Vehicular glass adhesive and method of adhering said glass
    1.
    发明授权
    Vehicular glass adhesive and method of adhering said glass 有权
    汽车玻璃粘合剂和粘附玻璃的方法

    公开(公告)号:US08729168B2

    公开(公告)日:2014-05-20

    申请号:US13093013

    申请日:2011-04-25

    IPC分类号: C08K5/00

    摘要: The invention is an adhesive composition comprising: a) an isocyanate functional polyether base prepolymers having a z molecular weight average (Mz) of about 10,000 to about 80,000 g/mole; a carbon black having an average oil absorption number of at least about 80 to at most about 400 cubic centimeters of dibutyl phthalate per 100 grams of the carbon black; (c) reactive silicon in an amount from about 0.001% to about 10% by weight of the adhesive composition; and (d) one or more catalysts for the reaction of isocyanate with hydroxyl groups. The adhesive compositions of the invention surprisingly may have improved sag performance (i.e., decreased sag) when heated, while also making them more easily pumped.

    摘要翻译: 本发明是一种粘合剂组合物,其包含:a)具有约10,000至约80,000g /摩尔的z分子量平均值(Mz)的异氰酸酯官能聚醚基预聚物; 平均吸油量为每100克炭黑至少约80至至多约400立方厘米邻苯二甲酸二丁酯的炭黑; (c)反应性硅,其量为粘合剂组合物重量的约0.001%至约10%; 和(d)用于使异氰酸酯与羟基反应的一种或多种催化剂。 当加热时,本发明的粘合剂组合物令人惊奇地具有改善的下垂性能(即,减小的下垂),同时也使它们更容易地泵送。

    VEHICULAR GLASS ADHESIVE AND METHOD OF ADHERING SAID GLASS
    2.
    发明申请
    VEHICULAR GLASS ADHESIVE AND METHOD OF ADHERING SAID GLASS 有权
    玻璃粘合剂和粘合玻璃的方法

    公开(公告)号:US20110265932A1

    公开(公告)日:2011-11-03

    申请号:US13093013

    申请日:2011-04-25

    摘要: The invention is an adhesive composition comprising: a) an isocyanate functional polyether base prepolymers having a z molecular weight average (Mz) of about 10,000 to about 80,000 g/mole; a carbon black having an average oil absorption number of at least about 80 to at most about 400 cubic centimeters of dibutyl phthalate per 100 grams of the carbon black; (c) reactive silicon in an amount from about 0.001% to about 10% by weight of the adhesive composition; and (d) one or more catalysts for the reaction of isocyanate with hydroxyl groups. The adhesive compositions of the invention surprisingly may have improved sag performance (i.e., decreased sag) when heated, while also making them more easily pumped.

    摘要翻译: 本发明是一种粘合剂组合物,其包含:a)具有约10,000至约80,000g /摩尔的z分子量平均值(Mz)的异氰酸酯官能聚醚基预聚物; 平均吸油量为每100克炭黑至少约80至至多约400立方厘米邻苯二甲酸二丁酯的炭黑; (c)反应性硅,其量为粘合剂组合物重量的约0.001%至约10%; 和(d)用于使异氰酸酯与羟基反应的一种或多种催化剂。 当加热时,本发明的粘合剂组合物令人惊奇地具有改善的下垂性能(即,减小的下垂),同时也使它们更容易地泵送。

    ACCELERATED ORGANOBORANE INITIATED POLYMERIZABLE COMPOSITIONS
    3.
    发明申请
    ACCELERATED ORGANOBORANE INITIATED POLYMERIZABLE COMPOSITIONS 失效
    加速有机发光可聚合组合物

    公开(公告)号:US20080295961A1

    公开(公告)日:2008-12-04

    申请号:US12182170

    申请日:2008-07-30

    IPC分类号: B32B27/32 C08F4/52 B05D3/02

    CPC分类号: C09J4/00 C09J4/06

    摘要: The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on the weight of the second part of i) a halogenated polyolefin having halosulfonyl groups or ii) a mixture of a halogenated polyolefin and an organic sulfonyl halide. The second part may further contain a compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprise one or more compounds capable of free radical polymerization.

    摘要翻译: 本发明是一种两部分可聚合组合物,其一部分包含能够形成自由基产生物质的有机硼化合物,在第二部分中包含一种或多种能够进行自由基聚合的化合物和约20至约30重量份,基于重量 的第二部分i)具有卤磺酰基的卤代聚烯烃,或ii)卤化聚烯烃和有机磺酰卤的混合物。 第二部分可以进一步包含能够使有机硼化合物在接触两部分时形成自由基产生物质的化合物。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。

    Accelerated organoborane initiated polymerizable compositions
    4.
    发明申请
    Accelerated organoborane initiated polymerizable compositions 失效
    加速有机硼烷引发的可聚合组合物

    公开(公告)号:US20080090981A1

    公开(公告)日:2008-04-17

    申请号:US11546794

    申请日:2006-10-12

    IPC分类号: C08F118/02

    CPC分类号: C09J4/00 C09J4/06

    摘要: The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on the weight of the second part of i) a halogenated polyolefin having halosulfonyl groups or ii) a mixture of a halogenated polyolefin and an organic sulfonyl halide. The second part may further contain a compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprise one or more compounds capable of free radical polymerization.

