10S521/902

摘要： A method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of a blowing agent, a cell stabilizer and a catalyst composition comprising at least one compound of either of the following formulas IA and IB: ##STR1## where R is hydrogen, methyl or hydroxymethyl. The preferred catalysts comprise 3-hydroxymethyl quinuclidine, 3-methyl-3-hydroxymethyl quinuclidine and 4-hydroxymethyl quinuclidine.

摘要翻译： 一种制备聚氨酯泡沫的方法，其包括在发泡剂，细胞稳定剂和催化剂组合物存在下使有机多异氰酸酯和多元醇反应，所述组合物包含至少一种下列式IA和IB的化合物： 其中R是氢，甲基或羟甲基。 优选的催化剂包括3-羟甲基奎宁环，3-甲基-3-羟甲基奎宁环和4-羟甲基奎宁环。

公开(公告)号：US6156814A

公开(公告)日：2000-12-05

申请号：US276962

申请日：1999-03-26

申请人： Ning Chen ,  Richard Van Court Carr ,  Mark Leo Listemann ,  Richard Paul Underwood

发明人： Ning Chen ,  Richard Van Court Carr ,  Mark Leo Listemann ,  Richard Paul Underwood

IPC分类号： C08G18/18 ,  C08G18/40 ,  C08G101/00 ,  C08J9/04

CPC分类号： C08G18/4072 ,  C08G18/1841 ,  C08G2101/00 ,  Y10S521/902

摘要： The use of 3-[3-(dimethylamino)propyl]-propionamide (Formula I) and 3,3'-{[3-(dimethylamino)propyl]imino}bis-propanamide (Formula II) as catalysts in the production of polyurethanes. ##STR1##

摘要翻译： 在制备聚氨酯中使用3- [3-（二甲基氨基）丙基] - 丙酰胺（式I）和3,3' - {[3-（二甲基氨基）丙基]亚氨基}双丙酰胺（式II）作为催化剂 。