    摘要翻译: 本发明是一种两部分可聚合组合物,其一部分包含能够形成自由基产生物质的有机硼化合物,在第二部分中包含一种或多种能够进行自由基聚合的化合物和约20至约30重量份,基于重量 的第二部分i)具有卤磺酰基的卤代聚烯烃,或ii)卤化聚烯烃和有机磺酰卤的混合物。 第二部分可以进一步包含能够使有机硼化合物在接触两部分时形成自由基产生物质的化合物。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。

    Accelerated organoborane initiated polymerizable compositions
    5.
    发明授权
    Accelerated organoborane initiated polymerizable compositions 失效
    加速有机硼烷引发的可聚合组合物

    公开(公告)号:US07683132B2

    公开(公告)日:2010-03-23

    申请号:US12182170

    申请日:2008-07-30

    CPC分类号: C09J4/00 C09J4/06

    摘要: The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on the weight of the second part of i) a halogenated polyolefin having halosulfonyl groups or ii) a mixture of a halogenated polyolefin and an organic sulfonyl halide. The second part may further contain a compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprise one or more compounds capable of free radical polymerization.

    摘要翻译: 本发明是一种两部分可聚合组合物,其一部分包含能够形成自由基产生物质的有机硼化合物,在第二部分中包含一种或多种能够进行自由基聚合的化合物和约20至约30重量份,基于重量 的第二部分i)具有卤磺酰基的卤代聚烯烃,或ii)卤化聚烯烃和有机磺酰卤的混合物。 第二部分可以进一步包含能够使有机硼化合物在接触两部分时形成自由基产生物质的化合物。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。

    Accelerated organoborane initiated polymerizable compositions
    6.
    发明授权
    Accelerated organoborane initiated polymerizable compositions 失效
    加速有机硼烷引发的可聚合组合物

    公开(公告)号:US07524907B2

    公开(公告)日:2009-04-28

    申请号:US11546794

    申请日:2006-10-12

    CPC分类号: C09J4/00 C09J4/06

    摘要: The invention is a two part polymerizable composition comprising in one part an organoboron compound capable of forming free radical generating species and in the second part one or more compounds capable of free radical polymerization and from about 20 to about 30 parts by weight based on the weight of the second part of i) a halogenated polyolefin having halosulfonyl groups or ii) a mixture of a halogenated polyolefin and an organic sulfonyl halide. The second part may further contain a compound capable of causing the organoboron compound to form free radical generating species upon contacting the two parts. The first part may further comprise one or more compounds capable of free radical polymerization.

    摘要翻译: 本发明是一种两部分可聚合组合物,其一部分包含能够形成自由基产生物质的有机硼化合物,在第二部分中包含一种或多种能够进行自由基聚合的化合物和约20至约30重量份,基于重量 的第二部分i)具有卤磺酰基的卤代聚烯烃,或ii)卤化聚烯烃和有机磺酰卤的混合物。 第二部分可以进一步包含能够使有机硼化合物在接触两部分时形成自由基产生物质的化合物。 第一部分还可以包含一种或多种能够进行自由基聚合的化合物。

    Amido-organoborate initiator systems
    7.
    发明授权
    Amido-organoborate initiator systems 失效
    酰胺 - 有机硼酸引发剂体系

    公开(公告)号:US07737241B2

    公开(公告)日:2010-06-15

    申请号:US11544502

    申请日:2006-10-06

    IPC分类号: C08F4/52 C08F265/06

    摘要: The invention is a system for initiating free radical polymerization comprising: a) in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b) in a second part, a liberating compound which reacts with the nitrogen atom(s) bound to the boron atom(s) upon contact with the amido-borate to form an organoborane radical.

    摘要翻译: 本发明是用于引发自由基聚合的体系,其包括:a)一种或多种含有一种或多种含有机硼酸盐的阴离子酰氨基硼酸盐部分的酰氨基硼酸盐化合物,其中硼原子与氨的氮原子键合 含有一个或多个氮原子的有机化合物,例如烃基胺,烃基多胺或含有一个或多个氮原子并且任选地含有一个或多个含杂原子或杂原子的官能部分的芳族杂环,以及一种或多种阳离子抗衡离子 和b)在第二部分中,与氨基硼酸盐接触时与硼原子结合的氮原子反应形成有机硼烷基团的释放化合物。

    Stabilized organoborane polymerization initiators and polymerizable compositions
    9.
    发明授权
    Stabilized organoborane polymerization initiators and polymerizable compositions 有权
    稳定的有机硼烷聚合引发剂和可聚合组合物

    公开(公告)号:US07247596B2

    公开(公告)日:2007-07-24

    申请号:US10864719

    申请日:2004-06-09

    IPC分类号: B01J31/18 C08F4/12

    摘要: The invention is polymerizable compositions comprising in one part an organoboron compound capable of forming a free radical generating species and a stabilizing amount of one or more compounds comprising a dihydrocarbyl hydroxyl amine, an alicyclic hydroxyl amine, or a nitrile oxide of a dihydrocarbyl hydroxyl amine or an alicyclic hydroxyl amine, and in the second part one or more compounds capable of free radical polymerization.

    摘要翻译: 本发明是一种可聚合组合物,其一部分包含能够形成自由基产生物质的有机硼化合物和稳定量的一种或多种包含二烃基羟胺的二烃基羟胺,脂环族羟基胺或腈氧化物的化合物或 脂环族羟基胺,第二部分是一种或多种能够进行自由基聚合的化合物。